Abstract
The recent rapid development of organic light-emitting diodes (OLEDs) has resulted in the commercialization of simple dot-matrix OLED displays.1 The great success of OLED devices has also introduced a brand new organic semiconductor. Now, we are in the process of designing the physical and chemical makeup of this new type of organic semiconductor. In this chapter, first we will briefly describe the OLED development from the 1960s to the 1980s. Second, we will define the new organic semiconductor especially utilized for OLED devices and clarify what the organic semiconductor is and how it differs from the conventional inorganic semiconductor. Then, we will review the recent OLED progress by taking the following aspects into consideration: the design of multilayer cell structures, the design of each molecular constituents, hole transport, electron transport, and emitter and dopant molecules. Finally, we will discuss the future prospects of OLEDs.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Similar content being viewed by others
References
In November 1997, Pioneer Co. Ltd. in Japan firstly commercialized the 256 x 64 dot-matrix OLED information display for automobiles.
A. Bernanose, Br. J. Appl. Phys. 6, S54 (1955).
A. Bernanose, J. Chim. Phys. 51, 255 (1954).
A. Bernanose, J. Chim Phys. 52, 396 (1955).
G. D. Short and D. M. Herucles, J. Am. Chem. Soc. 87, 1439 (1965).
M. Pope, H. Kalimann, and P. Magnate, J. Chem. Phys. 38, 2042 (1963).
W. Helfrich and W. G. Schneider, Phys. Rev. Lett. 14, 229 (1965).
M. Sano, M. Pope, and H. Kallmann, J. Chem. Phys. 43, 2920 (1965).
W. G. Schneider and W. Helfrich, J. Chem. Phys. 44, 2902 (1966).
T. C. Werner, J. Chang, and D. M. Hercules, J. Am. Chem. Soc. 92, 763 (1970).
D. F. Williams and M. Schadt, J. Chem. Phys. 53, 3480 (1970).
H. P. Schwob, D. Weitz, and D. E Williams, Mol. Cryst. Liq. Cryst. 24, 271 (1973).
L. L. T. Bradrey, H. P. Schwob, D. Weitz, and D. F. Williams, Mol. Cryst. Liq. Cryst. 23, 271 (1073).
W. Hwang and K. C. Kao, J. Chem. Phys. 60, 3845 (1974).
M. Witter and I. Zschokke-Granacher, J. Chem. Phys. 63, 4187 (1975).
E Lohmann and W. Mehl, J. Chem. Phys. 50, 500 (1969).
