Abstract
Metal-oxo and -peroxo species play key roles in catalytic oxidations using transition metals This contribution addresses gas-phase studies of diatomic metal-oxo species and their properties which turn out to be of prime importance for the understanding of the observed reactivity patterns. A second topic concerns higher transition-metal oxides such as di- and trioxides. For these species there exists a structural dichotomy with the corresponding dioxygen complexes, e.g., MO2 ⇆ M(O2). Most of the metal-based oxidations described involve crossings between surfaces of different spin as crucial steps, and the violation of spin conservation is proposed to determine the reactivity of the late transition-metal oxides. The ability of transition metals to mediate surface crossings via spin-orbit coupling is introduced as a key aspect in oxidation catalysis which has as yet not been fully appreciated. It is further outlined how these fundamental properties may relate to the properties of metal-oxo catalysts in the condensed phase.
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Schröder, D., Schwarz, H., Shaik, S. (2000). Characterization, Orbital Description, and Reactivity Patterns of Transition-Metal Oxo Species in the Gas Phase. In: Meunier, B. (eds) Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations. Structure and Bonding, vol 97. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-46592-8_4
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