Abstract
The previous chapters have set the foundation for understanding the underlying physics of organic semiconductors and the basic operation and characteristics of OLEDs. This chapter brings all of these concepts together and covers the main electronic processes occurring in complete devices and the important considerations for designing efficient devices. First, the role of different layers in bringing charges together in a balanced manner is discussed. Next, the conditions needed to achieve efficient charge recombination to form excitons and confine the excitons to the light-emitting materials are covered. Materials and device considerations for efficient light emission based on fluorescence, phosphorescence, and thermally-activated delayed fluorescence, the three primarily employed processes, are discussed along with a few other processes that are being explored for efficient emission. Finally, we turn our attention to considerations such as light outcoupling and alternative device structures.
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References
Adachi C (2014) Third-generation organic electroluminescence materials. Jpn J Appl Phys 53:060101
Adachi C, Tsutsui T (2004) Molecular LED: design concept of molecular materials for high-performance OLED. In: Shinar J (ed) Organic light-emitting devices: a survey, 1st edn. Springer, New York, pp 43–69
Adachi C, Baldo MA, Forrest SR (2000) Electroluminescence mechanisms in organic light emitting devices employing a europium chelate doped in a wide energy gap bipolar conducting host. J Appl Phys 87:8049–8055
Adachi C, Baldo MA, Thompson ME, Forrest SR (2001) Nearly 100% internal phosphorescence efficiency in an organic light emitting device. J Appl Phys 90:5048–5051
Adamovich VI, Cordero SR, Djurovich PI, Tamayo A, Thompson ME, D’Andrade BW, Forrest SR (2003) New charge-carrier blocking materials for high efficiency OLEDs. Org Electron 4:77–87
Aguirre CM, Auvray S, Pigeon S, Izquierdo R, Desjardins P, Martel R (2006) Carbon nanotube sheets as electrodes in organic light-emitting diodes. Appl Phys Lett 88:183104
Amos R, Barnes WL (1997) Modification of the spontaneous rate of Eu3+ ions close to a thin metal mirror. Phys Rev B 55:7249–7254
Baldo MA, O’Brien DF, You Y, Shoustikov A, Sibley S, Thompson ME, Forrest SR (1998) Highly efficient phosphorescent emission from organic electroluminescent devices. Nature 395:151–154
Baldo MA, Adachi C, Forrest SR (2000a) Transient analysis of organic electrophosphorescence. II. Transient analysis of triplet-triplet annihilation. Phys Rev B 62:10967–10977
Baldo MA, Thompson ME, Forrest SR (2000b) High-efficiency fluorescent organic light-emitting devices using a phosphorescent sensitizer. Nature 403:750–753
Barnes WL (1998) Fluorescence near interfaces: the role of photonic mode density. J Mod Opt 45:661–699
Berggren M, Gustafsson G, Inganas O, Andersson MR, Hjertberg T, Wennerstrom O (1994) White light from an electroluminescent diode made from poly[3(4-octylphenyl)-2,2′-bithiophene] and an oxadiazole derivative. J Appl Phys 76:7530–7534
Bertram D, Born M, Jüstel T (2007) Incoherent light sources. In: Träger F (ed) Springer handbook of lasers and optics, 1st edn. Springer, New York, pp 565–582
Brütting W (2005) Introduction to the physics of organic semiconductors. In: Brütting W (ed) Physics of organic semiconductors, 1st edn. Wiley-VCH, Weinheim, pp 1–14
Brütting W, Frischeisen J, Schmidt TD, Scholz BJ, Mayr C (2013) Device efficiency of organic light-emitting diodes: progress by improved light outcoupling. Phys Status Solidi 210:44–65
Bulović V, Tian P, Burrows PE, Gokhale MR, Forrest SR, Thompson ME (1997) A surface-emitting vacuum-deposited organic light emitting device. Appl Phys Lett 70:2954
Bulović V, Khalfin CB, Gu G, Burrows PE, Garbuzov DZ, Forrest SR (1998) Weak microcavity effects in organic light-emitting devices. Phys Rev B 58:3730–3740
Burn PL, Lo SC, Samuel IDW (2007) The development of light-emitting dendrimers for displays. Adv Mater 19:1675–1688