C. E. Swenberg and M. Pope, Phys. Rev. 12, 4113 (1975).
J. Kalinowski and J. Godlewski, Chem. Phys. Lett. 36, 345 (1975).
J. Kalinowski, J. Godlewski, and R. Signerski, Mol. Cryst. Liq. Cryst. 33, 247 (1976).
J. Glinski, J. Godlewski, and J. Kalinowski, Mol. Cryst. Liq. Cryst. 48, 1 (1977).
G. G. Roberts, B. S. Keating, P. S. Vincett, and W. A. Barlow, J. Phys. C: Solid State Phys. 11, 3847 (1978).
P. S. Vincett, W. A. Barlow, R. A. Hann, and G. G. Roberts, Thin Solid Films 94, 171 (1982).
N. P. Sinha, Y. Misra, L. N. Tripathi, and M. Misra, Solid State Commun. 39, 89 (1981).
R. M. Burgess, M. Gouterman, and G. E. Khalil, J. Lumin. 28, 377 (1983).
G. G. Roberts, M. McGinnity, P. S. Vincett, and W. A. Barlow, Solid State Commun. 32, 683 (1979).
P. H. Partridge, Polymer 24, 733 (1983).
P. H. Partridge, Polymer 24, 739 (1983).
P. H. Partridge, Polymer 24, 748 (1983).
P. H. Partridge, Polymer 24, 755 (1983).
S. Hayashi, H. Etoh, and S. Saito, Jpn. J. Appl. Phys. 25, L773 (1986).
C. W. Tang and S. A. VanSlyke, Appl. Phys. Lett. 51, 913 (1987).
C. Adachi, S. Tokito, T. Tsutsui, and S. Saito, Jpn. J. Appl. Phys. 27, L269 (1987).
C. Adachi, S. Tokito, T. Tsutsui, and S. Saito, Jpn. J. Appl. Phys. 27, L713 (1987).
C. Adachi, T. Tsutsui, and S. Saito, Appl. Phys. Lett. 55, 1489 (1989).
C. Adachi, T. Tsutsui, and S. Saito, Appl. Phys. Lett. 56, 799 (1990).
C. Adachi, T. Tsutsui, and S. Saito, Appl. Phys. Lett. 57, 531 (1990).
C. Adachi, T. Tsutsui, and S. Saito, Optoelectron: Devices Technol. 6, 25 (1991).
M. Pope and C. E. Swenberg, Electronic Processes in Organic Crystals, Oxford University Press, New York, 1982.
S. Tokito, T. Tsutsui, and S. Saito, Polym. Commun. 27, 333 (1986).
K. C. Kao and W. Hwang, Electrical Transport in Solids, with Particular Reference to Organic Semiconductors, International Series in the Science of the Solid States Vol. 14, Pergamon Press, London, 1981.
S. M. Sze, Physics of Semiconductor Devices, Wiley, New York, 1981.
K. Seki, E. Ito, and H. Ishii, Synth. Met. 91, 137 (1997).
Z. Shen, P. E. Burrows, V. Bulovic, D. M. McCarty, M. E. Thompson, and S. R. Forrest, Jpn. J. Appl. Phys. 35, L401 (1996).
Y. Abe, K. Onisawa, S. Aratani, and M. Hanazono, J. Electrochem. Soc. 139, 641 (1992).
T. Yonezawa, T. Nagata, H. Kato, A. Imamura, and K. Morokuma, Introduction of Quantum Chemistry, Kagaku-Dojin, Japan, 1983, (in Japanese).
N. J. Turro, Molecular Photochemisrty, Benjamin, San Francisco 1965.
Text book of Basic Optics
G. Gu, D. Z. Garbuzov, P. E. Burrows, S. Venkatesh, S. R. Forrest, and M. E. Thompson, Opt. Lett. 22, 396 (1997).
T. Tsutsui and S. Saito, in Intrinsically Conducting Polymer: An Emerging Technology, edited by M. Aldissi, Kluwer Academic, Dordrecht 1993, p. 123.
C. W. Tang, S. A. VanSlyke, and C. H. Chen, J. Appl. Phys. 65, 3610 (1989).
T. Tsutsui, E. Aminaka, Y. Hamada, C. Adachi, and S. Saito, SPIE Proc. 1910, 180 (1993).
T. Tsutsui, E. Aminaka, and S. Saito, J. Appl. Phys. 79, 8808 (1996).
K. H. Drexhage, in Progress in Optics, Volume 12, edited by E. Wolf, North-Holland, Amsterdam, 1974, p. 165.
S. A. VanSlyke and C. W. Tang, U.S. Patent 4, 720, 432.
S. A. VanSlyke, C. H. Chen, and C. W. Tang, Appl. Phys. Lett. 69, 2160 (1996).
Y. Shirota, Y. Kuwabara, H. Inada, T. Wakimoto, H. Nakada, Y. Yonemoto, S. Kawami, and K. Imai, Appl. Phys. Lett. 65, 807 (1994).
C. Adachi, K. Nagai, and N. Tamoto, Jpn. J. Appl. Phys. 35, 4819 (1996).
H. Tokailin, M. Matsura, H. Higashi, C. Hosokawa, and T. Kusumoto, SPIE Proceedings, 1910, 38 (1993).
C. P. Lin, T. Tsutsui, and S. Saito, J. Polym. Res. 2, 133 (1995).
J. Littman and R. Martic, J. Appl. Phys. 72, 1957 (1992).
H. Azuma, C. Hosokawa, H. Tokailin, and M. Kusumoto, Nippon Kagakukai-shi, 10, 1162 (1992) (in Japanese).
N. Tamoto, C. Adachi, and K. Nagai, Chem. Mater. 9, 1077 (1997).
C. Adachi, N. Tamoto, and K. Nagai, Appl. Phys. Lett. 66, 2679 (1995)
H. Tanaka, S. Tokito, Y. Taga, and A. Okada, Chem. Commun. 2175 (1996).
TDK patent (Japanese)
H. Antoniadis, M. R. Hueschen, J. McElvain, J. N. Miller, R. L. Moon, D. B. Roitman, and J. R. Sheats, Polymer. Prepr. (ACS) 382 (1997).
