Abstract
Recently, phase transfer catalysis has been effectively exploited in the field of synthetic organic chemistry.1–3 However, there are scant reports on the syntheses of condensation polymers by phase transfer methods. Five years ago, we started a broad investigation into the use of phase transfer catalysis (PTC) to effect polycondensation. Since then, we have successfully synthesized various types of condensation polymers with high molecular weights. For example, aromatic polysulfonate III from aromatic disulfonyl chloride I and bisphenol II [Eq. (1)],4,5 aromatic polyphosphonate V from phenylphosphonic dichloride IV and II [Eq.(2)],6 and aromatic polyether VII from activated aromatic dichloride VI and II [Eq.(3)].7
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© 1984 Plenum Press, New York
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Imai, Y., Ueda, M. (1984). Syntheses of Carbon-Carbon Chain Polymers and Polysulfides by Phase Transfer Catalyzed Polycondensation. In: Mathias, L.J., Carraher, C.E. (eds) Crown Ethers and Phase Transfer Catalysis in Polymer Science. Polymer Science and Technology. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-9349-2_11
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DOI: https://doi.org/10.1007/978-1-4615-9349-2_11
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