Introduction

For over 170 years, mercury (Hg) has been utilized as a dental amalgam for teeth filling in dentistry. Based on the World Health Organization (WHO) report, the highest human exposure to mercury is from dental amalgams. Extensive use of mercury in dentistry has resulted in the release of hundreds of tons of mercury into discharge systems, which can generate ionic mercury. The most toxic form of mercury is in its ionic species which mercury ions react with the biomolecules of a living being body and form very stable toxic bio-compounds [1,2,3,4]. Given these worrying statistics, how Hg(II) ions are removed from wastewater is a significant concern worldwide. Nowadays, various technologies have been put forward to remove Hg(II) ions such as biological treatment, precipitation, chemical reduction, ion-exchange, extraction, electrolytic accumulation, filtration, membrane technique, and adsorption methods [5,6,7,8]. Among these methods, adsorption is more effective and practical than other techniques [9]. Therefore, the increasing use of adsorption techniques has necessitated the development of recyclable and cost-effective adsorbents for the better removal of Hg(II) ions from contaminated media.

In recent years, nanotechnology appears as a new innovative technology with excellent potential for wastewater treatment in the natural environment through more effective strategies than previously explored methods [10,11,12,13]. In this regard, nanoparticles have attracted researchers’ attention due to their interesting properties such as large specific surface area, low cost, high stability and very small size. Among the various types of nanoparticles, metal oxide nanoparticles such as tin oxide (SnO2) and zinc oxide (ZnO) nanoparticles exhibited good activity in wastewater treatment [14,15,16]. There are various physicochemical techniques for the fabrication of these nanoparticles including thermal reduction [17, 18], chemical vapor synthesis [19, 20], sol-gel [21, 22], radiation methods [23, 24], microemulsion techniques [25, 26], laser ablation [27, 28] and mechanical attrition [29, 30]. Most of these methods have shortcomings such as low purity, harsh reaction conditions, production of side products, and the use of complicated equipment, toxic solvents and hazardous chemicals. So, it is desirable to develop more cost-effective and environmental-friendly approaches for the synthesis of metal oxide nanoparticles under mild conditions. The green synthesis of nanoparticles using natural and renewable materials like plant extract has advantages such as milder and cleaner conditions, and avoidance of expensive organic solvents and hazardous reagents [16, 31, 32].

Teucrium polium belongs to the Lamiaceae family and their shrubs grow in North Africa, Asia and Europe. From a long time ago, Teucrium polium has been used to treat gastrointestinal diseases, inflammation, diabetes and rheumatism. The phytochemical studies have shown which the main constituent of this plant is flavonoids [33]. The presence of these compounds in Teucrium polium induces excellent reducing properties to it that makes Teucrium polium extract as an excellent reducing agent and green media for the synthesis of nanoparticles [34].

In both chemical and green synthesis of nanoparticles, the major problem is the agglomeration of nanoparticles because of their small size. One of the best methods to overcome this problem is use natural suitable supports for the deposition of metal oxide nanoparticles and formation of nanocomposites such as TiO2/zeolite [35], SnO2/bentonite [36], Fe3O4/starch [37], FeO/chitosan [38], ZnO/cellulose [39], ZnO/alginate [39], MnFe2O4/diatomite [40], gelatin/TiO2[41] and graphene oxide/ZnO [42]. If the purpose of synthesizing a nanocomposite is to absorb pollutants, it would be valuable to use a support that has high adsorption property.

In recent years, researchers were used many agricultural and biological waste materials such as rice husk [43], eggshell [44], Moringa pods [45], bamboo leaf powder [46], cashew nut shells [47] and palm oil fruit shells [48] as low-cost adsorbents for the removal of heavy metals from aqueous medium. The eggshell could be a right choice as support because of its intrinsic porous structure. The eggshell is a cheap and readily available bio-waste. It is particularly attractive for the synthesis of nanocomposites due to the formation of strong metal-protein bonds between the eggshell and nanoparticles [49].