Y. Yang, and A. J. Heeger, J. Appl. Phys. 64, 1245 (1994)
TDK patent (Japanese)
A. Bacher, I. Bleyl, C. H. Eedelen, D. Haarer, W. Paulus, and H. W. Schmidt, Adv. Mater. 9, 1031 (1997).
T. Christ, V. Stumpflen, and J. H. Wendorff, Macromol. Rapid Commun. 18, 93 (1997).
S. Tanaka, C. Adachi, T. Koyama, and Y. Taniguchi, Chem. Lett. 975 (1998).
J. Salbeck, N. Yu, J. Bauer, F. Weissortel, and H. Bestgen, Synth. Met. 91, 209 (1997).
W. G. Gill, J. Appl. Phys. 43, 5033 (1972).
C. W. Tang, Appl. Phys. Lett. 48, 183 (1985).
C. Adachi, T. Tsutsui, and S. Saito, Vol. 358, Springer Proceedings in Physics Electroluminescence, Springer-Verlag, New York, 1989.
Y. Hamada, C. Adachi, T. Tsutsui, and S. Saito, Nippon Kagaku-kaishi 11, 1540 (1991) (in Japanese).
Y. Hamada, C. Adachi, T. Tsutsui, and S. Saito, Jpn. J. Appl. Phys. 31, 1812 (1992).
C. Adachi, K. Nagai, and N. Tamoto, Display Imaging 5, 325 (1997).
M. Strukelj, F. Papadimitrakopoulos, T. Miller, and L. Rothberg, Science 267, 1969 (1995).
E. Buchwald, M. Meier, S. Kag, R. Posch, H-W. Schmidt, R. Strohriegl, W. Reis, and M. Schwoerer, Adv. Mater. 10, 839 (1995).
J. Kido, G. Harada, and K. Nagai, Chem. Lett. 161 (1996).
Y. Yang and Q. Pei, J. Appl. Phys. 77, 4807 (1995).
Q. Pei and Y. Yang, Adv. Mater. 7, 559 (1995).
Q. Pei and Y. Yang, Chem. Mater. 7, 1568 (1995).
J. Kido, M. Kimura and K. Nagai, Science 267, 1332 (1995).
J. Bettenhausen, M. Greczmiel, M. Jandke, and P. Strohriegl, Synthe. Met. 91, 223 (1997).
Y. Kijima, N. Asai, and S. Tamura, MRS Abstract, 1998 Spring Meeting, 1998 p. 131.
M. Morikawa, C. Adachi, T. Tsutsui, and S. Saito, Denshi Jyoho Tsushin Gakkai Ronbunshi C-2, 661 (1990).
Y. Hamada, T. Sano, M. Fujita, T. Fujii, Y. Nishio, and K. Shibata, Jpn. J. Appl. Phys. 32, L514 (1993).
R. E. Burrows, L. S. Sapochak, D. M. McCarty, S. R. Forrest, and M. E. Thompson, Appl. Phys. Lett. 64, 2718 (1994).
Y. Hamada, T. Sano, M. Fujita, T. Fujii, Y. Nishio, and K. Shibata, Chem. Lett. 905 (1993).
J. Kido and Y. lizumi, Chem. Lett. 963 (1997).
S. A. VanSlyke, P. S. Bryan, and C. W. Tang, Inorganic and organic electroluminescence/EL 96, 1996, p. 195.
N. Nakamura, S. Wakabayashi, K. Miyairi, and T. Fujii, Chem. Lett. 1741 (1994).
Y. Hamada, K. Sano, M. Fujita, Y. Nishio, and K. Shibata, Nippon Kagakukai-shi, 879 (1993).
C. Hosokawa, H. Hagashi, H. Nakamura, and T. Kusumoto, Appl. Phys. Lett. 67, 3853 (1995).
TDK (unpublished).
