Abstract
We present major ion compositions for water samples from Jinshajiang, Lancangjiang, and Nujiang drainage basins of China, collected in a water-rich period. This was done to determine natural chemical weathering rates on the eastern Himalayan and Qinghai-Tibet Plateau (HQTP), where anthropogenic impacts are considered small. The major ion distribution of the mainstream samples primarily reflects the weathering of carbonates, which accounts for ~46 % of total cations in the samples of Lancangjiang and Nujiang. Evaporite dissolution prevailed in the mainstream samples of Jinshajiang, as evidenced by high total dissolved solids (TDS) (364–479 mg/L) and Cl, SO4, and Na-dominant major element composition. Silicate weathering contributed <16 % of total cations TDS in the studied rivers. Some samples of the Nujiang near the Tengchong Volcano showed distinctive silicate weathering signatures. Chemical erosion rates of carbonate were 22.5 and 42.7 t km−2 a−1 at Lancangjiang and Nujiang, respectively. At Jinshajiang, evaporite dissolution was important, with a weathering rate 29.5 t km−2 a−1. The contributions of silicate weathering to total dissolved materials were minor, with weathering rates of 1.8, 2.2, and 5.1 t km−2 a−1 at Jinshajiang, Lancangjiang, and Nujiang, respectively. Net CO2 consumption by silicate weathering was 96 × 103 mol km−2 a−1 on average, which is much less than values of the Indus, Ganges, and Brahmaputra draining the HQTP front, and the Amazon and Orinoco draining the Andes Mountains. However, total chemical denudation fluxes (including silicate, carbonate, and evaporite weathering) of the three rivers varied between 44.5 and 70.4 t km−2 a−1, higher than published global mean values. This may indicate more intense chemical denudation for the three rivers draining the HQTP than those in the other areas of the world.
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Introduction
The Himalayan and Qinghai-Tibet Plateau (HQTP) is called the “Water Tower of Asia,” because it is the source of the ten largest rivers in Asia, which are the water sources for ~40 % of global population (Huang et al. 2009). The Jinshajiang, Lancangjiang (Mekong), and Nujiang (Salween) regions (Three Rivers Region, TR R) make up a tectonically active region at the eastern margin of the HQTP (Hallet and Molnar 2001). Collision of the Indian and Eurasian plates led to several left-lateral strike-slip faults in the eastern HQTP, which produces extensional pull-apart basins and three steep valleys forming the TRR (Tapponnier et al. 1982; Holt et al. 1991; Wang and Burchfiel 2000). Topographic map or satellite images of the eastern HQTP reveals that the Jinshajiang, Lancangjiang and Nujiang run very close to each other, near the eastern Himalayan syntaxis through three steep narrow ravines in the upper and middle parts of the river system (Hallet and Molnar 2001). We investigate the effect of this unusual geomorphology and strong topographic relief on water chemistry composition and chemical weathering processes of the three rivers.
Studying chemical weathering processes in the TRR is meaningful because the “tectonics-weathering-climate” hypothesis suggests uplift of the HQTP as a major driver of Cenozoic cooling because it caused increases in chemical weathering ability of silicates and thereby enhanced CO2 drawdown from the atmosphere (Raymo and Ruddiman 1992). To test this hypothesis, rivers draining the HQTP have received considerable attention in recent years (e.g,. Gaillardet et al. 1999; Galy and France-Lanord 1999, 2001; Krishnaswami et al. 1999; Karim and Veizer 2000; Dalai et al. 2002; Oliver et al. 2003; Bickle et al. 2005; Singh et al. 2005; Moon et al. 2007; Hren et al. 2007; Wang et al. 2007; Wu et al. 2008; Noh et al. 2009; Jiang et al. 2015).
Geochemical data from the Ganges, Brahmaputra, and Indus originating on the southern flank of the Himalayas reveal that drainage basins of these rivers have greater chemical weathering rates than the average of the entire continent (e.g., Edmond 1992; Pande et al. 1994; Galy and France-Lanord 1999; Krishnaswami et al. 1999; Karim and Veizer 2000; Dalai et al. 2002; Bickle et al. 2003, 2005; Singh et al. 2005). Geochemical study on the upper Huang River indicates that silicate weathering and associated net CO2 consumption rates of the northeastern HQTP were lower than the Ganges–Brahmaputra (Wu et al. 2005). Qin et al. (2006) examined fluvial geochemistry of the Min River, one of the headwater tributaries of the Changjiang River (Yangtze). They concluded that carbonate weathering was important and had higher chemical weathering rate in the Min River basin than the average of the Changjiang basin. The drainage area of the above rivers draining the HQTP represents a small portion of the entire HQTP. Wu et al. (2008) studied chemical weathering of seven major rivers (Jinshajiang, Lancangjiang, Nujiang, Yalong River, Min River, Dadu River, and upper Huang River) draining the eastern HQTP. These seven rivers have much larger drainage area than that of the Ganges, Brahmaputra, and Indus draining the southern flank of HQTP. The results of that study demonstrated that silicate weathering rates are generally lower than in rivers draining the Himalayan front. Similar conclusions were obtained by a chemical weathering study of the TRR by Noh et al. (2009). They compared three rivers to other rivers originating on the HQTP and non-HQTP rivers draining major orogenic zones of the world, showing that chemical weathering and CO2 consumption rates of the three rivers were not significantly higher than those of other major rivers draining the Himalayan front and orogenic zones of the world.
Wu et al. (2008) selected only one sampling site, where each of the three aforementioned rivers flows down the plateau. Considering the potential effects of varying topography and geomorphology on water chemistry, data from one sampling site in each river may not be adequate to estimate chemical weathering in the entire drainage basins of the three rivers. Noh et al. (2009) estimated silicate weathering and CO2 consumption rates of the TRR. However, they collected some samples in lower reaches of the TRR, where the rivers flow through heavily populated plains and hence may be polluted by industrialized and agricultural activities. Therefore, the estimated chemical weathering may be inadequate because of considerable anthropogenic impacts. The authors did not estimate carbonate and evaporite weathering and corresponding CO2 consumption rates in the TRR. In the present study, we collected mainstream and tributary samples in the upper and middle reaches of the three rivers (Figs. 1, 2). The sampling areas have essentially no anthropogenic pollution. Major elemental compositions of the water samples were analyzed to estimate chemical weathering and CO2 consumption rates. We compared the three rivers to the results of Wu et al. (2008) and Noh et al. (2009), other rivers draining the HQTP, and rivers draining major orogenic zones of the world. Our study was aimed at in-depth understanding of major ion compositions and chemical weathering processes in the three river regions.