Since our goal in this study is the adsorption of Hg(II) ions using nanoparticles, and due to the excellent performance of SnO2 and ZnO nanoparticles in the removal of contaminants from wastewater [14, 50], to benefit the fantastic properties of SnO2 and ZnO nanoparticles, we decided to the synthesis of SnO2-ZnO nanocomposites based on the principles of green chemistry. On the other, to prevent the agglomeration of nanoparticles, we selected eggshells as natural support for nanoparticles which itself acts as an efficient adsorbent. Therefore, we synthesized SnO2-ZnO-eggshell nanocomposites via a facile and non-toxic method using Teucrium polium extract as a renewable reducing agent and efficient stabilizer. Then, the activity of the SnO2-ZnO-eggshell nanocomposites was studied in the removal of Hg(II) ions from aqueous solution. The SnO2-ZnO-eggshell nanocomposites exhibited highly excellent catalytic performance in the adsorption of Hg(II) ions at room temperature. Moreover, the SnO2-ZnO-eggshell nanocomposites could be recovered three times without considerable loss of catalytic activity. To our knowledge, the green synthesis of SnO2-ZnO-eggshell nanocomposites has not been reported in the literature.

Experimental

Materials

The tin (II) chloride dehydrate (SnCl2.2H2O), zinc nitrate hexahydrate [Zn(NO3)2.6H2O] and mercury(II) chloride (HgCl2) were purchased from Sigma-Aldrich and Fluka companies. Teucrium polium plant was collected from the deserts of South Khorasan in Iran. The eggs were purchased from the local supermarket.

Characterization techniques

The crystal structure and composition of SnO2-ZnO-eggshell nanocomposites was studied by X-ray diffraction (XRD) on a Philips model PW 1800 X’pert diffractometer. The shape and particle size distribution of the SnO2-ZnO-eggshell nanocomposites were specified by Transmission Electron Microscopy (TEM- ZEISS EM900). Energy dispersive X-ray spectroscopy (EDS- ZEISS, EVO18) and scanning electron microscopy (SEM-ZEISS, EVO18) analyses were carried out to study the elemental composition and morphology of SnO2-ZnO-eggshell nanocomposites and other compounds. The concentration of Hg(II) in the solutions after adsorbent exposure was investigated by inductively coupled plasma-light emission spectroscopy (ICP-OES, ES-730).

Preparation of the Teucrium polium extract

The dried powder of Teucrium polium leaves (10 g) was refluxed using distilled water (100 mL) at 80 °C for 45 minutes. The Teucrium polium extract was filtered and used for the green synthesis of nanomaterials in the next steps.

Biosynthesis of SnO2 nanoparticles

The extract of Teucrium polium (50 mL) was dropped into a well-mixed solution of tin (II) chloride dihydrate (25 mL, 0.05 M) with constant stirring at laboratory temperature for 30 minutes. The resulting mixture was magnetostirred for another 30 minutes at 70 °C. In the following, the reaction mixture was cooled and the synthesized precipitates were centrifuged at 10,000 rpm and rinsed three times with double distilled water and dried at laboratory temperature. The biosynthesized nanocomposites were powdered using a mortar and placed in an electric furnace at 550 °C for 2 h.

Biosynthesis of ZnO nanoparticles

The extract of Teucrium polium (180 mL) was dropped into a well-mixed solution of zinc nitrate hexahydrate (25 mL, 1 M) with constant stirring at laboratory temperature for 30 minutes. The resulting mixture was magnetostirred for another 8 h at 70 °C. The continuing the steps were quite similar to the one mentioned above.

Biosynthesis of SnO2-ZnO-eggshell nanocomposites

The tin (II) chloride dihydrate solution (25 mL, 0.05 M), zinc nitrate hexahydrate (25 mL, 1 M), and crushed eggshell (1 g) was vigorously stirred for 30 minutes at laboratory temperature. The extract of the Teucrium polium (180 mL) was added drop-wise to the above well-mixed mixture for 30 minutes. The resulting mixture was magnetostirred for another 8 h at 70 °C. In the following, the reaction mixture was cooled and the synthesized precipitates were centrifuged at 10,000 rpm and rinsed three times with double distilled water and dried at laboratory temperature. The biosynthesized nanocomposites were powdered using a mortar and placed in an electric furnace at 550 °C for 2 h. The ZnO and SnO2 loading in SnO2-ZnO-eggshell nanocomposites was 1:0.05 (molar ratio ZnO:SnO2).