Ricoh Patent (Japanese)
C. Adachi, K. Nagai, and N. Tamoto, Jpn. J. Appl. Phys. 35, 4819 (1996).
E. Aminaka, T. Tsutsui, and S. Saito, J. Appl. Phys. 79, 8808 (1996).
F. P. Schafer (ed.), Dye Lasers, Springer-Verlag, New York, 1973.
T. Wakimoto, Y. Yoneyama, J. Funaki, M. Tsuchida, R. Murayama, H. Nakada, H. Matsumoto, S. Yamamura, and M. Nomura, IGEL, Abstracts (Kitakyushu), 1997, p. 4 (1997).
H. Nakada and T. Tohma, Inorganic and Organic Electroluminescence/EL96, 1996, p. 385.
C. W Tang, SID 96 Digest 1996, p. 181.
J. Shi and C. W. Tang, Appl. Phys. Lett. 70, 1665 (1997).
T. Sano, M. Fujita, T. Fujii, and Y. Hamada, Jpn. J. Appl. Phys. 34, 1883 (1995).
T. Sano, Y. Hamada, and K. Shibata, Inorganic and Organic Electroluminescence/EL96, 1996, p. 249.
C. H. Chen and C. W. Tang, Chemistry of Functional Dyes,Mita Press, 1992, Vol. 2, p, 536.
Y. Sato, T. Ogata, S. Ichinosawa, and Y. Murata, Synthe. Met. 91, 103 (1997).
J. Kido, K. Nagai, Y. Okamoto, and T. Skotheim, Chem. Lett. 1267 (1991).
J. Kido, K. Nagai, and Y. Okamoto, J. Alloys Compounds 192 (1993).
M. Era, C. Adachi, T. Tsutsui, and S. Saito, Chem. Phys. Lett. 178, 488 (1991).
O. B. Dabbousi, M. G. Bawendi, O. Onitsuka, and M. F. Rubner, Appl. Phys. Lett. 66, 1316 (1995).
M. Era, S. Morimoto, T. Tsutsui, and S. Saito, Appl. Phys. Lett. 65, 676 (1994).
A. Kraft, Liebigs Ann. 1463 (1997).
R. N. Marks, F. Biscarini, R. Zamboni, and C. Taliani, EuroPhys. Lett. 32, 523 (1995).
M. Era, T. Tsutsui, and S. Saito, Appl. Phys. Lett. 67, 2436 (1995).
M. Granstrom and O. Inganas, Adv. Mater. 7, 1012 (1995).
C. Adachi, S. Hibino, T. Koyama, and Y. Taniguchi, Jpn. J. Appl. Phys. 36, L827 (1997).
Q. Pei, Y. Yang, G. Yu, C. Zhang, and A.J. Heeger, J. Am. Chem. Soc. 118, 3922 (1996).
A. Yamamori, C. Adachi, T. Koyama, and Y. Taniguchi, Appl. Phys. Lett. 72, 2147 (1998).
T. Tsutsui, C. Adachi, S. Saito, M. Watanabe, and M. Koishi, Chem. Phys. Lett. 182, 143 (1991).
A. Dodabalapur, L. J. Rothberg, T. M. Miller, and E. W. Kwock, Appl. Phys. Lett. 64, 2486 (1994).
F. Hide, B. Benjamin, J. Schwartz, M. A. Diaz-Garcia, and A. J. Heeger, Chem. Phys. Lett. 256, 424 (1996).
V. G. Kozlov, V. Bulovic, P. E. Burrows, and S. R. Forrest, Nature 389, 362 (1997).
M. Nagawa, C. Adachi, T. Koyama, and Y. Taniguchi, Appl. Phys. Lett. (submitted).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2004 Springer Science+Business Media New York
About this chapter
Cite this chapter
Adachi, C., Tsutsui, T. (2004). Molecular LED: Design Concept of Molecular Materials for High-Performance OLED. In: Shinar, J. (eds) Organic Light-Emitting Devices. Springer, New York, NY. https://doi.org/10.1007/978-0-387-21720-8_2
Download citation
DOI: https://doi.org/10.1007/978-0-387-21720-8_2
Publisher Name: Springer, New York, NY
Print ISBN: 978-1-4419-2960-0
Online ISBN: 978-0-387-21720-8
eBook Packages: Springer Book Archive