Study areas
The three rivers originate on the eastern margin of the HQTP and run towards the East China, South China, and Andaman seas, respectively. We mainly studied the upper and middle reaches of the rivers from their origin to their divergence in southwestern China (Fig. 1). The lithology of the studied basins was confirmed by the Geological Map of China (China Geological Survey 2004).
The Jinshajiang
As the headwater of the Changjiang River, the Jinshajiang has a length of ~2300 km. The drainage basin of Jinshajiang extends from 35°38′N 90°33′E to 25°97′N 104°64′E, with a total drainage area of 473,640 km2. The source of the Jinshajiang is the Tuotuo River, originating on the eastern side of the Tanggula Mountains, the main peak of Geladandong Snow Mountain at an elevation of 6621 m. From the source area of the Jinshajiang Basin to where it reaches the fluvial plain (average elevation ~500 m) of the Sichuan Basin after flowing down the plateau, the population density is low. The study area of the Jinshajiang Basin is composed mainly of carbonates, Paleozotic clastic rocks, igneous rocks (mainly granitoid intrusive, and volcanic), lower-grade metamorphic rocks, and evaporite-bearing Quaternary deposits (Fig. 2). Ophiolite mélanges within the suture zones of Jinshajiang largely consist of basic and ultrabasic rocks and limestones (Wang et al. 2000).
The Lancangjiang
The Lancangjiang drainage basin extends from 33°81′N 94°40′E to 21°75′N 101°15′E, with a total length of ~2160 km and a drainage area of 167,400 km2 in China. The Lancangjiang basin is sourced from rivers of Zaqu and Angqu, both rivers originate on the northern flank of the Tanggula Mountains. Below the source area, the Lancangjiang basin shows the main topographic features of high mountains, deep valleys and great changes of elevation, and has a very sparse population. In the lower reach, the Lancangjiang basin has less topographic changes and numbers of tributary increase. A famous tourist district called Xishuangbanna Dai Autonomous Prefecture is in the lower reach, in China’s Yunnan Province, and has a dense population. The study area is composed mainly of Paleozotic clastic rocks, carbonates, low-grade metamorphic rocks, and volcanic rocks with some metamorphic and plutonic rocks (Fig. 2).
The Nujiang
The Nujiang drainage basin extends from 33°30′N 91°52′E to 24°11′N 99°17′E, with an area of 136,000 km2 and a total length of ~2010 km in China. The source of Nujiang basin is the Naqu River, which originates on the southern flank of the Tanggula Mountains. Most of the Nujiang Basin in China is near the Lancangjiang. In the upper reach, the Nujiang basin has a relatively flat topography. In the middle reach of the river, most of the mountains on the two sides of Nujiang have elevations of ~5000 m. The Nujiang flows through orogenic belts, where the deeply cutting Gaoligong Mountain, Biluo Snow Mountain, and Nu Mountain of the Traverse Range form a great gorge district. The elevation rapidly declines after the river flows across the Traverse Range. From the source area to near the end of that range, the population density is very low. The studied basin largely consists of carbonates, Paleozotic clastic rocks, low-grade metamorphic rocks, volcanic rocks (basaltic volcanic and granitoid intrusive), and Precambrian high-grade metamorphic rocks (Fig. 2).
Overall, carbonates make up ~63 %, igneous rock ~13 %, clastic rock ~12 %, metamorphic rock ~9 %, and evaporite ~3 % of the lithologic compositions in the studied basins (Fig. 2). The Lincang Batholith, a large body of plutonic acid rock (mostly Paleozoic granites), is found in the area of lower Lancangjiang and Nujiang next to the Changning-Menglian Ophiolite Belt (Wu et al. 1995). The Tengchong Volcano (25°19′N, 98°28′E), which erupted in the year 1609, is near the last sampling site in Nujiang basin (Figs. 1, 2).
Climate, vegetation, and population
Annual mean air temperature of the TRR ranges from −7 to 16 °C, with an average of ~1 °C. The studied basins are influenced by the Asian monsoon, which brings heavy rainfall in summer. Mean annual precipitation in the TRR is ~560 mm, more than 60 % of which falls in summer (Noh et al. 2009). Drainage basins in the HQTP interior are very arid, with a mean annual potential evapotranspiration of 684 mm (Burbank et al. 2003; Noh et al. 2009). Mean annual runoff increases gradually downstream, with ~245 mm above 4000 m elevation and 600 mm below that elevation (Noh et al. 2009). Alpine steppe mixed with grassland is the dominant vegetation in areas above 4000 m elevation. In downstream areas, the dominant vegetation is alpine scrub meadow, mixed coniferous forest, and subtropical forest. Local people build the terraced fields on the steep slopes and potatoes, corn, beans and rice are cultivated depending on elevation of the slope (Weyerhaeuser et al. 2005). The TRR has an average population density of 29 km−2, which is low compared with the rest of China (Tian et al. 2006).