Burroughes JH, Bradley DDC, Brown AR, Marks RN, Mackay K, Friend RH, Burn PL, Holmes AB (1990) Light-emitting diodes based on conjugated polymers. Nature 347:539–541
Chance RR, Prock A, Silbey R (1974) Lifetime of an emitting molecule near a partially reflecting surface. J Phys Chem 60:2744–2748
Chang YJ, Chow TJ (2011) Highly efficient red fluorescent dyes for organic light-emitting diodes. J Mater Chem 21:3091–3099
Chang JH, Lin WH, Wang PC, Taur JI, Ku TA, Chen WT, Yan SJ, Wu CI (2015) Solution-processed transparent blue organic light-emitting diodes with graphene as the top cathode. Sci Rep 5:9693
Chaskar A, Chen H-F, Wong KT (2011) Bipolar host materials: a chemical approach for highly efficient electrophosphorescent devices. Adv Mater 23:3876–3895
Chen SY, Chu TY, Chen JF, Su CY, Chen CH (2006) Stable inverted bottom-emitting organic electroluminescent devices with molecular doping and morphology improvement. Appl Phys Lett 89:053518
Chen J, Zhao F, Ma D (2014) Hybrid white OLEDs with fluorophors and phosphors. Mater Today 17:175–183
Chiang CJ, Kimyonok A, Etherington MK, Griffiths GC, Jankus V, Turksoy F, Monkman AP (2013) Ultrahigh efficiency fluorescent single and bi-layer organic light-emitting diodes: the key-role of triplet fusion. Adv Funct Mater 23:739–746
Chou PY, Chou HH, Chen YH, Su TH, Liao CY, Lin HW, Lin WC, Yen HY, Chen IC, Cheng CH (2014) Efficient delayed fluorescence via triplet-triplet annihilation for deep-blue electroluminescence. Chem Commun 50:6869–6871
Christogiannis N, Somaschi N, Micchetti P, Coles DM, Savvidis PG, Lagoudakis PG, Lidzey DG (2013) Characterizing the electroluminescence emission from a strongly-coupled organic semiconductor microcavity LED. Adv Opt Mater 1:503–509
Chu TY, Chen JF, Chen SY, Chen CJ, Chen CH (2006) Highly efficient and stable inverted bottom-emission organic light emitting devices. Appl Phys Lett 89:053503
Crawford OH (1988) Radiation from oscillating dipoles embedded in a layered system. J Chem Phys 89:6017–6027
Cui LS, Ruan SB, Bencheikh F, Nagata R, Zhang L, Inada K, Nakanotani H, Liao LS, Adachi C (2017) Long-lived efficient delayed fluorescence organic light-emitting diodes using n-type hosts. Nat Commun 8:2250
D’Andrade BW, Forrest SR (2004) White organic light-emitting devices for solid-state lighting. Adv Mater 16:1585–1595
D’Andrade BW, Baldo MA, Adachi C, Brooks J, Thompson ME, Forrest SR (2001) High-efficiency yellow double-doped organic light-emitting devices based on phosphor-sensitized fluorescence. Appl Phys Lett 79:1045–1047
D’Andrade BW, Thompson ME, Forrest SR (2002) Controlling exciton diffusion in multilayer white phosphorescent organic light emitting devices. Adv Mater 14:147–151
D’Andrade BW, Holmes RJ, Forrest SR (2004) Efficient organic electrophosphorescent white-light-emitting device with a triple doped emissive layer. Adv Mater 16:624–628
Dobbertin T, Kroeger M, Heithecker D, Schneider D, Metzdorf D, Neuner H, Becker E, Johannes HH, Kowalsky W (2003) Inverted top-emitting organic light-emitting diodes using sputter-deposited anodes. Appl Phys Lett 82:284–286
Dodabalapur A, Rothberg LJ, Jordan RH, Miller TM, Slusher RE, Phillips JM (1996) Physics and applications of organic microcavity light-emitting diodes. J Appl Phys 80:6954–6964
Drexhage KH (1970) Influence of a dielectric interface on fluorescence decay time. J Lumin 1-2:693–701
Endo A, Ogasawara M, Takahashi A, Yokoyama D, Kato Y, Adachi C (2009) Thermally-activated delayed fluorescence from Sn4+-porphyrin complexes and their application to organic light-emitting diodes- a novel mechanism for electroluminescence. Adv Mater 21:4802–4806
Erickson NC, Holmes R (2013) Investigating the role of emissive layer architecture on the exciton recombination zone in organic light-emitting devices. Adv Funct Mater 23:5190–5198
Feng J, Li F, Gao WB, Liu SY, Liu Y, Wang Y (2001) White light emission from exciplex using tris-(8-hydroxyquinoline)aluminum as chromaticity-tuning layer. Appl Phys Lett 78:3947–3949
