Abstract
The synthesis and characterization of CoII, NiII, CuII and CdII complexes with 2-furfuralsemicarbazone (FSC) and 5-methyl 2-furfuralsemicarbazone (MFSC) are reported. These ligands lead to the complexes: [ML2X2] or [MLX2] (L = FSC or MFSC) whose structures were determined using elemental analysis, molar conductivity, magnetic measurements, i.r., far i.r. and electronic spectra as well as by n.m.r. FSC and MFSC act as bidentate ligands in most of the CoII, NiII, CuII and CdII complexes. MFSC is a monodentate ligand in [NiBr2(MFSC)4].
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
G. Ibrahim, M. A. Khan, P. Richomme, O. Benali-Baïtich and G. Bouet, Polyhedron, 16, 3455 (1997).
G. Bouet and J. Dugué, Transition Met. Chem., 15, 257 (1990).
G. Bouet, G. Ibrahim and M. A. Khan, Transition Met. Chem., 19, 135 (1994).
N. Kanoongo, R. Shingh and J. P. Tandon, Transition Met. Chem., 13, 343 (1988).
A. Garg and J.P. Tandon, Transition Met. Chem., 12, 212 (1987).
K. K. Aravindaksan and K. Muraleedharan, Reactivity of Solids, 8, 91 (1990).
V. G. Puranik, S. S. Tavale, T. N. Gururow, P. Umapathy and P. Budhkar, Acta Crystallog., Sect. C, 43, 2303 (1987).
J. M. Cano Pavon and F. Cino, Talanta, 20, 339 (1973).
M. M. Bekheit, K. M. Ibrahim and T. H. Rakha, Bull. Soc. Chim. Fr., 6, 785 (1989).
A. Kumar, and S. Chandra, Synth. React. Inorg. Met-Org. Chem., 23, 671 (1993).
L. P. Battaglia, M. B. Ferrari and R. Boggia, Inorg. Chim. Acta, 215, 85 (1994).
B. Beecroft, M. J. M. Campbell and R. J. Grzeskowiak, J. Inorg. Nucl. Chem., 36, 55 (1974).
N. T. Akinchan, R. Akinchan D. X. West and Y. Yang, Transition Met. Chem., 19, 135 (1994).
R. Raina and T. S. Srivastava, Indian J. Chem., 22A, 701 (1983).
P. S. Patel, R. M. Ray, and M. M. Patel, Indian J. Chem., 32A, 597 (1993).
I. H. Hall, C. Lee, G. Ibrahim, M. A. Khan and G. Bouet, Appl. Organometal. Chem., 11, 565 (1997).
I. H. Hall, S. Y. Chen, K. G. Rajendran and D. X. West, Appl. Organometal. Chem., 10, 485 (1996).
D. X. West, J. J. Ingram, N. M. Kozub, G. A. Bain and A. E. Liberta, Transition Met. Chem., 21, 213 (1996).
D. X. West, N. M. Kozub and G. A. Bain, Transition Met. Chem., 21, 52 (1996).
D. X. West, M. A. Lockwood, A. E. Liberta, X. Chen and R. D. Willet, Transition Met. Chem., 18, 221 (1993).
W. J. Geary, Coord. Chem. Rev., 7, 81 (1971).
A. N. Singh, R. P. Singh, J. G. Mohanty, A. Chakravorty, Inorg. Chem., 16, 2597 (1977).
J. R. Ferraro, Low-Frequency Vibrations of Inorganic and Coordination Compounds, Plenum Press, New-York, 1971.
E. König, Structure and Bonding (Berlin), 9, 175 (1971).
A. B. P. Lever, Inorganic Electronic Spectroscopy, Elvesier, Amsterdam, 1968.
M. A. Khan and M. J. Schwing-Weill, Inorg. Chem., 15, 2202 (1976).
Handbook of Chemistry and Physics, 69th edition, CRC Press, Boca Raton (1988–89), F164.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Ibrahim, G., Chebli, E., Khan, M.A. et al. Metallic complexes from 2-furaldehyde semicarbazone and 5-methyl-(2-furaldehyde) semicarbazone. Transition Metal Chemistry 24, 294–298 (1999). https://doi.org/10.1023/A:1006980908726
Issue Date:
DOI: https://doi.org/10.1023/A:1006980908726