Sampling and analytical methods
Sampling
Discharge of the three rivers is greatly variable, seasonally and interannually. Time-series analyses of dissolved major element compositions at the Min River monitoring station showed that chemical weathering flux calculated using major ionic data during abundant water periods has the strongest agreement with annual time-series estimates (<±10 %) and poorest during water-scarce periods (up to 37 %) (Qin et al. 2006). Thus, we collected water samples in July and August 2013, corresponding to a water period (Table 1). Nine mainstream and six tributary samples were collected from the Jinshajiang Basin (Fig. 3), with an elevation ranging from >4200 to ~1200 m (Fig. 1). In Lancangjiang Basin, ten mainstream and three tributary samples were collected from upper-middle reaches (Fig. 3), with an elevation between 3863 and ~990 m (Fig. 1). Ten mainstreams and one tributary sample were collected in Nujiang Basin (Fig. 3). The elevation of sampling sites was between 2789 and ~688 m (Fig. 1). Between 15 and 20 L of river water was collected and filtered within 24 h of collection, using 0.45-μm cellulose acetate filters. The first liter was discarded and subsequent ones stored in acid-washed polyethylene bottles after filtering. Major cations were analyzed after acidification to pH 2 with ultrapure grade 1:1 nitric acid, and the filtered non-acidified samples were analyzed for major anions.
Analytical methods
pH and water temperature were measured in the field. Alkalinity was determined with the Gran titration method using 0.02 M HCl. Accuracies were ±0.01 in the determination of pH, ±0.1 (°C) for temperature, and ±0.01 (mL) for the amount of HCl consumed in the titration of alkalinity. Anions (Cl, SO4, and NO3) were measured by ionic chromatography with precision 5 %. Major cations (K, Na, Ca, and Mg) and silicic acid concentrations were determined by inductively coupled plasma optical emission spectrometry with precision better than 5 %. Reagent and procedural blanks were determined in parallel with sample treatment, and national standard reference materials of China (GBW(E)080118 for Ca, GBW(E)080126 for Mg, GBW(E)080127 for Na, GBW(E) 080125 for K, GBW(E)080272 for SiO2, GBW(E)082048 for Cl, GBW(E)082050 for SO4, and GBW(E)082049 for NO3) were used in the determination of cations and anions.
Results and discussion
General characteristics of water chemistry
Data of pH, water temperature, major ions, silica, and total dissolved solids (TDS) in the rivers are presented in Table 1. pH of river water samples were neutral to mildly alkaline (7.53–8.70), and water temperatures were 8.9–22.7 °C (Table 1). The pH values obtained in TRR water suggest that alkalinity is imparted primarily by bicarbonates, reflecting the intensity of water–rock interactions and weathering of carbonates. The temperature of river water reflects the elevations of the sampling sites.
Total cationic charge (TZ+ = K + Na + 2Ca + 2 Mg), as a measure of total dissolved content, was strongly variable, from 2188 to 6964 µEq L−1 in mainstream samples of the studied rivers (Table 1). This was within the range measured in the 61 largest rivers of the world (Gaillardet et al. 1999). The mean value of 3797 µEq L−1 was much larger than the estimated average of world rivers (TZ+ = 1125 µEq/L, Meybeck 2003), and larger than values of the Min River (TZ+ = 1300–4100 µEq L−1, Qin et al. 2006), Yalong River (TZ+ = 225–3974 µEq L−1, Li et al. 2014), Jialingjiang (TZ+ = 3708 µEq L−1, Li et al. 2011) and upper Xijiang (TZ+ = 3456 µEq L−1, Xu and Liu 2007), but smaller than a value reported for Wujiang River, which drains karst terrain (TZ+ = 4140 µEq L−1, Han and Liu 2004). The first two rivers and the studied rivers are all on the eastern HQTP and the last three rivers are in southwestern China.
The extent of TZ+–TZ− charge imbalance, characterized in terms of normalized inorganic charge balance (NICB = (TZ+–TZ−)/TZ+×100 %, where TZ− = HCO3 + Cl + NO3 + 2SO4 in µEq), was generally within ±10 % for most samples, indicating that TZ+ is balanced by the total anionic charge (TZ−) and that unanalyzed organic anions are only a minor component. As indicated in Table 1 and Figs. 1 and 2, samples with TZ+ >4000 µEq L−1 were from the Jinshajiang mainstream, and they show input from evaporite dissolution (high Na and Cl + SO4). Samples with TZ+ between 1000 and 4000 µEq L−1 were from Lancangjiang and Nujiang samples, showing dominant input from carbonate weathering.
TDS (mg L−1), expressed here as the sum of major inorganic species concentrations (Na + K + Ca + Mg + HCO3 + Cl + SO4 + NO3 + SiO2) of mainstream samples of the TRR, decreased from 196–479 mg L−1 above 2000 m elevation to 165–379 mg L−1 downstream, owing to dilution. There was a strong correlation between TDS and TZ+ (r 2 = 0.98, n = 39) for all samples.
Major ion distributions
Ternary diagrams of dissolved major elements effectively show a wide diversity of composition of all samples collected in the drainage basins (Fig. 4), which attests to the presence of diverse lithological components within the study area. As shown in anion ternary diagrams (Fig. 4a), most of the data concentrate near the HCO3 apex and lie along the HCO3–(SO4 + Cl) line, characteristic of carbonate–evaporite–sulfide weathering.
HCO3 is the dominant anion, ranging from 671 to 2520 μmol L−1 with a mean 1535 μmol L−1 for all water samples, constituting on average 64, 73, and 72 % of the anion budget in Jinshajiang, Lancangjiang, and Nujiang, respectively. Cl and SO4 are also important anions, accounting for >22 % of total anion composition in the three rivers. In tributary samples, the greatest HCO3 was observed in samples JT15 (1679 μmol L−1) and LT12 (1896 μmol L−1), and most HCO3 was basically balanced by Ca and Mg in the two samples [(Ca + Mg)/HCO3 = 0.51 and 0.49 for JT15 and LT12, respectively.]
On the cation ternary diagram (Fig. 4b), most of the samples cluster near the Ca apex and lie along the Ca–Mg line. Cationic composition of river water samples were mostly dominated by Ca, with the order Ca > Mg > Na > K. The concentration of Ca was 313–1185 μmol L−1 in the three rivers, with averages of 807, 957, and 676 μmol L−1 for Jinshajiang, Lancangjiang, and Nujiang, respectively. The concentration of Mg varied between 75 and 750 μmol L−1, accounting for more than 15 % (in μmol L−1) of total cation concentrations in river waters. Ca and Mg constituted >80 % of total cation concentrations in most of the samples. Na was the third most abundant cation, ranging from 58 to 672 μmol L−1, except for the Jinshajiang mainstream samples, representing >9 % in most of the river waters. The K concentration was relatively low over the entire basin, and is estimated to be ~3 % of total cation composition.