Flämmich M, Frischeisen J, Setz DS, Michaelis D, Krummacher BC, Schmidt TD, Brütting W, Danz N (2011) Oriented phosphorescent emitters boost OLED efficiency. Org Electron 12:1663–1668
Forget S, Chenais S, Tondelier D, Geffroy B, Gozhyk I, Lebental M, Ishow E (2010) Red-emitting fluorescent organic light emitting diodes with low sensitivity to self-quenching. J Appl Phys 108:064509
Freitag P, Zakhidov AA, Luessem B, Zakhidov AA, Leo K (2012) Lambertian white top-emitting organic light emitting device with carbon nanotube cathode. J Appl Phys 112:114505
Frischeisen J, Yokoyama D, Endo A, Adachi C, Brütting W (2011) Increased light outcoupling efficiency in dye-doped small molecule organic light-emitting diodes with horizontally oriented emitters. Org Electron 12:809–817
Fukugawa H, Shimizu T, Ohbe N, Tokito S, Tokumaru K, Fujikake H (2012) Anthracene derivatives as efficient emitting hosts for blue organic light-emitting diodes utilizing triplet-triplet annihilation. Org Electron 13:1197–1203
Furno M, Meerheim R, Hofmann S, Lüssem B, Leo K (2012a) Efficiency and rate of spontaneous emission in organic electroluminescent devices. Phys Rev B 85:115205
Furno M, Rosenow TC, Gather MC, Lüssem B, Leo K (2012b) Analysis of the external and internal quantum efficiency of multi-emitter, white organic light emitting diodes. Appl Phys Lett 101:143304
Furukawa T, Nakanotani H, Adachi C (2015) Dual enhancement of electroluminescence efficiency and operational stability by rapid upconversion of triplet excitons in OLEDs. Sci Rep 5:8429
Gao Y (2010) Interface in organic semiconductor devices: dipole, doping, band bending, and growth. In: So F (ed) Organic electronics: materials, processing, devices and applications, 1st edn. CRC Press, Boca Raton, pp 141–179
Gather MC, Reineke S (2015) Recent advances in light outcoupling from white organic light-emitting diodes. J Photonics Energy 5:057607
Goushi K, Kwong R, Brown J, Sasabe H, Adachi C (2004) Triplet exciton confinement and unconfinement by adjacent hole-transport layers. J Appl Phys 97:7798–7802
Goushi K, Yoshida K, Sato K, Adachi C (2012) Organic light-emitting diodes employing efficient reverse intersystem crossing for triplet-to-singlet state conversion. Nat Photonics 6:253–258
Greenham NC, Friend RH, Bradley DDC (1994) Angular dependence of the emission from a conjugated polymer light-emitting diode: implications for efficiency calculations. Adv Mater 6:491–494
Gu G, Bulović V, Burrows PE, Forrest SR, Thompson ME (1996) Transparent organic light emitting devices. Appl Phys Lett 68:2606–2608
Han TH, Lee Y, Choi MR, Woo SH, Bae SH, Hong BH, Ahn JH, Lee TW (2012) Extremely efficient flexible organic light-emitting diodes with modified graphene anode. Nat Photonics 6:105–110
Helander MG, Wang Z, Lu Z-H (2012) Electrode-organic Interface physics. In: Bhushan B (ed) Encyclopedia of nanotechnology, 1st edn. Springer Netherlands, Dordrecht, pp 702–710
Higuchi T, Nakanotani H, Adachi C (2015) High-efficiency white organic light-emitting diodes based on blue thermally activated delayed fluorescent emitter combined with green and red fluorescent emitters. Adv Mater 27:2019–2023
Hirata S, Sakai Y, Masi K, Tanaka H, Lee SY, Nomura H, Nakamura N, Yasumatsu M, Nakanotani H, Zhang Q, Shizu K, Miyazaki H, Adachi C (2015) Highly efficient blue electroluminescence based on thermally-activated delayed fluorescence. Nat Mater 14:330–336
Holmes RJ, D’Andrade BW, Forrest SR, Ren X, Li J, Thompson ME (2003) Efficient, deep-blue organic electrophosphorescence by guest charge trapping. Appl Phys Lett 83:3818–3820
Hu JY, Pu YJ, Satoh F, Kawata S, Katagiri H, Sasabe H, Kido J (2014) Bisanthracene-based donor-acceptor type light-emitting dopants: highly efficient deep-blue emission in organic light-emitting devices. Adv Funct Mater 24:2064–2071
Huang Q, Walzer K, Pfeiffer M, Lyssenko V, He G, Leo K (2006) Highly efficient top emitting organic light-emitting diodes with organic outcoupling enhancement layers. Appl Phys Lett 88:113515
