Abstract
A method for determining the gas chromatographic retention indices of structural isomers of compounds of tetracoordinated phosphorus, based on the correlation between chemical shifts in 13C nuclear magnetic resonance (NMR) spectra and the retention indices of the structural isomers, and on the theory of intermolecular interactions, is proposed. The capabilities of the method are demonstrated for structural isomers of O-alkylmethylfluorophosphonates, which are typical representatives of compounds from the class of tetracoordinated phosphonates. The results from using the correlation approach are compared to experimental data.
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References
I. G. Zenkevich, J. Anal. Chem. 56, 806 (2001).
A. G. Prudkovskii and A. M. Dolgonosov, J. Anal. Chem. 63, 852 (2008).
R. I. Sidorov, L. S. Romanenko, and S. A. Reznikov, Zh. Fiz. Khim. 51, 2913 (1977).
K. Panneerselvam, M. P. Antony, T. G. Srinivasa, and P. R. Vasudeva Rao, Thermochim. Acta 51, 107 (2010).
V. I. Maistrenko, R. Z. Khamitov, and G. K. Budnikov, Ecological and Analytical Monitoring of Superecotoxicants (Khimiya, Moscow, 1996), p. 235 [in Russian].
I. V. Rybal’chenko, Ross. Khim. Zh. 51(2), 101 (2007).
V. V. Vazhev and M. K. Aldabergenov, Russ. J. Appl. Chem. 78, 453 (2005).
A. M. Dolgonosov, Russ. J. Phys. Chem. A 72, 91 (1998).
A. V. Kiselev, Intermolecular Interactions in Adsorption and Chromatography (Vyssh. Shkola, Moscow, 1986) [in Russian].
A. M. Dolgonosov, Electron Gas Model and Theory of Generalized Charges for Description of Interatomic Forces and Adsorption (Librokom, Moscow, 2009) [in Russian].
I. G. Kaplan, Introduction to the Theory of Molecular Interactions (Nauka, Moscow, 1982) [in Russian].
A. N. Vereshchagin, Polarizability of Molecules (Nauka, Moscow, 1980) [in Russian].
A. N. Vereshchagin, Characteristics of Anisotropy of Molecular Polarizability (Nauka, Moscow, 1982) [in Russian].
Ch. Reichardt, Solvents and Solvent Effects in Organic Chemistry (Wiley, Weinheim, 2003), p. 468.
J. W. Emsley, J. Feeney, and L. H. Sutcliffe, High Resolution Nuclear Magnetic Resonance Spectroscopy (Pergamon, Oxford 1966; Mir, Moscow, 1982).
B. Howard, B. Linder, and T. Merle, J. Chem. Phys. 36, 485 (1962).
V. I. Minkin, Molecular Structure Theory (Electron Shells) (Vyssh. Shkola, Moscow, 1979) [in Russian].
R. M. Aminova, E. R. Martynchuk, and G. M. Galiullina, in Proceedings of the 24th Conference on Modern Chemical Physics (2012), p. 143.
R. M. Aminova, A. V. Aganov, and E. R. Martynchuk, Uch. Zap. Kazan. Gos. Univ., Ser. Fiz. Mat. Nauki 154 5 (2012).
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Original Russian Text © A.K. Zhokhov, P.V. Fomenko, A.M. Aparkin, E.B. Belousov, 2015, published in Zhurnal Fizicheskoi Khimii, 2015, Vol. 89, No. 1, pp. 116–120.
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Zhokhov, A.K., Fomenko, P.V., Aparkin, A.M. et al. Relationship between gas chromatographic retention indices and chemical shifts in the 13C NMR spectra of structural isomers of compounds of tetracoordinated phosphorus. Russ. J. Phys. Chem. 89, 125–128 (2015). https://doi.org/10.1134/S0036024415010331
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DOI: https://doi.org/10.1134/S0036024415010331