Abstract
The oxidative addition of bis-o-benzoquinone Q–(CH=N–N=CH)–Q (L), in which two 3,5-ditert-butyl-o-benzoquinones are linked to each other in positions 6 via the CH=N–N=CH group, to triphenylstibine gave a new binuclear triphenylantimony(V) bis-catecholate complex, Ph3Sb(Cat–(CH=N–N=CH)–Cat)SbPh3 (I). Recrystallization of I from a methanol–trichloromethane mixture resulted in an additional coordination of a methanol molecule to each antimony atom to give the binuclear complex, (CH3OH)Ph3Sb(Cat–(CH=N–N=CH)–Cat)SbPh3(CH3OH) (I · 2CH3OH), the crystals of which (I · 2CH3OH) · 2CH3OH · CHCl3 (II) contain additionally two methanol solvate molecules, which fix the geometry of the nitrogen-containing bridging group, and a trichloromethane molecule. The molecular structure of compound II in the crystalline state was determined by X-ray diffraction (CIF file CCDC no. 1560840).
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Original Russian Text © M.V. Arsen’ev, L.S. Okhlopkova, A.I. Poddel’skii, G.K. Fukin, 2018, published in Koordinatsionnaya Khimiya, 2018, Vol. 44, No. 1, pp. 71–76.
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Arsen’ev, M.V., Okhlopkova, L.S., Poddel’skii, A.I. et al. Binuclear Triphenylantimony(V) Catecholate Based on Redox-Active Bis-o-Benzoquinone, a Bis-Catechol-Aldimine Derivative. Russ J Coord Chem 44, 162–168 (2018). https://doi.org/10.1134/S1070328418020021
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DOI: https://doi.org/10.1134/S1070328418020021