Hung LS, Tang CW, Mason MG, Raychaudhuri P, Madathil J (2001) Application of an ultrathin LiF/Al bilayer in organic surface-emitting diodes. Appl Phys Lett 78:544–546
Hung WY, Chiang PY, Lin SW, Tang WC, Chen YT, Liu SH, Chou PT, Hung YT, Wong KT (2016) Balance the carrier mobility to achieve high performance exciplex OLED using a triazine-based acceptor. ACS Appl Mater Interfaces 8:4811–4818
Ishii H, Sugiyama K, Ito E, Seki K (1999) Energy level alignment and interfacial electronic structures at organic/metal and organic/organic interfaces. Adv Mater 11:605–625
Jurow MJ, Mayr C, Schmidt TD, Lampe T, Djurovich PI, Brütting W, Thompson ME (2016) Understanding and predicting the orientation of heteroleptic phosphors in organic light-emitting materials. Nat Mater 15:85–91
Kaji H, Suzuki H, Fukushima T, Shizu K, Suzuki K, Kubo S, Komino T, Oiwa H, Suzuki F, Wakamiya A, Murata Y, Adachi C (2015) Purely organic electroluminescent material realizing 100% conversion from electricity to light. Nat Commun 6:8476
Kanno H, Sun Y, Forrest SR (2005) High-efficiency top-emissive white-light-emitting organic electrophosphorescent devices. Appl Phys Lett 86:263502
Kawamura Y, Yanagida S, Forrest SR (2002) Energy transfer in polymer electrophosphorescent light emitting devices with single and multiple doped luminescent layers. J Appl Phys 92:87–93
Kawamura Y, Goushi K, Brooks J, Brown JJ, Sasabe H, Adachi C (2005) 100% phosphorescence quantum efficiency of Ir(III) complexes in organic semiconductor films. Appl Phys Lett 86:071104
Kena-Cohen S, Forrest SR (2010) Room-temperature polariton lasing in an organic single-crystal microcavity. Nat Photonics 4:371–375
Kido J, Hongawa K, Okuyama K, Nagai K (1994) White light-emitting organic electroluminescent devices using the poly(N-vinylcarbazole) emitter layer doped with three fluorescent dyes. Appl Phys Lett 64:815–817
Kido J, Shionoya H, Nagai K (1995a) Single-layer white light-emitting organic electroluminescent devices based on dye-dispersed poly(N-vinylcarbazole). Appl Phys Lett 67:2281–2283
Kido J, Kimura M, Nagai K (1995b) Multilayer white light-emitting organic electroluminescent device. Science 267:1332–1334
Kim JS, Ho PHK, Thomas DS, Friend RH, Bao GW, Li SFY, Cacialli F (1999) X-ray photoelectron spectroscopy of surface-treated indium tin oxide thin films. Chem Phys Lett 315:307–312
Kim JS, Ho PKH, Greenham NC, Friend RH (2000) Electroluminescence emission pattern of organic light-emitting diodes: implications for device efficiency calculations. J Appl Phys 88:1073–1081
Kim HK, Kim DG, Lee KS, Huh MS, Jeong SH, Kim KI, Seong TY (2005) Plasma damage-free sputtering of indium tin oxide cathode layers for top-emitting organic light-emitting diodes. Appl Phys Lett 86:183503
Kim KH, Lee S, Moon CK, Kim SY, Park YS, Lee JH, Lee JW, Huh J, You YM, Kim JJ (2014) Phosphorescent dye-based supramolecules for high efficiency organic light-emitting diodes. Nat Commun 5:4769
Komino T, Tanaka H, Adachi C (2014) Selectively controlled orientational ordering linear-shaped thermally activated delayed fluorescent dopants. Chem Mater 26:3665–3671
Kondakov DY (2008) Role of chemical reactions of arylamine hole transport materials in operational degradation of organic light-emitting diodes. J Appl Phys 104:084520
Kondakov DY, Lenhart WC, Nichols WF (2007) Operational degradation of organic light-emitting diodes: mechanism and identification of chemical products. J Appl Phys 101:024512
Kondakov DY, Pawlik TD, Hatwar TK, Spindler JP (2009) Triplet annihilation exceeding spin statistical limit in highly efficient fluorescent organic light-emitting diodes. J Appl Phys 106:124510
Kondakova ME, Pawlik TD, Young RH, Giesen DJ, Kondakov DY, Brown CT, Deaton JC, Lenhard JR, Klubek KP (2008) High-efficiency, low-voltage phosphorescent organic light-emitting diode devices with mixed host. J Appl Phys 104:094501
Krummacher BC, Nowy S, Frischeisen J, Klein M, Brütting W (2009) Efficiency analysis of organic light-emitting diodes based on optical simulation. Org Electron 10:478–485