All these results generally demonstrate the dominance of carbonate weathering in the study basins. In the samples, significant correlation was observed between HCO3 and Ca (r 2 = 0.92, n = 30). An exception to this general ion distribution is Cl-, SO4-, and Na-dominant samples from the Jinshajiang mainstream. As seen in the ternary ion diagrams (Fig. 4), data points of those samples are more similar to the Cl + SO4 apex and K + Na apex. In these samples, Cl (in μmol L−1) makes up >36 % and SO4 >11 % of the total anion budget, and Na+ forms >52 % of the total cation budget. Fu et al. (1998) and Zhao et al. (2003) showed that the Chumar and Tuotuo Rivers, the two main tributaries of the Jinshajiang, have extremely high concentrations of Na and Cl (~10,000 μmol L−1), which is mainly attributed to weathering and dissolution of halite (Bureau of Geology and Mineral Resources of Qinghai Province 1990) and the contribution from saline lakes and hot springs in the drainage areas (Shui et al. 2006a, b). The Cl-, SO4-, and Na-dominant ion compositions may derive from extreme headwater tributaries in the source areas of the Jinshajiang. In the samples, significant correlation was observed between Na and Cl (r 2 = 0.94, n = 9).
Figure 5 shows the equivalent charge balance of Ca + Mg vs. HCO3 and vs. HCO3 + SO4, plus Ca + Na vs. HCO3 + Cl. In the tributary samples of the Jinshajiang, Lancangjiang, and Nujiang, HCO3 is basically balanced by Ca + Mg, and SO4 is not significant in the chemical equilibrium (Fig. 5a). However, for the mainstream samples of the three rivers, Ca + Mg was greater than HCO3 but smaller than HCO3 + SO4 (Fig. 5b), indicating measurable contribution from the dissolution of evaporite minerals (gypsum-salt layer) or oxidation of sulfide minerals such as pyrite (FeS2). The best correlation was between Ca + Na and HCO3 + Cl (r 2 = 0.98, n = 39) (Fig. 5c), and the data points were mostly on the [Ca + Na]:[HCO3 + Cl] = 1:1 line, indicating that HCO3 + Cl was well balanced by Ca + Na. This observation suggests that halite (NaCl) dissolution in addition to carbonate weathering and evaporite (mainly gypsum) dissolution is important in the equivalent charge balance of most river waters.
Sources of major ions in rivers
Dissolved ions in river water result from atmospheric inputs, anthropogenic inputs, weathering of silicate, carbonate and evaporates, and oxidation of sulfide minerals. Thus, for any element X in river water, the budget equation can be written as
where subscripts “carb”, “sil”, and “evap” represent inputs from weathering of carbonate, silicate, and evaporite, respectively. It is necessary to constrain the contributions from these sources to the dissolved load to derive chemical weathering rates and associated CO2 consumption within the basin.
Atmospheric inputs and anthropogenic contributions
Atmospheric input is typically considered to enhance the chemical composition of riverine water. To examine the lithologic origin of the dissolved load, one must first correct for that input. As shown by numerous research works, Cl, whose concentration is generally very low in carbonate and silicate rock, is the most commonly used element to evaluate the atmospheric contribution to the chemical composition of river water (Negrel et al. 1993; Xu and Liu 2007; Liu et al. 2013).
To determine atmospheric Cl inputs to the three rivers, we considered rivers that do not drain any saline formation or hydrothermal area (Rai et al. 2010). Lancangjiang tributary sample LT13 (collected at Yuquhe) had the lowest Cl concentration of 3.3 μmol L−1 (Table 1), and no salt-bearing rocks or hydrothermal areas were found by field observation and via knowledge of the river basin geology. We assumed that the sample of lowest Cl concentration (LT13, 3.3 μmol L−1) acquired its dissolved Cl exclusively from rain. The atmospheric contribution of element X (X = Ca, Mg, Na, K, and SO4) to river water can be derived from
where [X]rain is the contribution of element X from rain (μmol L−1) to rivers; [Cl]rain (=3.3 μmol L−1) is the atmospheric contribution of Cl to river water; and (X/Cl)rain is the molar ratio of element X over Cl in rainwater. X/Cl ratios in precipitation at three Tibetan towns that were volume-weighted means over 1998–2000 were used as (X/Cl)rain in the calculation (Zhang et al. 2003). These were Na/Cl = 4.17, Mg/Cl = 1.79, Ca/Cl = 16.06, K/Cl = 3.55, and SO4/Cl = 1.03. Rain percentages were calculated by dividing the sum of the cations from rain (∑cationrain = Narain + Krain + Carain + Mgrain = 49.1 μmol L−1) by \(({\sum {\text{cation}} })_{\text{river}}\).
Most of the sampling sites in the upper reaches of the Jinshajiang, Lancangjiang, and Nujiang are unaffected by industrial and agricultural activities and are far from densely populated areas (some areas are basically pristine). Direct anthropogenic contributions to their major ion budgets are consequently small. River nitrate concentrations, which are often used as an indicator of anthropogenic activities, were low (Table 1). Therefore, direct anthropogenic contamination is negligible.
Evaporite dissolution
According to the estimate of Meybeck (1987), the dissolution rate of evaporite is 40–80 times that of granites, and 4–7 times that of carbonate. Consequently, evaporite dissolution can significantly influence river chemistry, even if evaporite outcrops are sparse in a basin. Noh et al. (2009) showed that evaporite (halite plus gypsum/anhydrite) dissolution is important in the dissolved load of water samples in the three rivers.