Adsorption experiments

All adsorption tests were carried out with three replicates to examine the adsorption properties of SnO2-ZnO-eggshell nanocomposites in the removal of Hg(II) from aqueous solutions. The experiments were done under different conditions such as pH values (2–7), initial metal concentration of Hg(II) ions (10-5000 mg.L− 1) and adsorbent amounts (0.001–0.05 g L− 1). The pH of solutions was adjusted using hydrochloric acid (HCl), sodium hydroxide (NaOH) solutions (0.1 M) and a pH-meter instrument (Metrohm, Switzerland). After the adsorption process, the SnO2-ZnO-eggshell nanocomposites were separated by centrifugation and the concentration of Hg(II) ions in the solution phase was analyzed using ICP-OES. The following equations were used to evaluate the adsorptive capacity (Qe, mg.g− 1) and the removal percentage (E, %) of mercury (II), respectively:

$${Q}_{e}= \frac{{(C}_{0}- {C}_{e}) V}{m}$$
$$E= \frac{{C}_{0}- {C}_{e}}{{C}_{0}} \times 100$$

In the above equations, C0 and Ce are the initial and equilibrium concentration concentrations of mercury (II) (mg.L− 1) in solution, respectively. V (L) is the solution volume, and m (g) is the SnO2-ZnO-eggshell nanocomposites dosage.

Desorption and regeneration studies

The desorption of Hg(II) was done using aqueous solutions of EDTA (0.05 M) as a suitable desorbing agent. After the adsorption process, the Hg(II) loaded nanocomposites were collected and agitated with the above desorbing agent (10 mL) for 5 h. Then the SnO2-ZnO-eggshell nanocomposites were separated from the solution, washed three times with deionized water, dried at laboratory temperature and used again in the adsorption-desorption process the next three cycles.

Results and discussions

The aqueous extract of Teucrium polium leaves was used as an eco-friendly medium to the synthesis of SnO2-ZnO-eggshell nanocomposites. The flavonoids in the extract of Teucrium polium leaves act as a green reducing agent and effectively reduced the Zn2+ and Sn2+ salt ions to Zn and Sn nanoparticles (Scheme 1). Also, the extract of Teucrium polium act as an efficient stabilizer and through the green reduction of Sn(II) and Zn(II) ions, were remarkably dispersed the formed nanoparticles in situ on the eggshell, and limited their agglomeration. The biosynthesized nanocomposites were finally obtained after calcination in an electric furnace at 550 °C for 2 h (Fig. 1). After the successful synthesis of SnO2-ZnO-eggshell nanocomposites, the biosynthesized nanocomposites were employed as a green adsorbent to removal Hg(II) ions (Fig. 2).

Scheme 1
scheme 1

The proposed mechanism for the green synthesis of Sn and Zn nanoparticles

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Fig. 1
figure 1

Schematics of the green synthesis procedure of SnO2-ZnO-eggshell nanocomposites using Teucrium polium

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Fig. 2
figure 2

Schematics of adsorption experiment of Hg ions using SnO2-ZnO-eggshell nanocomposites

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The characterization of SnO2-ZnO-eggshell nanocomposites

At first, to obtain information about the elemental composition of eggshell, SnO2 nanoparticles, ZnO nanoparticles, and SnO2-ZnO-eggshell nanocomposites was done energy-dispersive X-ray spectroscopy (EDX) analysis (Fig. 3). The presence of carbon, oxygen, calcium and sulfur elements was determined in the EDX spectrum of the eggshell (Fig. 3a). The EDX spectra of the SnO2 and ZnO nanoparticles were well indicated in the presence of tin, zinc and oxygen elements (Fig. 3b and c). The elements such as carbon and phosphorus with a low weight percentage in EDX spectra of the biosynthesized SnO2 and ZnO nanoparticles were detected that were related to the used Teucrium polium extract in the synthesis process of nanoparticles. The presence of all the above elements in the EDX spectrum of SnO2-ZnO eggshell nanocomposites indicated the successful synthesis of biosynthetic nanocomposites (Fig. 3d).

Fig. 3
figure 3

EDX spectra of (a) eggshell, (b) SnO2 nanoparticles, (c) ZnO nanoparticles and (d) SnO2-ZnO-eggshell nanocomposites

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To understand the occurred morphological changes in the surface of the eggshell, SEM images of eggshell and SnO2-ZnO-eggshell nanocomposites were recorded. As shown in Fig. 4a, eggshell is a macroporous network with interwoven fibers. Figure 4b shows the three-dimension structure of SnO2-ZnO-eggshell nanocomposites in which eggshell was wholly coated with SnO2 and ZnO nanoparticles.