Kuma H, Hosokawa C (2014) Blue fluorescent OLED materials and their application for high performance devices. Sci Technol Adv Mater 15:034201
Langevin P (1903) Ionisation des gaz. Ann Chim Phys 28:289–384
Lee H, Park I, Kwak J, Yoon DY, Lee C (2010) Improvement of electron injection in inverted bottom-emission blue phosphorescent organic light emitting diodes using zinc oxide nanoparticles. Appl Phys Lett 96:153306
Lee S, Kim KH, Limbach D, Park YS, Kim JJ (2013) Low roll-off and high efficiency orange organic light-emitting diodes with controlled co-doping of green and red phosphorescent dopants in an exciplex forming co-host. Adv Funct Mater 23:4105–4110
Lee JS, Chen HF, Batagoda T, Coburn C, Djurovich PI, Thompson ME, Forrest SR (2016) Deep blue phosphorescent organic light-emitting diodes with very high brightness and efficiency. Nat Mater 15:92–98
Li W, Kwok H (2012) Conduction mechanisms in organic semiconductors. In: Bhushan B (ed) Encyclopedia of nanotechnology, 1st edn. Springer Netherlands, Dordrecht, pp 493–500
Li J, Hu L, Wang L, Zhou Y, Grüner G, Marks TJ (2006) Organic light-emitting diodes having carbon nanotube anodes. Nano Lett 6:2472–2477
Li W, Li J, Wang F, Gao Z, Zhang S (2015) Universal host materials for high-efficiency phosphorescent and delayed-fluorescence OLEDs. ACS Appl Mater Interfaces 7:26206–26216
Liao LS, Hung LS, Chan WC, Ding XM, Sham TK, Bello I, Lee CS, Lee ST (1999) Ion-beam-induced surface damages on tris-(8-hydroxyquinoline) aluminum. Appl Phys Lett 75:1619–1621
Lin HW, Lin CL, Chang HH, Lin YT, Wu CC, Chen YM, Chen RT, Chien YY, Wong KT (2004) Anisotropic optical properties and molecular orientation in vacuum-deposited ter(9,9-diarylfluorene)s thin films using spectroscopic ellipsometry. J Appl Phys 95:881–886
Liu XK, Chen Z, Zheng CJ, Chen M, Liu W, Zhang XH, Lee CS (2015) Nearly 100% triplet harvesting in conventional fluorescent dopant-based organic light-emitting devices through energy transfer from exciplex. Adv Mater 27:2025–2030
Lu MH, Weaver MS, Zhou TX, Rothman M, Kwong RC, Hack M, Brown JJ (2002) High-efficiency top-emitting organic light-emitting devices. Appl Phys Lett 81:3921–3923
Lu CY, Jiao M, Lee WK, Chen CY, Tsai WL, Lin CY, Wu CC (2016) Achieving above 60% external quantum efficiency in organic light-emitting devices using ITO-free low index transparent electrode and emitters with preferential horizontal emitting dipoles. Adv Funct Mater 26:3250–3258
Lyu YY, Kwak J, Kwon O, Lee SH, Kim D, Lee C, Char K (2008) Silicon cored anthracene derivatives as host materials for highly efficient blue organic light-emitting devices. Adv Mater 20:2720–2724
Ma R (2012) Organic light emitting diodes (OLEDS). In: Chen J, Cranton W, Fihn M (eds) Handbook of visual display technology, 1st edn. Springer, Heidelberg, pp 1209–1222
Masui K, Nakanotani H, Adachi C (2013) Analysis of exciton annihilation in high-efficiency sky-blue organic light-emitting diodes with thermally activated delayed fluorescence. Org Electron 14:2721–2272
Mazzeo M, Pisignano D, Della Sala F, Thompson J, Blyth RIR, Gigli G, Cingolani R, Sotgiu G, Barbarella G (2003) Organic single-layer white light-emitting diodes by exciplex emission from spin-coated blends of blue emitting molecules. Appl Phys Lett 82:334–336
Meerheim R, Furno M, Hofmann S, Lüssem B, Leo K (2010) Quantification of energy loss mechanisms in organic light-emitting diodes. Appl Phys Lett 97:253305
Morii K, Ishida M, Takashima T, Shimoda T, Wang Q, Nazeeruddin K, Grӓtzel M (2006) Encapsulation-free hybrid organic-inorganic light-emitting diodes. Appl Phys Lett 89:183510
Murawski C, Leo K, Gather MC (2013) Efficiency roll-off in organic light-emitting diodes. Adv Mater 25:6801–6827
Nakanotani H, Masui K, Nishide J, Shibata T, Adachi C (2013) Promising operational stability of high-efficiency organic light-emitting diodes based on thermally activated delayed fluorescence. Sci Rep 3:2127
Nakanotani H, Higuchi T, Furukawa T, Masui K, Morimoto K, Numata M, Tanaka H, Sagara Y, Yasuda T, Adachi C (2014) High-efficiency organic light-emitting diodes with fluorescent emitters. Nat Commun 5:4016–4023