In the present study, we estimated the contributions from evaporite (chloride and sulfate salts) after a rain correction. Assuming all Cl in river water remaining after that correction comes from halite (Clevap = Clriver − Clrain; Naevap = Clevap) and all SO4 from gypsum/anhydrite (SO4evap = SO4river − SO4rain; Caevap = SO4evap), we approximated the contribution to riverine cations from halite (Clevap/∑cationriver) and sulfate (SO4evap/∑cationriver) dissolution.
Silicate weathering
For cations, silicate weathering input to the dissolved Na and K mainly from aluminosilicate weathering and Ca and Mg mainly from calcium-magnesium silicate weathering in river water (Wu et al. 2008). We assumed that all Na remaining after rain and halite correction is silicate derived (Nasil = Nariver − Narain − Naevap) and that all dissolved K in the river after rain correction is from silicate (Ksil = Kriver − Krain).
The ratio Si/(Nasil + Ksil) is a proxy commonly related to the ‘‘intensity’’ of silicate weathering (Edmond et al. 1995). Here, Si represents the content of dissolved silicon, mainly originating from silicate weathering, and Nasil and Ksil represent the contents of Na and K from silicate weathering in the rivers. Si/(Nasil + Ksil) = 1.7 for weathering of average shield to kaolinite and 3.5 to gibbsite, and 1.0 for average shale to kaolinite and 3.4 to gibbsite (Huh et al. 1998). Most of the Si/(Nasil + Ksil) ratios were <1.7 (Fig. 6), indicating that silicate weathering in the Jinshajiang, Lancangjiang, and Nujiang basins is superficial, i.e., to cation-rich secondary minerals but not to kaolinite or gibbsite.
The contribution of Na in the rivers from carbonate weathering may be neglected (Dalai et al. 2002). On average, Nasil and Ksil together constitute only ~22 % of total cations in most river waters, suggesting that silicate weathering is not a major source of cations for the rivers at basin scale. Considering that there are other sources of Na such as borax, mirabilite, or trona in the evaporite deposits of the three river basins, correction for evaporites and rain using Clevap and Narain as indices can give an upper limit of Na from silicates.
Ca in river waters is mainly derived from carbonates, evaporites, and silicates, whereas sources for Mg are carbonates and silicates. In river waters, Ca and Mg derived from silicate weathering (Casil and Mgsil) can be obtained from Nasil and Ksil using appropriate (Ca/Na)sil and (Mg/K)sil molar ratios (Galy and France-Lanord 1999). The reliabilities of (Ca/Na)sil and (Mg/K)sil directly affect the proportion of dissolved cations resulting from silicate weathering, and this requires some care.
For estimating the silicate contributions of Ca and Mg to rivers in the Nepal Himalaya, values of 0.18–0.3 and 0.5 ± 0.2, respectively, for (Ca/Na)sil and (Mg/K)sil were used by Galy and France-Lanord (1999), which are based on (Ca/Na) in silicate composition of original rock in the Higher Himalaya (HH) and Lesser Himalaya (LH) and in plagioclase of the High Himalaya Crystalline (HHC). Based on (Ca/Na) in LH granites/gneisses, soil profiles, and rivers draining predominately silicates, Krishnaswami et al. (1999) used the values 0.7 ± 0.3 and 0.3 ± 0.2, respectively, for (Ca/Na)sil and (Mg/Na)sil. Dalai et al. (2002) used two values (0.7 ± 0.3 and 0.35 ± 0.15) for (Ca/Na)sil for estimation of Casil in the Yamuna Basin. Values of 0.7 and 0.3, respectively, for (Ca/Na) and (Mg/Na) in the silicate fraction in the Min River basin were used by Qin et al. (2006). (Ca/Na)sil = 0.2 and (Mg/Na)sil = 0.5 were used for the Wujiang and upper Xijiang basins (Xu and Liu 2007; Han and Liu 2004). Moon et al. (2007) assumed a Ca/Na of 0.44 and Mg/Na of 0.16 for silicate fraction in the Hong River drainage basin. Therefore, estimation of (Ca/Na)sil and (Mg/K)sil has considerable variability. For the large TRR, local bedrock has the wide variety ranging from acid plutonic rocks to basaltic ophiolite mélanges (Wang et al. 2000).
According to Blum et al. (1998), samples of riverbed sand can represent unweathered bedrock in the watershed. We used Ca/Na ratios measured in the silicate fraction of riverbed sediment as (Ca/Na)sil, which was measured and used by Wu et al. (2008) in a calculation of cation contributions from silicate weathering to seven rivers draining the eastern HQTP. According to Wu et al., the (Ca/Na)sil molar ratio of the silicate fraction of riverbed sediments was 0.40, 0.17, and 0.29 for Jinshajiang, Lancangjiang, and Nujiang, respectively. Similarly, the Mg contribution from silicate (Mgsil) in rivers can also be obtained using river Ksil to multiply the (Mg/K)sil molar ratio of the silicate fraction of riverbed sediments (Blum et al. 1998). The latter ratio was 0.84 for Jinshajiang, 0.50 for Lancangjiang, and 0.42 for Nujiang (Wu et al. 2008). Our values of (Ca/Na)sil in the three rivers are similar to other drainage basins in the HQTP and a common set of ratios for global river silicate end member composition of 0.35 ± 0.15 (Gaillardet et al. 1999).
According to the above values, the fraction of cation contributions from the silicates to the three rivers could be calculated as in Dalai et al. (2002):
Here, Nariver, Kriver, Cariver, and Mgriver represent total contents of each element in river waters, whereas Nasil, Ksil, Casil and Mgsil indicate elemental concentrations derived from the silicate fraction, and (Ca/Na)sil and (Mg/K)sil denote elemental molar ratios of silicate fraction in riverbed sediments.
Carbonate weathering
In many watersheds of the world, carbonate weathering is important in controlling river water chemistry, regardless of the major rock type or not in local area, because carbonate is more susceptible to weathering than silicate (Roy et al. 1999; Karim and Veizer 2000).
It has been observed during field work that carbonate rocks constitute a major lithology in the catchment basins of these rivers. HCO3 and Ca are the major anion and cation in the three rivers. Furthermore, compared with most major rivers in the world (Gaillardet et al. 1999), the three river samples are characterized by higher alkalinity, implying that the contribution from carbonate weathering is significant.