Fig. 4
figure 4

SEM images of (a) eggshell and (b) SnO2-ZnO-eggshell nanocomposites

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The TEM image of SnO2-ZnO-eggshell nanocomposites demonstrated that biosynthesized nanocomposites have almost spherical morphology with homogeneous particle sizes in the range of 20–25 nanometer (Fig. 5).

Fig. 5
figure 5

TEM image of SnO2-ZnO-eggshell nanocomposites

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The XRD patterns of the synthesized SnO2-ZnO-eggshell nanocomposites were shown in Fig. 6. In the XRD pattern of eggshell, the strong and sharp peaks at 2θ = 29.45°, 36.04°, 39.49°, 43.03°, 47.76°, 48.65°, 57.55°, 60.89°, 64.67° and 68.99° could be indexed to (104), (110), (113), (202), (024), (116), (122), (214), (300) and (217) Bragg’s reflections of rhombohedral CaCO3 (JCPDS No. 00-002-0623) [51, 52]. To confirm the presence of SnO2 nanoparticles in the biosynthesized nanocomposite, the typical XRD pattern showed diffraction peaks at 26.59°, 33.88°, 37.95°, 51.78°, 54.76°, 61.89°, 64.76° and 65.98° corresponding to (110), (101), (200), (211), (220), (310), (112) and (301) respectively (JCPDS No. 01-072-1147) [53]. The diffraction peaks at 31.69°, 34.33°, 36.10°, 47.36°, 56.31°, 62.64°, 67.64° and 68.73° were consistent with (100), (002), (101), (102), (110), (103), (112) and (201) reflections of the hexagonal phase of ZnO nanoparticles (JCPDS No. 01-079-0208) [54]. All of these peaks showed that SnO2-ZnO-eggshell nanocomposites had been successfully prepared.

Fig. 6
figure 6

XRD pattern of SnO2-ZnO-eggshell nanocomposites

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Based on the obtained results from TEM and XRD analysis and the definition of nanocomposite (nanocomposite is a multiphase solid material where one of the phases has one, two or three dimensions of less than 100 nanometers [55]), the naming of the nanocomposite for the biosynthesized compound was correct.

The adsorption of Hg(II) ions using biosynthesized SnO2-ZnO-eggshell nanocomposites

Due to the undeniable toxicity of Hg(II) ions, in this work, the SnO2-ZnO-eggshell nanocomposites were employed as a green adsorbent for removal of Hg(II) ions. The influence of several operating parameters such as pH values, the dose of catalyst, initial metal concentration of Hg(II) ions, catalyst type, existing other ions on adsorption capacity of Hg(II) using SnO2-ZnO-eggshell nanocomposites was investigated.

Effect of pH

The pH value of solutions, in the adsorption process of pollutants, is one of the most significant parameters on adsorption capacity [12, 56]. Therefore, Hg(II) ions solution were prepared with different pH values (2, 3, 4, 5, 6 and 7) and their adsorption capacity was studied while other factors such as volume and concentration of the aqueous solution of HgCl2 (100 mL, 20 mg.L− 1), the dose of catalyst (0.05 g) and temperature (laboratory temperature) were constant. The adsorption capacities of Hg(II) ions in different pH values were found to be around 361.2-396.6 mg.g− 1 with the standard deviation of 11.6 mg.g− 1. As shown in Fig. 7a, the adsorption capacity of Hg(II) ions onto SnO2-ZnO-eggshell nanocomposites increased with increasing pH values first and then decreased slightly. At lower pH values, there are a large amount of H+ ions in the solution, and they can compete with Hg(II) ions for the active sites on the surface of SnO2-ZnO-eggshell nanocomposites and interfere in the adsorption process [57, 58]. When the pH values were more than 3, adsorption capacity was decreased because of the production of metal hydroxide of Hg(OH) 2 or Hg(OH)+ [59]. Therefore, the maximum adsorption capacity of Hg(II) ions was obtained at pH value of 3 and after that, all of the experiments was carried out at pH = 3. At pH values greater than 8, metal hydroxides start to precipitate and the adsorption studies are practically impossible. Also, the zeta potential was applied to investigate the charge type on the surface of SnO2-ZnO-eggshell nanocomposites in solutions with different pH values. The zeta potential values of SnO2-ZnO-eggshell nanocomposites were shown in Fig. 7b. The isoelectric point was obtained when the pH value was 3.76. SnO2-ZnO-eggshell nanocomposites have a positive charge when the pH value was less than 3.76 and have a negative charge when the pH value was higher than 3.76. The changes in the zeta potential of SnO2-ZnO-eggshell nanocomposites showed which the electrostatic adsorption was not the main adsorption mechanism of Hg(II) ions by the biosynthesized nanocomposites [60].

