Abstract
A class of novel fluorine containing core-shell hybrid latexes were obtained from soybean oil-based polyurethanes and poly(2,2,2-trifluoroethyl methacrylate) (PTFEMA) by two-step synthesis under mild reaction conditions. Structural and morphology properties of the resulting hybrid latexs have been characterized by FT-IR and TEM. In addition, thermal properties (DSC, TGA) and coating performance (contact angle, stress-strain curve, and surface free energy) were investigated and discussed. The hybrid latexes exhibit outstanding thermal stability and coating performance. More importantly, through this method, low-valued foods are successfully transformed into high-valued functional materials which bring new solutions for preparing materials from renewable sources.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
N. Karl-Ludwig, J. Prog. Org. Coat., 32, 131 (1997).
D. K. Chattopadhyay and K. V. S. N. Raju, J. Prog. Polym. Sci., 32, 352 (2007).
D. E. Fiori, J. Prog. Org. Coat., 32, 65 (1997).
Y. Lu and R. C. Larock, J. Prog. Org. Coat., 69, 31 (2010).
B. U. Ahn, S. K. Lee, and S. K. Lee, J. Prog. Polym. Sci., 60, 17 (2007).
S. Y. Lee, J. S. Lee, and B. K. Kim, J. Polym. Int., 42, 67 (1997).
A. C. Aznar, O. R. Pardini, and J. I. Amalvy, J. Prog. Polym. Sci., 55, 43 (2006).
G. Lligadas, J. C. Ronda, and M. Galia, J. Biomacromolecules, 8, 686 (2007).
G. Lligadas, J. C. Ronda, and M. Galia, J. Biomacromolecules, 11, 2825 (2010).
H. Xin, Y. Shen, and X. Li, J. Colloid. Surface. A, 384, 205 (2011).
C. Decker, F. Masson, and R. Schwalm, J. Polym. Degrad. Stabil., 83, 309 (2004).
X. Jiang, J. Li, Ming, M. Ding, H. Tan, Q. Ling, Y. Zhong, and Q. Fu, Eur. Polym. J., 43, 1838 (2007).
Y. Lu and R. C. Larock, J. Biomacromolecules, 9, 3332 (2008).
P. J. Peruzzo, P. S. Anbinder, and O. R. Pardini, J. Prog. Org. Coat., 72, 429 (2011).
P. J. Peruzzo, P. S. Anbinder, and O. R. Pardini, J. Prog. Org. Coat., 72, 429 (2011).
Y. Lu, Y. Xia, and R. C. Larock, J. Prog. Org. Coat., 71, 336 (2011).
S. T. Wang, F. J. Schork, G. W. Poehlein, and J. W. Gooch, J. Prog. Polym. Sci., 60, 2069 (1996).
H. Xin, Y. Shen, and X. Li, J. Colloid. Surface. A, 384, 205 (2011).
A. J. Dong, Y. L. An, and S. Y. Feng, J. Colloid. Interf. Sci., 214, 118 (1999).
A. Guyut, K. Landfester, and F. J. Schork, J. Prog. Polym. Sci., 32, 1439 (2007).
S. L. Chai and M. M. Jin, J. Appl. Polym. Sci., 114, 2030 (2009).
A. Guo, Y. J. Cho, and Z. S. Petrovic, J. Polym. Sci. Pol. Chem., 38, 3900 (2000).
G. Lligadas, J. C. Ronda, and M. Galia, J. Biomacromolecules, 7, 3521 (2006).
P. Krol, J. Prog. Mater. Sci., 52, 915 (2007).
G. Lligadas, J. C. Ronda, and M. Galia, J. Biomacromolecules, 8, 686 (2007).
Y. Lu and R. C. Larock, J. Biomacromolecules, 8, 3108 (2007).
P. J. Peruzzo, P. S. Anbinder, and O. R. Pardini, J. Prog. Org. Coat., 72, 429 (2011).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Yu, D., Wang, L., Sun, B. et al. Synthesis and characterization of hybrid latexes from soybean oil-based polyurethane and poly(2,2,2-trifluoroethyl methacrylate). Fibers Polym 15, 208–214 (2014). https://doi.org/10.1007/s12221-014-0208-x
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12221-014-0208-x