Any remaining cations not accounted for by rain, evaporates, halites, and silicates are attributed to carbonate weathering. We calculated the contribution of carbonate weathering to riverine cations:
Chemical budget and calculation results
To quantify the contributions from rain input, evaporite (halite and gypsum) dissolution, carbonate and silicate weathering, a forward model based on mass balance was used. For each element, we can write mass balance equations with the assumptions discussed above.
The calculated contributions of various weathering sources to the cationic TDS (mg L−1) for the TRR are illustrated in Fig. 7. Cationic TDS is equal to the sum of K, Na, Ca, and Mg from the different reservoirs.
Atmospheric inputs were generally minor in the TRR. Cations from atmospheric sources accounted for 0.9–3.9 % of total riverine cations in Jinshajiang, 1.9–2.8 % in Lancangjiang, and 3.3–4.1 % in Nujiang. However, in some small tributaries (samples JT12, JT13, JT14, and LT11) with low TDS (76.1–82.0 mg/L), rain can provide as much as ~10 % of dissolved cations.
Assuming that evaporite is composed of halite and gypsum, cationic TDS contributions from halite and gypsum dissolution were calculated separately. Halite contributions were minor for most samples. Large halite proportions (39.7–49.8 %) were seen in the Jinshajiang mainstream samples. Substantial sulfate salt contributions of 25.5–37.8 and 33.0–38.5 % were calculated for the Nujiang and Lancangjiang mainstream samples, respectively. The exact mineralogy of the sulfate salt (e.g., CaSO4, MgSO4, and Na2SO4) does not affect the sulfate budget but can affect that of silicates and carbonates. Sulfate is also likely generated by sulfide oxidation, and therefore this estimate is an upper limit of the gypsum contribution.
Silicate contributions of cations, \(({\sum {\text{cation}} })_{\text{sil}}\), in the studied rivers were generally <16 % (average 13 %) of total cations, except for one Jinshajiang tributary sample (JT10) at 35.8 % (Fig. 7). There are two sources of uncertainty in these estimates. The misallocation of sulfate salts to gypsum/anhydrite instead of Na-sulfate can overestimate Nasil and hence \(({\sum {\text{cation}} })_{\text{sil}}\). The large \(({\sum {\text{cation}} })_{\text{sil}}\) calculated for JT10 is suspect because of the possible existence of Na2SO4. Additionally, considering uncertainties of ±50 % for (Ca/Na)sil and (Mg/K)sil molar ratios, the propagated error is 11.4–20.4 % in the \(({\sum {\text{cation}} })_{\text{sil}}\) calculations.
Furthermore, we did not observe any general correlations between cations derived from silicate weathering (Cationsil = Nasil +Ksil + Casil + Mgsil) and SiO2 in any mainstream samples of the three rivers. Likewise, Wu et al. (2008) also found no general correlations between Cationsil and SiO2 in the seven rivers draining the HQTP. Some possible reasons are: (1) The varying lithological formations, terrain, and topography may control the chemical weathering rate of the three river basins. (2) The abundant evaporite minerals in the three drainage basins and saline lakes near the source areas are rich in trona, soda, borax, epsomite, and mirabilite (Yu and Tang 1981), which can result in overestimation of the contribution of silicate weathering. (3) Many unevenly distributed thermokarst lakes are found in source areas of the Jinshajiang, Lancangjiang, and Nujiang basins (Frenzel et al. 1995). Some dissolved Si may be consumed by diatom growth in thermokarst lakes (Huh et al. 1998).
Carbonate weathering contributed 42.8–56.4, 36.4–48.3, and 15.8–39.2 % of total cations in mainstream samples of Nujiang, Lancangjiang, and Jinshajiang, respectively. High \(({\sum {\text{cation}} })_{\text{carb}}\), between 32.0 and 79.7 %, was found in the tributary samples of the three river basins. As mentioned for silicate contributions, the assumption of all sulfates being gypsum or anhydrite may underestimate Cacarb and hence \(({\sum {\text{cation}} })_{\text{carb}}\). This is because sulfide oxidation can produce SO4, although SO4 concentrations are generally lower than Ca concentrations. Thus, the calculated \(({\sum {\text{cation}} })_{\text{carb}}\) is a lower limit of the carbonate contribution.
In summary, the result of the forward model showed that weathering of evaporite (halite and gypsum) followed by carbonate weathering is dominant in the Jinshajiang mainstream, and weathering of carbonate and gypsum is important in mainstream samples of Lancangjiang and Nujiang. Silicate weathering is not important as that of evaporite and carbonate in terms of cation contribution percentages. Carbonate weathering was the major contributor in the tributary samples of the TRR.
Chemical weathering and CO2 consumption rate
The contributions of silicate weathering, carbonate weathering, and evaporite dissolution to TDS in river water was calculated using the following equations (Xu and Liu 2007):
Together with information of drainage area and multiyear average discharge data from hydrologic yearbooks for each basin, chemical weathering rates of silicates, carbonates, and evaporite in the basins were estimated from the budget of silicate, carbonate, and evaporite weathering (Roy et al. 1999).
Silicate weathering rate (SWR) is calculated as
Carbonate weathering rate (CWR) is calculated as
Evaporite dissolution rate (EWR) is calculated as
The influence of rock weathering on the consumption of atmospheric CO2 must be considered with respect to time. In less than 105 years (the time required by rivers to transport dissolved C to the oceans), weathering of all lithologies is important for the consumption of CO2 from the atmosphere. For a million years or more, C supplied by carbonate weathering is removed from the sea by calcite precipitation and soon returned to the atmosphere; therefore, CO2 consumption from carbonate weathering can be neglected (Berner et al. 1983). We calculated CO2 consumption rates (Φ[CO2]: mol km−2 a−1) from silicate and carbonate weathering as follows (Roy et al. 1999).
