Abstract
The reaction between pyridine-2-carbaldehyde and zinc chloride in wet MeCN yielded a zinc chelate complex with hemiacetal formed in situ from the hydrated pyridine-2-carbaldehyde and the second molecule of pyridine-2-carbaldehyde. According to X-ray diffraction data, the pentacoordinated environment of the zinc ion is formed by two chlorine atoms and the N,N',O-tridentate ligand. In the crystal, molecules are combined into a 3D supramolecular framework due to the intermolecular hydrogen bonds O–H···Cl, C–H···Cl, and π–π stacking interactions between pyridine rings.
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References
A. Kleemann, J. Engel, B. Kutscher, and D. Reichert, Pharmaceutical Substances: Syntheses, Patents, Applications of the Most Relevant APIs (Thieme, Stuttgard/New York, 2008).
C. M. Alvarez, R. García-Rodrígues, and D. Miguel, J. Chem. Soc., Dalton Trans., 3546 (2007).
W. Wang, B. Springler, and R. Alberto, Inorg. Chim. Acta 355, 386 (2003).
G. Annibale, G. Marangoni, B. Pitteri, et al., Trans. Met. Chem. 25, 485 (2000).
V. Bertolasi, G. Annibale, G. Marangoni, et al., J. Coord. Chem. 56, 397 (2003).
V. E. Alvarez, R. J. Allen, T. Matsubara, and P. C. Ford, J. Am. Chem. Soc. 96, 7686 (1974).
A. E. El-Hilaly and M. S. El-Ezaby, J. Inorg. Nucl. Chem. 38, 1533 (1976).
R. H. Prince and P. Wyeth, J. Inorg. Nucl. Chem. 43, 845 (1981).
A. M. Guidote, K.-I. Ando, Y. Kurusu, et al., Inorg. Chim. Acta 314, 27 (2001).
M. G. B. Drew, S. Nag, P. K. Pal, and D. Datta, Inorg. Chim. Acta 361, 2562 (2008).
K. C. Mondal, O. Sengupta, and P. S. Mukherjee, Inorg. Chem. Commun. 12, 682 (2009).
K. J. Franz, Curr. Opin. Chem. Biol. 17, 143 (2013).
R. H. Prince, J. Inorg. Nucl. Chem. 43, 839 (1981).
B. Müller and H. Vahrenkamp, Eur. J. Inorg. Chem., 137 (1999).
J.-L. Liu, Y.-C. Chen, Q.-W. Li, et al., Chem. Commun. 49, 6549 (2013).
G. M. Sheldrick, Acta Crystallogr., Sect. A 64, 112 (2008).
A. W. Addison, T. N. Rao, J. Reedijk, et al., J. Chem. Soc., Dalton Trans., 1349 (1984).
J. M. Li, Acta Crystallogr., Sect. E 64, m1468 (2008).
J. Emsley, The Elements (Clarendon Press, Oxford, 1991).
Y. Pocker and J. E. Meany, J. Am. Chem. Soc. 89, 631 (1967).
Yu. M. Shapiro, Russ Chem. Rev. 60 1035 (1991). https://doi.org/10.1070/RC1991v060n09ABEH001127
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Original Russian Text © L.A. Grishchenko, L.N. Parshina, M.Ya. Khil’ko, V.I. Smirnov, T.N. Borodina, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 7, pp. 839–844.
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Grishchenko, L.A., Parshina, L.N., Khil’ko, M.Y. et al. Synthesis, Molecular, and Crystal Structure of a Complex of Pentacoordinated Zinc with Chloride Ions and Pyridine-2-Carbaldehyde Hemiacetal. Russ. J. Inorg. Chem. 63, 881–886 (2018). https://doi.org/10.1134/S0036023618070082
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DOI: https://doi.org/10.1134/S0036023618070082