Nishide JI, Nakanotani H, Hiraga Y, Adachi C (2014) High-efficiency white organic light-emitting diodes using thermally activated delayed fluorescence. Appl Phys Lett 104:23304
Noriega R, Salleo A (2012) Charge transport theories in organic semiconductors. In: Klauk H (ed) Organic electronics II: more materials and applications, 1st edn. Wiley-VCH, Weinheim, pp 67–104
Notsuka N, Kabe R, Goushi K, Adachi C (2017) Confinement of long-lived triplet excitons in organic semiconducting host-guest systems. Adv Funct Mater 27:1703902
Olthof S, Meerheim R, Schober M, Leo K (2009) Energy level alignment at the interfaces in a multilayer organic light-emitting diode structure. Phys Rev B 79:245308
Park YS, Lee S, Kim KH, Kim SY, Lee JH, Kim JJ (2013) Exciplex-forming co-host for organic light-emitting diodes with ultimate efficiency. Adv Funct Mater 23:4914–4920
Parthasarathy G, Adachi C, Burrows PE, Forrest SR (2000) High-efficiency transparent organic light-emitting devices. Appl Phys Lett 76:2128–2130
Pu Y-J, Nakata G, Satoh F, Sasabe H, Yokoyama D, Kido J (2012) Optimizing the charge balance of fluorescent organic light-emitting devices to achieve high external quantum efficiency beyond the conventional upper limit. Adv Mater 24:1765–1770
Purcell EM (1946) Spontaneous emission probabilities at radio frequencies. Phys Rev 69:681
Reineke S, Walzer K, Leo K (2007) Triplet-exciton quenching in organic phosphorescent light-emitting diodes with Ir-based emitters. Phys Rev B 75:125328
Reineke S, Lindner F, Schwartz G, Seidler N, Walzer K, Lüssem B, Leo K (2009a) White organic light-emitting diodes with fluorescent tube efficiency. Nature 459:234–238
Reineke S, Schwartz G, Walzer K, Falke M, Leo K (2009b) Highly phosphorescent organic mixed films: the effects of aggregation on triplet-triplet annihilation. Appl Phys Lett 94:163305
Ribierre JC, Ruseckas A, Knights K, Staton SV, Cumpstey N, Burn PL, Samuel IDW (2008) Triplet exciton diffusion and phosphorescence quenching in iridium(III)-centered dendrimers. Phys Rev Lett 100:017402
Riel H, Karg S, Beierlein T, Ruhstaller B, Rieß W (2003) Phosphorescent top-emitting organic light-emitting devices with improved light outcoupling. Appl Phys Lett 82:466–468
Samuel IDW, Turnbull GA (2007) Organic semiconductor lasers. Chem Rev 107:1272–1295
Sasabe H, Kido J (2013) Recent progress in phosphorescent organic light-emitting devices. Eur J Org Chem 2013:7653–7663
Sasabe H, Nakanishi H, Watanabe Y, Yano S, Hirasawa M, Pu Y-J, Kido J (2013) Extremely low operating voltage green phosphorescent organic light-emitting devices. Adv Funct Mater 23:5550–5555
Saxena K, Jain VK, Mehta DS (2009) A review on the light extraction techniques in organic electroluminescent devices. Opt Mater 32:221–233
Schmidt TD, Setz DS, Flämmich M, Frischeisen J, Michaelis D, Krummacher BC, Danz N, Brütting W (2011) Evidence for non-isotropic emitter orientation in a red phosphorescent organic light-emitting diode and its implications for determining the emitter’s radiative quantum efficiency. Appl Phys Lett 99:163302
Scholz S, Kondakov D, Lüssem B, Leo K (2015) Degradation mechanisms and reactions in organic light-emitting devices. Chem Rev 115:8449–8503
Scott JC, Karg S, Carter SA (1997) Bipolar charge and current distributions in organic light-emitting diodes. J Appl Phys 82:1454–1460
Scott JC, Malliaras GG, Salem JR, Brock PJ, Bozano L, Carter SA (1998) Injection, transport, and recombination in organic light-emitting diodes. Proc SPIE 3476:111–122
Shin H, Lee SG, Kim KH, Moon CK, Yoo SJ, Lee JH, Kim JJ (2014) Blue phosphorescent organic light-emitting diodes using an exciplex forming co-host with the external quantum efficiency of theoretical limit. Adv Mater 26:4730–4734
Shinar J, Savvateev V (2004) Introduction to organic light-emitting devices. In: Shinar J (ed) Organic light-emitting devices: a survey, 1st edn. Springer, New York, pp 1–41
