Abstract
The partial inclusion complexes (ICs) between poly(L-lactic acid) (PLLA) with high molecular weight and β-cyclodextrin (CD) were prepared and characterized by 1H nuclear magnetic resonance spectra (1H NMR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and polarizing optical microscopy (POM), respectively. The thermal results demonstrated that the crystallization performance of ICs were significantly improved, and the decomposition temperature of ICs were increased compared with PLLA. The mechanical tests indicated that the mechanical performance of ICs was improved, and the β-CD-PLLA ICs exhibited a higher non-Newtonian effect than PLLA. The degradation rate for the partial ICs in phosphate buffer solution accelerated as the ratio of β-CD increased, meanwhile, the partial ICs had a good shape memory behavior. The wetting measurements suggested the hydrophilicity of ICs was also enhanced markedly in comparison with the bulk PLLA.
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Zhou, Y., Song, Y., Zhen, W. et al. The effects of structure of inclusion complex between β-cyclodextrin and poly(L-lactic acid) on its performance. Macromol. Res. 23, 1103–1111 (2015). https://doi.org/10.1007/s13233-015-3146-6
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DOI: https://doi.org/10.1007/s13233-015-3146-6