Fig. 7
figure 7

Effect of pH on (a) adsorption capacity of Hg(II) using SnO2-ZnO-eggshell nanocomposites (C0 = 200 mg.L− 1, dosage of catalyst = 0.05 g, t = 5 min, and T = 298 K) and (b) Zeta potential of SnO2-ZnO-eggshell nanocomposites

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Effect of dosage

The effect of dosage using newly SnO2-ZnO-eggshell nanocomposites on the removal percentage and the adsorption capacity of Hg(II) ions was studied under the optimum conditions (C0 = 200 mg.L− 1, pH = 3, t = 5 min, and T = 298 K) and the results were presented in Fig. 8. The selected dosages were 0.001, 0.005, 0.01, 0.025 and 0.05 g. The removal percentage of Hg(II) ions in different dosages was found to be around 84.91–99.15 mg.g− 1 with the standard deviation of 5.78 mg.g− 1. The obtained results showed that the removal percentage of Hg(II) ions increased with an increasing dose of SnO2-ZnO-eggshell nanocomposites, while adsorption capacity decreased. The increase in the adsorption percentage could be due to an increase in the number of available sites for adsorption of Hg(II) ions. However, in the case of a decrease in absorption capacity, it could be said with an increasing dose of SnO2-ZnO-eggshell nanocomposites, active sites of adsorbent increase but the content of Hg(II) ions and the solution volume remain constant. The obtained results in this field were consistent with those reported in previous papers [61].

Fig. 8
figure 8

Effects of dose of SnO2-ZnO-eggshell nanocomposites (C0 = 200 mg.L− 1, pH = 3, t = 5 min, and T = 298 K)

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Effect of initial concentration

To study the effect of Hg(II) ions concentration on adsorption capacity, SnO2-ZnO-eggshell nanocomposites (0.05 g) were immersed in solution (100 mL) at pH = 3 with initial Hg(II) ions concentrations of 100, 200, 500, 1000 and 5000 mg.L− 1, respectively. Then the solutions were stirred for 5 minutes. The adsorption capacities of Hg(II) ions in Hg(II) ions concentrations are found to be around 197.3-2229.7 mg.g− 1 with a standard deviation of 1110.6 mg.g− 1. The obtained results are exhibited in Fig. 9. It could be found when the initial Hg(II) ions concentration increased from 100 to 5000 mg.L− 1, the adsorption capacity of Hg(II) increased. The increase of the adsorption capacity was because of the increase in the driving force of the concentration gradient [62].

Fig. 9
figure 9

Effects of initial concentration of Hg(II) ions (dose of catalyst = 0.05 g, pH = 3, t = 5 min, and T = 298 K)

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Effect of catalyst type

To study the exact role of SnO2-ZnO-eggshell nanocomposites on the adsorption capacity of Hg(II), the adsorption of Hg(II) ions were performed in the presence of SnO2 nanoparticles, ZnO nanoparticles, eggshell and SnO2-ZnO-eggshell nanocomposites. The adsorption capacity of Hg(II) using SnO2 nanoparticles, ZnO nanoparticles, eggshell, and SnO2-ZnO-eggshell nanocomposites were obtained 372.44, 366.82, 345.98 and 396.6 mg.g− 1, respectively, after 5 minutes. Surprisingly, all the components of the SnO2-ZnO-eggshell nanocomposites were efficiently involved in the uptake of Hg(II) ions.