The correlative equations via the data of cations, discharge, and drainage area of the rivers are
The average of the last two mainstream samples in each basin was used to calculate rock weathering and CO2 consumption rates, and the results are not significantly different from those calculated using average values of all the waters in each river. Average densities of 2.7 and 2.4 g cm−3 for silicate and carbonate were used to calculate erosion rate (Galy and France-Lanord 1999). Results of the calculation for rock weathering and CO2 consumption rates for each basin are listed in Table 2.
In Jinshajiang evaporite (halite plus gypsum) dissolution was dominant with EWR of 29.5 t km−2 a−1. Carbonate weathering is more important, with CWR of 42.7 and 22.5 t km−2 a−1 in Nujiang and Lancangjiang, respectively. The contributions of silicate weathering to total dissolved materials were minor compared with evaporite dissolution and carbonate weathering, with SWR of 1.8, 2.2, and 5.1 t km−2 a−1 in Jinshajiang, Lancangjiang, and Nujiang, respectively. The silicate weathering fluxes ranged from 0.25 × 106 to 0.44 × 106 t a−1. We found that a total 1.14 × 106 t a−1 of dissolved materials originated from silicate weathering for the three rivers. This only represents <1 % of the global river drainage silicate weathering flux, 550 × 106 t a−1 (Gaillardet et al. 1999). However, total chemical denudation fluxes (including silicate, carbonate, and evaporite weathering) of the three rivers were 44.5–70.4 t km−2 a−1 (average 54.3 t km−2 a−1), greater than published global mean weathering values of 24, 26, and 21 t km−2 a−1 (Meybeck 1979; Berner and Berner 1996; Gaillardet et al. 1999), respectively. This may indicate more intense chemical denudation of the three rivers draining the HQTP relative to those in the other areas of the world.
Calculated results of Φ[CO2]sil are 45.6 × 103, 84.9 × 103, and 157.5 × 103 mol km−2 a−1 for Jinshajiang, Lancangjiang, and Nujiang, respectively. The corresponding CO2 consumption rates by carbonate weathering (Φ[CO2]carb) are 157.8 × 103, 191.3 × 103, and 450.5 × 103 mol km−2 a−1. Uncertainties in calculating the \(({\sum {\text{cation}} })_{\text{sil}}\) carry over to the flux calculations. Considering uncertainties of ±50 % in (Ca/Na)sil and (Mg/K)sil estimation, Φ[CO2]sil and Φ[CO2]carb are 25.5–37.3 × 109 mol a−1 (213.4–313.1 × 103 mol km−2 a−1) and 92.3–99.8 × 109 mol a−1 (770.9–821.1 × 103 mol km−2 a−1). Variability was about ±20 and ±4 % for Φ[CO2]sil and Φ[CO2]carb, respectively, for the three rivers.
We assumed that all SO4 2− was from evaporite (mainly gypsum) dissolution, which may overestimate \(({\sum {\text{cation}} })_{\text{sil}}\) and Φ[CO2]sil, and underestimate \(({\sum {\text{cation}} })_{\text{carb}}\) and Φ[CO2]carb. This is because sulfide oxidation can generate sulfuric acid (H2SO4), which can dissolve carbonate and silicate minerals without uptake of atmospheric CO2. The assumption that all SO4 2− was from evaporite (mainly gypsum) dissolution was based on reports of gypsum mines and gypsiferous red beds and our field observation in the basins (Wu et al. 2008). This information indicates that gypsum dissolution could be a major source of SO4 in rivers. It is very difficult to distinguish gypsum dissolution and sulfide oxidation sources of SO4 from the lithological makeup and major ion data. With exact mineralogical investigation of sulfate in the TRR, δ34S values of dissolved sulfate could be used to trace whether sulfate comes from sulfide minerals or gypsum because those two usually have very different δ34S values (Hoefs 1997).
Given these uncertainties, however, total CO2 consumption fluxes from silicate and carbonate weathering were, respectively, 33.5 × 109 and 96.6 × 109 mol a−1 in the three rivers, accounting for about 0.4 and 0.8 % of corresponding global total CO2 consumption fluxes (8700 × 109 and 12,300 × 109 mol a−1) (Gaillardet et al. 1999). The three basins are responsible for ~0.5 % of global water discharge to oceans, and 0.4 % of global continental area (Gaillardet et al. 1999). Thus, the contribution of the three rivers to global CO2 consumption is commensurate with their drainage area and water discharge. This also demonstrates that chemical weathering of the three rivers draining the HQTP makes only a minor contribution to the reduction of atmospheric CO2 content.
Worldwide comparison
We compared SWR, CWR, EWR, Φ[CO2]sil, and Φ[CO2]carb from the present study of the TRR to earlier ones and from other large rivers in the world (Tables 2, 3).
Table 2 shows that estimated rock weathering and CO2 consumption rates in our study are generally smaller than those estimated for the seven rivers by Wu et al. (2008). In particular, our estimates of SWR, Φ[CO2]sil, CWR, and Φ[CO2]carb for Jinshajiang are clearly smaller than those of Wu et al. (2008). Reasons could be as follows. First, the drainage area used for estimating rock weathering and CO2 consumption rates vary between the two studies. Second, by comparing ion data from Jinshajiang basin between the studies, the Na concentration of 2391 μmol L−1 in Wu et al. (2008) is higher than our value (an average 1789 μmol L−1 for the last two mainstream samples), and the Cl concentration of 1269 μmol L−1 in Wu et al. (2008) is lower than our figure (an average 1690 μmol L−1 for the last two mainstream samples). Assuming that Nasil equals Nariver minus Clevap and Narain, Casil estimation using an appropriate (Ca/Na)sil gave greater Nasil and Casil in Wu et al. (2008) than our study. Therefore, the estimated SWR, CWR, Φ[CO2]sil, and Φ[CO2]carb of Wu et al. (2008) are greater than our values. The different measured Na and Cl concentrations between the two works may be related to uneven distributions of halite minerals across the three river basins. The rapid dissolution of halite after random rainfall may greatly increase Na and Cl concentrations in river waters near the halite materials. To overcome this, long-term field observation of water chemistry and more samples for calculating average values of rock weathering and CO2 consumption rates may be needed. The final reason for the discrepancy may be that unlike our study, Wu et al. (2008) calculated the total weathering rates of carbonate and evaporite for Jinshajiang, Lancangjiang, and Nujiang.
