Abstract
The reaction between zinc(II) acetate dihydrate and ((1H-indol-3-yl)methylene)-N-methylhydrazinecarbothioamide (L) in methanol results in the formation of Zn(II) complex [Zn(C11H11N4S)2] (1). The complex is characterized by CHNS and various spectroscopic analyses. The structure of the complex is determined by the single crystal X-ray diffraction technique. XRD reveals that the Zn(II) complex crystallizes in the triclinic system with the P-1 space group and has a distorted tetrahedral geometry. Two ligand molecules are coordinated to the Zn(II) ion in the bidentate monobasic (NS−) fashion.
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I. E. Dreosti. Mutat. Res., 2001, 475, 161–167.
A. S. Prasad. J. Am. Coll. Nutr., 1998, 17, 542–543.
A. S. Prasad and O. Kucuk. Cancer Metastasis Rev., 2002, 21, 291–295.
A. S. Prasad. Br. Med. J., 2003, 326, 409–410.
T. M. Bray and W. J. Bettger. Free Radie Biol. Med., 1990, 8, 281–291.
S. R. Powell. J. Nutr., 2000, 130, 1447S–154S.
A. Tarushi, P. Kastanias, C. P. Raptopoulou, V. Psycharis, D. P. Kessissoglou, A. N. Papadopoulos, and G. Psomas. J. Inorg. Biochem., 2016, 163, 332–345.
C. P. Larson, U. R. Saha, and H. Nazrul. PLoS Med., 2009, 6, e1000175.
E. C. Fusch and B. Lippert. J. Am. Chem. Soc., 1994, 116, 7204–7209.
J. d’Angelo, G. Morgant, N. E. Ghermani, D. Desmaele, B. Fraisse, F. Bonhomme, E. Dichi, M. Sghaier, Y. Li, Y. Journaux, and J. R. J. Sorenson. Polyhedron, 2008, 27, 537–546.
H. Sakurai, Y. Kojima, Y. Yoshikawa, K. Kawabe, and H. Yasui. Coord. Chem. Rev., 2002, 226, 187–198.
Q. Zhou, T. W. Hambley, B. J. Kennedy, P. A. Lay, P. Turner, B. Warwick, J. R. Biffin, and H. L. Regtop. Inorg. Chem., 2000, 39, 3742–3748.
N. C. Kasuga, K. Sekino, M. Ishikawa, A. Honda, M. Yokoyama, S. Nakano, N. Shimada, C. Koumo, and K. Nomiya. J. Inorg. Biochem., 2003, 96, 298–310.
Z. Li, F. Wu, Y. Gong, C. Hu, Y. Zhang, and M. Gan. Chin. J. Chem., 2007, 25, 1809–1814.
Z. Chen, R. Xiong, J. Zhang, X. Chen, Z. Xue, and X. You. Inorg. Chem., 2001, 40, 4075–4077.
M. P. Lopez-Gresa, R. Ortiz, L. Perello, J. Latorre, M. Liu-Gonzalez, S. Garcia-Granda, M. Perez-Priede, and E. Canton. J. Inorg. Biochem., 2002, 92, 65–74.
D. Xiao, E. Wang, H. An, Z. Su, Y. Li, L. Gao, C. Sun, and L. Xu. Chem. Eur. J., 2005, 11, 6673–6686.
A. Tarushi, K. Lafazanis, J. Klun, I. Turel, A. A. Pantazaki, G. Psomas, and D. P. Kessissoglou. J. Inorg. Biochem., 2013, 121, 53–65.
A. Tarushi, Z. Karaflou, J. Kljun, I. Turel, G. Psomas, A. N. Papadopoulos, and D. P. Kessissoglou. J. Inorg. Biochem., 2013, 128, 85–96.
A. Tarushi, X. Totta, A. Papadopoulos, J. Kljun, I. Turel, D. P. Kessissoglou, and G. Psomas. Eur. J. Med. Chem., 2014, 74, 187–198.
J. S. Casas, E. E. Castellano, M. D. Couce, J. Ellena, A. Sanchez, J. Sordo, and C. Taboada. J. Inorg. Biochem., 2006, 100, 124–132.