Effect of existing ions

The selectivity of SnO2-ZnO-eggshell nanocomposites for adsorption of Hg(II) ions was carried out using the mixed metal ion solutions containing Ag, Cu, Sn and Hg chloride salts. These metal ions were chosen because they were components of dental amalgam. The concentration of each ion, dose of catalyst and pH were set at 200 ppm, 0.05 g and 3. The adsorption capacities of the mixed metal ions solution were shown in Fig. 10. The adsorption capacities for Ag(I), Cu(II), Sn(II) and Hg(II) ions were 10.15, 39.78, 23.43 and 285.96 mg.g− 1, respectively, with the standard deviation of 131.3 mg.g− 1. The obtained results clearly showed that the SnO2-ZnO-eggshell nanocomposites have a higher selectivity for adsorption of Hg(II) ions than the other metal ions.

Fig. 10
figure 10

Effects of existing ions (C0 = 200 mg.L− 1, dose of catalyst = 0.05 g, t = 5 min, and T = 298 K)

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Comparison of the adsorption capacity with other adsorbents

To show the advantages of the SnO2-ZnO-eggshell nanocomposites in the present work, a comparative study was performed between the SnO2-ZnO-eggshell nanocomposites and other previously reported composites for the removal Hg(II). As shown in Table 1, among the reported composites, the highest adsorption capacity and shortest time in the removal of Hg(II) were obtained using SnO2-ZnO-eggshell nanocomposites. Furthermore, the present study showed that the SnO2-ZnO-eggshell nanocomposites were biosynthesized using the plant extract as a green reducing agent and safe stabilizing.

Table 1 Comparison of adsorption capacities of various composites for Hg(II)
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Reusability and stability of SnO2-ZnO-eggshell nanocomposites

To have a cost-effective adsorbent, it must be reused several times in the adsorption-desorption cycles. For the desorption process and removing adsorbed Hg(II) ions from the adsorbent, firstly, used SnO2-ZnO-eggshell nanocomposites were agitated with aqueous solutions of EDTA as a suitable desorbing agent. Then, SnO2-ZnO-eggshell nanocomposites were separated from the reaction mixture, washed three times with water, dried and reused at least three times without any significant loss in their adsorption performance (Fig. 11). Furthermore, the stability of reused SnO2-ZnO-eggshell nanocomposites was confirmed by TEM image (Fig. 12).

Fig. 11
figure 11

Hg(II) adsorption efficiency using SnO2-ZnO-eggshell nanocomposites in three consecutive cycles (C0 = 200 mg.L− 1, dose of catalyst = 0.05 g, t = 5 min, and T = 298 K)

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Fig. 12
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TEM image of reused SnO2-ZnO-eggshell nanocomposites after three times

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Conclusion

In this work, a simple procedure was described for the green synthesis of SnO2-ZnO-eggshell nanocomposites using teucrium polium extract as a naturally-sourced reducing agent and efficient stabilizer. The SnO2-ZnO-eggshell nanocomposites were characterized by EDX, SEM, TEM and XRD to study the chemical elemental composition, morphology and crystalline size of the biosynthesized nanocomposites. The SnO2-ZnO-eggshell nanocomposites were employed as an efficient adsorbent for the removal of Hg(II) ions. The influence of several parameters, including pH value, the dose of catalyst, initial metal concentration of Hg(II) ions, catalyst type, existing other ions on adsorption capacity of Hg(II) using SnO2-ZnO-eggshell nanocomposites were investigated. The obtained results confirmed the high ability of SnO2-ZnO-eggshell nanocomposites in the removal of Hg(II) from aqueous solution, so that after only 5 minutes, the removal percentage and adsorption capacity approached to 100% and 400 mg.g-1, respectively. The use of eggshell as a bio-waste and natural support not only prevented the aggregation of SnO2 and ZnO nanoparticles but also improved the adsorption activity of nanocomposite for efficient removal of Hg(II) ions. Furthermore, the SnO2-ZnO-eggshell nanocomposites showed higher selectivity for adsorption of Hg(II) ions than the other metal ions. Also, the SnO2-ZnO-eggshell nanocomposites could be recycled three times without considerable loss in their adsorption activity. The high stability and durability of SnO2-ZnO-eggshell nanocomposites during the adsorption process were confirmed by the comparison of the TEM image of the reused nanocomposites after three cycles with fresh ones. Generally, SnO2-ZnO-eggshell nanocomposites were the efficient and green-based adsorbent for the removal of Hg(II) ions. The present study includes diverse advantages such as eco-friendly protocol, optimal use of bio-waste materials, simple conditions and excellent adsorption capacities as same as short adsorption times.