Abstract
The following new triphenylantimony(V) catecholate complexes bearing the protonated imine group are synthesized from the new sterically hindered 3,5-di-tert-butylpyrocatechols (6-(CH=N-o-(C6H4–NH2))-3,5-Cat)H2 (H2L1) and (6-(CH=N-o-(C6H4–OH))-3,5-Cat)H2 (H2L2) containing in position 6 the iminomethyl group bonded to the aniline or phenol substituent: (6-(CH=NH+-o-(C6H4–NH2))-3,5-Cat)SbPh3X (X = Br (I), OMe (III)) and (6-(CH=NH+-o-(C6H4–OH))-3,5-Cat)SbPh3X (X = Br (II), OMe (IV)). The molecular structure of complex III · CH 3 OH in the crystalline state is determined by X-ray diffraction analysis (CIF file CCDC no. 1554694). The electrochemical properties of complexes III and IV are studied by cyclic voltammetry.
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Original Russian Text © A.I. Poddel’sky, M.V. Arsen’ev, L.S. Okhlopkova, I.V. Smolyaninov, G.K. Fukin, 2017, published in Koordinatsionnaya Khimiya, 2017, Vol. 43, No. 12, pp. 744–753.
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Poddel’sky, A.I., Arsen’ev, M.V., Okhlopkova, L.S. et al. New catecholate complexes of triphenylantimony(V) based on 6-iminomethyl-3,5-di-tert-butylpyrocatechols N-functionalized by the aniline or phenol group. Russ J Coord Chem 43, 843–851 (2017). https://doi.org/10.1134/S1070328417120089
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DOI: https://doi.org/10.1134/S1070328417120089