Abstract
The valence photoisomerization of four aromatic norbornadiene (NBD)derivatives has been studied in ethanol and in 0.01 M β-cyclodextrin(β-CD) water–ethanol (v/v, 99/1) solution (WECD). Observedfirst-order rate constants are found to be of the same order of magnitude inethanol and WECD, ranging between 0.1 and 0.28 s-1, accordingto the compound. These photoisomerization kinetic properties are attributedto the formation of inclusion complexes between NBDs and β-CD. Thestoichiometry is 1 : 1, and association constants ranging between 310 and390 M-1 have been determined fluorimetrically, usingBenesi–Hildebrand plots and a nonlinear regression method. Thestructure of the inclusion complexes is discussed on the basis of AMIsemiempirical dimension calculations and photophysical properties.
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Maafi, M., Aaron, JJ. & Lion, C. Effect of the Formation of Inclusion Complexes With β-Cyclodextrin on the Photoisomerization and Fluorescence Properties of Aromatic Norbornadiene Derivatives. Journal of Inclusion Phenomena 30, 227–241 (1998). https://doi.org/10.1023/A:1007908709056
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DOI: https://doi.org/10.1023/A:1007908709056