Abstract
The equilibrium pressure-volume-temperature properties and thermoelastic behavior of kaolin-filled composites of the injection molding grade of high density polyethylene (HDPE) were studied in the temperature interval 423–473 K and in thepressure range 30–100 MPa. It was established that the HDPE melts in filled composites existed in a somewhat expanded, more compressible state. This effect was quantitatively accounted for by the increased number of external degrees of freedom derived from the Simha-Somcynsky equation of state. The effect of the coupling agent on thermal diffusivities and specific heat capacities of filled samples turned out negligibly small.
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R. Walter, K. Friedrich, V. P. Privalko and A. Savadori, J. Adhesion, 64 (1997) 87.
V. P. Privalko, F. J. Balta Calleja, D. I. Sukhorukov, E. G. Privalko, R. Walter and K. Friedrich, J. Mater. Sci., 34 (1999) 497.
V. P. Privalko, D. I. Sukhorukov, E. G. Privalko, R. Walter, K. Friedrich and F. J. Balta Calleja, J. Appl. Polymer Sci., 73 (1999) 1041.
E. G. Privalko, A. V. Pedosenko, V. P. Privalko, R. Walter and K. Friedrich, J. Appl. Polymer Sci., 73 (1999) 1267.
V. P. Privalko, F. J. Balta Calleja, D. I. Sukhorukov, E. G. Privalko, R. Walter and K. Friedrich, J. Macromol. Sci. Phys., (in press).
V. P. Privalko, V. V. Korskanov, E. G. Privalko, R. Walter, K. Friedrich and F. J. Balta Calleja, J. Therm. Anal. Cal., (submitted for publication).
V. P. Privalko, G. E. Yarema, Yu. D. Besklubenko and G. V. Titov, in: ‘Physical Methods of Polymer Characterization’ (Ed. V. P. Privalko), Naukova Dumka, Kyiv 1981, p. 107 (in Russian).
A. V. Shmorgun, PhD Thesis, Institute of Macromolecular Chemistry, National Academy of Sciences of Ukraine, Kyiv 1993.
G. E. Yarema, PhD Thesis, Institute of Macromolecular Chemistry, National Academy of Sciences of Ukraine, Kyiv 1993.
V. P. Privalko and A. V. Shmorgun, J. Thermal Anal., 38 (1992) 1257.
V. P. Privalko and V. V. Korskanov, J. Therm. Anal. Cal., 55 (1999) 741.
A. G. Shashkov, G. M. Volokhov and T. N. Abramenko, ‘Techniques for Measurements of Heat Conductivity and Thermal Diffusivity’ (Ed. A. V. Lykov), Energhia, Moscow 1973 (in Russian).
O. Olabisi and R. Simha, Macromolecules, 8 (1975) 206, 211.
H. S. Katz and J. V. Milewski, ‘Handbook of Fillers for Plastics’, Van Norstrand-Reinhold, New York 1987.
D. R. Lide (Ed.), ‘CRC Handbook of Chemistry and Physics’ (76th Edition), CRC Press, Boca Raton 1997.
R. Simha and T. Somcynsky, Macromolecules, 2 (1969) 342.
V. P. Privalko, ‘Properties of Bulk Polymers’ (Vol. 2 in ‘Handbook of Physical Chemistry of Polymers’, Ed. Yu. S. Lipatov); Naukova Dumka, Kyiv 1984 (in Russian).
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Privalko, V.P., Korskanov, V.V., Privalko, E.G. et al. Composition-Dependent Properties of Polyethylene/Kaolin Composites: VI. Thermoelastic behavior in the melt state. Journal of Thermal Analysis and Calorimetry 59, 509–516 (2000). https://doi.org/10.1023/A:1010149726679
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DOI: https://doi.org/10.1023/A:1010149726679