Shirota J, Kageyama H (2007) Charge carrier transporting molecular materials and their applications in devices. Chem Rev 107:953–1010
Smith LH, Wasey JAE, Barnes WL (2004) Light outcoupling efficiency of top-emitting organic light-emitting diodes. Appl Phys Lett 84:2986
Smith LH, Wasey JAE, Samuel IDW, Barnes WL (2005) Light out-coupling efficiencies of organic light-emitting diode structures and the effect of photoluminescence quantum yield. Adv Funct Mater 15:1839–1844
So F (2010) Organic electronics: materials, processing, devices and applications. CRC Press, Boca Raton
Sun Y, Giebink NC, Kanno H, Ma B, Thompson ME, Forrest SR (2006) Management of singlet and triplet excitons for efficient white organic light-emitting devices. Nature 440:908–912
Sun JW, Lee JH, Moon CK, Kim KH, Shin H, Kim JJ (2014) A fluorescent organic light-emitting diode with 30% external quantum efficiency. Adv Mater 26:5684–5688
Tanaka D, Sasabe H, Li YJ, Su SJ, Takeda T, Kido J (2007) Ultrahigh efficiency green organic light-emitting devices. Jpn J Appl Phys 46:L10–L12
Tang CW, Van Slyke SA (1987) Organic electroluminescent diodes. Appl Phys Lett 51:913–915
Tang CW, VanSlyke SA, Chen CH (1989) Electroluminescence of doped organic thin films. J Appl Phys 65:3610–3616
Tao Y, Yang C, Qin J (2011) Organic host materials for phosphorescent organic light-emitting diodes. Chem Soc Rev 40:2943–2970
Tsang DPK, Matsushima T, Adachi C (2016) Operational stability enhancement in organic light-emitting diodes with ultrathin Liq interlayers. Sci Rep 6:22463
Tse SC, Cheung CH, So SK (2010) Charge transport and injection in amorphous organic semiconductors. In: So F (ed) Organic electronics: materials, processing, devices and applications, 1st edn. CRC Press, Boca Raton, pp 61–109
Tsutsui T, Takada N (2013) Progress in emission efficiency of organic light-emitting diodes: basic understanding and its technical application. Jpn J Appl Phys 52:110001
Tsutsui T, Yahiro M, Yokogawa H, Kawano K, Yokoyama M (2001) Doubling coupling-out efficiency in organic light-emitting devices using a thin silica aerogel layer. Adv Mater 13:1149–1152
Udagawa K, Sasabe H, Igarashi F, Kido J (2016) Simultaneous realization of high EQE of 30%, low drive voltage, and low efficiency roll-off at high brightness in blue phosphorescent OLEDs. Adv Opt Mater 4:86–90
Uoyama H, Goushi K, Shizu K, Nomura H, Adachi C (2012) Highly efficient organic light-emitting diodes from delayed fluorescence. Nature 492:234–238
Walzer K, Maennig B, Pfeiffer M, Leo K (2007) Highly efficient organic devices based on electrically doped transport layers. Chem Rev 107:1233–1271
Wang Q, Ding J, Ma D, Cheng Y, Wang L, Jing X, Wang F (2009) Harvesting excitons via two parallel channels for efficient white organic LEDs with nearly 100% internal quantum efficiency: fabrication and emission-mechanism analysis. Adv Funct Mater 19:84–95
Wang ZB, Helander MG, Qiu J, Puzzo DP, Greiner MT, Hudson ZM, Wang S, Liu ZW, Lu ZH (2011) Unlocking the full potential of organic light-emitting diodes on flexible plastic. Nat Photonics 5:753–757
Wasey JAE, Barnes WL (2000) Efficiency of spontaneous emission from planar microcavities. J Mod Opt 47:725–741
Williams EL, Haavisto K, Li J, Jabbour GE (2007) Excimer-based white phosphorescent organic light-emitting diodes with nearly 100% internal quantum efficiency. Adv Mater 19:197–202
Wu ZC, Chen ZH, Du X, Logan JM, Sippel J, Nikolou M, Kamaras K, Reynolds JR, Tanner DB, Hebard AF, Rinzler AG (2004) Transparent, conductive carbon nanotube films. Science 305:1273–1276
Wu J, Agrawal M, Becerril HA, Bao Z, Liu Z, Chen Y, Peumans P (2010) Organic light-emitting diodes on solution-processed graphene transparent electrodes. ACS Nano 4:43–48
Xiao L, Chen Z, Qu B, Luo J, Kong S, Gong Q, Kido J (2011) Recent progresses on materials for electrophosphorescent organic light-emitting devices. Adv Mater 23:926–952
Xu H, Chen R, Sun Q, Lai W, Su Q, Huang W, Liu X (2014) Recent progress in metal-organic complexes for optoelectronic applications. Chem Soc Rev 43:3259–3302
