Abstract
The synthesis and characterization of isolated, isomerically pure tetranuclear iron sandwich polyoxotungstates [(FeII)4(B-PW9O34)2]10- and [(FeII)4(B-P2W 15 O 56)2]16- as organic-soluble tetra-n-butylammonium salts are reported. These complexes have been characterized by 31p NMR, elemental analysis, magnetic susceptibility, UV-visible, infrared and EPR.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Similar content being viewed by others
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1993 Springer Science+Business Media New York
About this chapter
Cite this chapter
Khenkin, A.M., Hill, C.L. (1993). Hydrocarbon Oxidation by a Polynuclear Iron Sandwich Polyoxotungstate - Hydrogen Peroxide System. In: Barton, D.H.R., Martell, A.E., Sawyer, D.T. (eds) The Activation of Dioxygen and Homogeneous Catalytic Oxidation. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-3000-8_54
Download citation
DOI: https://doi.org/10.1007/978-1-4615-3000-8_54
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4613-6307-1
Online ISBN: 978-1-4615-3000-8
eBook Packages: Springer Book Archive