Z. Travnicek, V. Krystof, and M. Sipl. J. Inorg. Biochem., 2006, 100, 214–225.
M. Di Vaira, C. Bazzicalupi, P. Orioli, L. Messori, B. Bruni, and P. Zatta. Inorg. Chem., 2004, 43, 3795–3797.
A. K. McCall, H. Chih-chin, and C. A. Fierke. J. Nutr, 2000, 130, 1437S–1446S.
J. Osredkar and N. Sustar. J. Clinic Toxicol., 2011, S3, 1–18.
R. Donovick, F. Pansy, G. Stryker, and J. Bernstein. J. Bacteriol., 1950, 59, 667–674.
G. Domagk, R. Behnisch, F. Mietzsch, and H. Schmidt. Naturwissenschaften, 1946, 33, 315.
A. E. Liberta and D. X. West. Biometals, 1992, 5, 121–126.
D. L. Klayman, J. F. Bartosevich, T. S. Griffin, C. J. Mason, and J. P. Scovill. J. Med. Chem., 1979, 22, 855–862.
D. Hamre, J. Bernstein, and R. Donovick. Proc. Soc. Exp. Bio. Med., 1950, 73, 275–278.
C. Shipman Jr., S. H. Smith, J. C. Drach, and D. L. Klayman. Antiviral Res., 1986, 6, 197–222.
K. A. Brownlee and D. Hamre. J. Bacterio!, 1951, 61, 127–134.
R. W. Brockman, J. R. Thomson, M. J. Bell, and H. E. Skipper. Cancer Res., 1956, 16, 167–170.
T. S. Lobana, R. Sharma, G. Bawa, and S. Khanna. Coord. Chem. Rev., 2009, 253, 977–1055.
A. A. Ibrahim, H. Khaledi, P. Hassandarvish, H. M. Ali, and H. Karimian. Dalton Trans., 2014, 43, 3850–3860.
J. Haribabu, K. Jeyalakshmi, Y. Arun, N. S. P. Bhuvanesh, P. T. Perumal, and R. Karvembu. J. Biol. Inorg. Chem., 2017, 22, 461–480.
J. Haribabu, G. Sabapathi, M. Muthu Tamizh, C. Balachandran, N. S. P. Bhuvanesh, P. Venuvanalingam, and R. Karvembu. Organometallics, 2018, 37, 1242–1257.
J. Haribabu, M. Muthu Tamizh, C. Balachandran, Y. Arun, N. S. P. Bhuvanesh, A. Endo, and R. Karvembu. New J. Chem., 2018, 42, 10818–10832.
APEX3 “Program for Data Collection on Area Detectors” BRUKER AXS Inc., 5465 East Cheryl Parkway, Madison, WI 53711-5373 USA.
G. M. Sheldrick. TWINABS. “Program for Absorption Correction of Area Detector Frames”, BRUKER AXS Inc., 5465 East Cheryl Parkway, Madison, WI 53711-5373 USA.
G. M. Sheldrick. Acta Crystallogr., 2008, A64, 112–122.
G. M. Sheldrick. Acta Crystallogr., 2015, A71, 3–8.
G. M Sheldrick. Acta Crystallogr., 2015, C71, 3–8.
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard, and H. Puschmann. J. Appl. Cryst., 2009, 42, 339–341.
K. N. Anees Rahman, J. Haribabu, C. Balachandran, N. S. P. Bhuvanesh, R. Karvembu, and A. Sreekanth. Polyhedron, 2017, 135, 26–35.
P. Murrayrust, H. B. Burgi, and J. D. Dunitz. J. Am. Chem. Soc., 1975, 97, 921–922.
S. Keinan and D. Avnir. J. Chem. Soc. Dalton Trans., 2001, 6, 941–947.
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CCDC 1907485 contains the supplementary crystallographic data for 1. These data can be downloaded free of charge form the Cambridge Crystallographic Data Center viawww.ccdc.cam.ac.uk/datarequest.cif or from the Cambridge Crystallographic Data Centre (CCDC), 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44(0)1223-336033 or e-mail: deposit@ccdc.cam.ac.uk.
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Text © The Author(s), 2020, published in Zhurnal Strukturnoi Khimii, 2020, Vol. 61, No. 1, pp. 71–77.
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Haribabu, J., Priyarega, S., Bhuvanesh, N.S.P. et al. Synthesis and Molecular Structure of the Zinc(II) Complex Bearing an N, S Donor Ligand. J Struct Chem 61, 66–72 (2020). https://doi.org/10.1134/S0022476620010072
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DOI: https://doi.org/10.1134/S0022476620010072