Abstract
Oxidation catalysis is of extreme importance in many areas of chemistry. The intrinsic mechanisms of oxidation reactions are, however, quite often understood only rather poorly, and catalyst research is mostly, if not exclusively, based on entirely empirical approaches. In this respect, gas-phase experiments can provide a complementary approach in that they can allow the investigation of the elementary processes in oxidation catalysis step by step. By such, some general insight can be obtained, which may assist in the development of more efficient oxidation catalysts.
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Acknowledgments
Generous financial support by the Academy of Sciences of the Czech Republic, the Deutsche Forschungsgemeinschaft (Sfb 546), and the Fonds der Chemischen Industrie is gratefully acknowledged.
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Schröder, D., Schwarz, H. (2006). Intrinsic Mechanisms of Oxidation Reactions as Revealed by Gas-Phase Experiments. In: Meyer, F., Limberg, C. (eds) Organometallic Oxidation Catalysis. Topics in Organometallic Chemistry, vol 22. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3418_056
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DOI: https://doi.org/10.1007/3418_056
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