Yamamoto H, Oyamada T, Sasabe H, Adachi C (2004) Amplified spontaneous emission under optical pumping from an organic semiconductor laser structure equipped with transparent carrier injection electrodes. Appl Phys Lett 84:1401
Yao L, Zhang S, Wang R, Li W, Shen F, Yang B, Ma Y (2014) Highly efficient near-infrared organic light-emitting diode based on a butterfly-shaped donor-acceptor chromophore with strong solid-state fluorescence and a large proportion of radiative excitons. Angew Chem 126:2151–2155
Yersin H, Finkenzeller WJ (2008) Triplet emitters for organic light-emitting diodes: basic properties. In: Yersin H (ed) Highly efficient OLEDs with phosphorescent materials, 1st edn. Wiley-VCH, Weinheim, pp 1–97
Yokoyama D (2011) Molecular orientation in small molecule organic light-emitting diodes. J Mater Chem 21:19187–19202
Yokoyama D, Adachi C (2010) In situ real-time spectroscopic ellipsometry measurement for the investigation of molecular orientation in organic amorphous multilayer structures. J Appl Phys 107:123512
Yokoyama D, Sakaguchi A, Suzuki M, Adachi C (2009) Horizontal orientation of linear-shaped organic molecules having bulky substituents in neat and doped vacuum-deposited amorphous films. Org Electron 10:127–137
Yook KS, Lee JY (2014) Small molecule host materials for solution processed phosphorescent organic light-emitting diodes. Adv Mater 26:4218–4233
Yoshida K, Nakanotani H, Adachi C (2016) Effect of Joule heating on transient current and electroluminescence in p-i-n organic light-emitting diodes under pulsed voltage operation. Org Electron 31:287–294
Zhang M, Fang S, Zakhidov AA, Lee SB, Aleiv AE, Williams CD, Atkinson KR, Baughman RH (2005) Strong, transparent, multifunctional, carbon nanotube sheets. Science 309:1215–1219
Zhang D, Ryu K, Liu X, Polikarpov E, Ly J, Tompson ME, Zhou C (2006) Transparent, conductive, and flexible carbon nanotube films and their application in organic light-emitting diodes. Nano Lett 6:1880–1886
Zhang Y, Lee J, Forrest SR (2014a) Tenfold increase in the lifetime of blue phosphorescent organic light-emitting diodes. Nat Commun 5:5008
Zhang Q, Li B, Huang S, Nomura H, Tanaka H, Adachi C (2014b) Efficient blue organic light-emitting diodes employing thermally-activated delayed fluorescence. Nat Photonics 8:326–332
Zhang Q, Kuwabara H, Potscavage WJ, Huang S, Hatae Y, Shibata T, Adachi C (2014c) Anthraquinone-based intramolecular charge transfer compounds: computational molecular design, thermally-activated delayed fluorescence, and highly efficient red electroluminescence. J Am Chem Soc 136:18070–18081
Zhang Q, Tsang D, Kuwabara H, Hatae Y, Li B, Takahashi T, Lee SY, Yasuda T, Adachi C (2015) Nearly 100% internal quantum efficiency in undoped electroluminescent devices employing pure organic emitters. Adv Mater 27:2096–2100
Zhao Y, Zhu L, Chen J, Ma D (2012) Improving color stability of blue/orange complementary white OLEDs by using single-host double-emissive layer structure: comprehensive experimental investigation into the device working mechanism. Org Electron 13:1340–1348
Zhao L, Komino T, Inoue M, Kim JH, Ribierre JC, Adachi C (2015) Horizontal molecular orientation in solution-processed organic light-emitting diodes. Appl Phys Lett 106:063301
Zhou X, Pfreiffer M, Huang JS, Blochwitz-Nimoth J, Qin DS, Werner A, Drechsel J, Maennig B, Leo K (2002) Low-voltage inverted transparent vacuum deposited organic light-emitting diodes using electrical doping. Appl Phys Lett 81:922–924
Zhu M, Yang C (2013) Blue fluorescent emitters: design tactics and applications in organic light-emitting diodes. Chem Soc Rev 42:4963–4976
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Méhes, G., Sandanayaka, A.S.D., Ribierre, JC., Goushi, K. (2020). Physics and Design Principles of OLED Devices. In: Adachi, C., Hattori, R., Kaji, H., Tsujimura, T. (eds) Handbook of Organic Light-Emitting Diodes. Springer, Tokyo. https://doi.org/10.1007/978-4-431-55761-6_49-1
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