In comparison with other large rivers, similar SWR values were found in the Nujiang, Wujiang, Lancangjiang, and Min River (Han and Liu 2004; Wu et al. 2008). The Jinshajiang and Xijiang had similar values of Φ[CO2]sil in terms of flux (103 mol km−2 a−1) (Gaillardet et al. 1999). The Langcangjiang and Huang River had similar CWR, Φ[CO2]sil, and Φ[CO2]carb in terms of flux (103 mol km−2 a−1) (Wu et al. 2008). Nujiang had a CWR similar to the Min and Yalong Rivers (Wu et al. 2008). The Min, Huang, and Yalong Rivers are all on the eastern HQTP, with landscapes, vegetation coverage, and populations similar to the TRR. The Wujiang and Xijiang Rivers are in southwestern China and drain a typical carbonate rock area, and carbonate weathering was a major contributor to dissolved materials in river water.
Gaillardet et al. (1999) quoted data of Jinshajiang (Changjiang) and Lancangjiang (Mekong) from near the river mouths. They calculate larger values of SWR, CWR, Φ[CO2]sil, and Φ[CO2]carb than our estimates.
However, their estimates may be not suitable for evaluation of the impact of chemical weathering of the HQTP on global climate, because the lower courses of their studied rivers flow through heavily populated plains and hence may be polluted by industrialized and agricultural activities. Meanwhile, many tributaries not originating on the HQTP and some irrigation ditches flow into the main channels in the lower courses of these rivers. Therefore, the estimated chemical weathering may be inadequate due to considerable anthropogenic impacts on chemical compositions of river water in those areas.
The net CO2 consumption by silicate weathering (Φ[CO2]sil) was from 45.6 × 103 to 157.5 × 103 mol km−2 a−1, with an average of 96 × 103 mol km−2 a−1 in the TRR. Our average Φ[CO2]sil is near the estimated 88 × 103 mol km−2 a−1 for the upper Huang River by Wu et al. (2005), slightly smaller than the average 109 × 103 mol km−2 a−1 for the TRR estimated by Noh et al. (2009), but much smaller than values for the Indus, Ganges and Brahmaputra draining the HQTP south flank and the Amazon and Orinoco draining the Andes Mountains. In the Ganges and Brahmaputra, the contribution of silicate weathering is large (20–30 % of cations in river water) and water discharge of the two rivers is substantial, therefore net CO2 consumption rates are accordingly higher (Dalai et al. 2002). The high chemical weathering rates were attributed to strong physical erosion caused by strong precipitation and extreme topography (Singh et al. 2005). The Mackenzie draining the western Canadian orogenic belt (Rocky and Mackenzie Mountains) has relatively small CO2 consumption fluxes, likely owing to the low exposure of silicates and low temperatures (Millot et al. 2003).
Conclusions
The Jinshajiang, Lancangjiang, and Nujiang had variable major ion compositions, with TDS = 76.1–479 mg/L, reflecting the complex geologic makeup of the three drainage basins. Ca and HCO3 were the most abundant cation and anion, respectively, in the water samples, primarily reflecting the weathering of carbonates. Cl, SO4, and Na dominated the major element compositions in the mainstream samples of the Jinshajiang, indicating that evaporite dissolution was the major contributor to ionic compositions. On average, silicate weathering contributed ~13 % to total cations. Some samples of the Nujiang near the Tengchong Volcano showed distinctive silicate weathering signatures.
Calculation of chemical weathering rates based on a forward model showed that carbonate weathering was dominant, with rates of 22.5 and 42.7 t km−2 a−1 in Lancangjiang and Nujiang, respectively. In Jinshajiang, evaporite dissolution was important and had a rate of 29.5 t km−2 a−1. The contributions of silicate weathering to total dissolved materials were minor, with rates of 1.8, 2.2, and 5.1 t km−2 a−1 in Jinshajiang, Lancangjiang, and Nujiang, respectively. The more intense silicate weathering in the Nujiang basin may be related to abundant volcanic rocks and granites in that basin. Long-term average CO2 consumption by silicate weathering was 96 × 103 mol km−2 a−1, much smaller than values of the Indus, Ganges, and Brahmaputra draining the south flank of HQTP and the Amazon and Orinoco draining the Andes Mountains. Silicate and carbonate weathering in the Jinshajiang, Lancangjiang, and Nujiang basins on the HQTP consumed 33.5 × 109 and 96.6 × 109 mol a−1 of atmospheric CO2, respectively, making up 0.4 and 0.8 % of global total CO2 consumption fluxes by silicate and carbonate weathering. This demonstrates that chemical weathering of the three rivers draining the HQTP has only a minor contribution to reducing the CO2 content of the atmosphere. However, the average total chemical weathering flux (including silicate, carbonate, and evaporite weathering) of the three rivers is 54.3 t km−2 a−1, greater than the published global mean value of ~24 t km−2 a−1. This suggests a more intense chemical weathering for the three rivers draining the HQTP than in the other areas of the world.
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Acknowledgments
The authors thank two anonymous reviewers for helpful comments and suggestions that greatly improved the manuscript. This work was supported jointly by the Ministry of Science and Technology of China through the National Basic Research Program of China (‘973’ Program, Grant No. 2013CB956401), and by the National Natural Science Foundation of China (Grant Nos. 41210004, 41130536, 41173030, 41463004, 41372376).
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Zhang, LL., Zhao, ZQ., Zhang, W. et al. Characteristics of water chemistry and its indication of chemical weathering in Jinshajiang, Lancangjiang and Nujiang drainage basins. Environ Earth Sci 75, 506 (2016). https://doi.org/10.1007/s12665-015-5115-y
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DOI: https://doi.org/10.1007/s12665-015-5115-y