Abstract
We compared the relationship of the behavior and performance of sugarcane baggase and rice straw as supercapacitor electrodes. X-ray diffraction revealed the evolution of crystallites of carbon and silica during activation at higher temperature. The morphology of the carbon samples was determined by SEM. The surface area, pore volume, and pore size distribution of carbon composites were measured. The electrochemical responses were studied by using cyclic voltammetry experiment at 25 °C in a three-electrode configuration. The specific capacitance of the sugarcane bagasse carbon electrodes was in the range 92-340 F/g, whereas for rice straw, it was found to be 56–112 F/g at scan rates of 2-3 mV/s. The sugarcane bagasse carbon exhibited better performance than rice straw carbon using H2SO4 as the electrolyte. However, the results clearly show that lignocellulosic wastes possess a new biomass source of carbonaceous materials for high-performance supercapacitors.
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References
J. R. Miller and P. Simon, Science, 321, 651 (2008).
P. Simon and Y. Gogotsi, Nature Materials, 7, 845 (2008).
A.G. Pandolfo and A. F. Hollenkamp, J. Power Sources, 157, 11 (2006).
V.N. Vasile Obreja, Physica E: Low. Dimens. Syst. Nanostruct., 40, 2596 (2008).
J. A. Pessoa, I.M. de Manchilha and S. Sato, J. Ind. Microbio. Biotechnol., 18, 360 (1997).
P. Robinson, University of California Davis, Personal Communication (2006).
W. T. Tsai, C. Y. Chang and S. L. Lee, Carbon, 35, 1198 (1997).
G. Yanping and D. A. Rockstraw, Micropor. Mesopor. Mater., 100, 12 (2007).
J. Hayashi, H. Toshihide, T. Isao, M. Katsuhiko and N.A. Fard, Carbon, 40, 2381 (2002).
W. C. Lim, C. Srinivasakannan and N. Balasubramanian, J. Anal. Appl. Pyrol., 88, 181 (2010).
T. E. Rufford, D. H. Jurcakova, K. Khosla, Z. Zhu and L. Gao, J. Power Sources, 195, 912 (2010).
H. Chun-Hisen and A. D. Ruey, Micropor. Mesopor. Mater., 147, 47 (2012).
F. Zhang, K. X. Wang, G. D. Li and J. S. Chen, Electrochem. Commun., 11, 130 (2009).
I. Salame and J. B. Teresa, J. Ind. Eng. Chem. Res., 39, 301 (2000).
S. J Gregg and K. S.W. Sing, Adsorption, Surface Area and Porosity, Academic Press, London (1982).
A. C. Pastor, R. Rodriguez, H. Marsh and M. A. Martinez, Carbon, 37, 1275 (1999).
C. Liao, C. Wu, Y. Yanyongjie and H. Huang, Biomass. Bioenerg., 27, 119 (2004).
P. J. Van Soest, Anim. Feed. Sci. Technol., 130, 137 (2006).
K. Raveendran, G. Anuraddha, C. Kartick and K. Khilar, Fuel, 74, 1812 (1995).
N. Yalcin and V. Sevnic, Ceram. Int., 27, 219 (2001).
H.Y. Chang, H. P. Yun and R. P. Chong, Carbon, 39, 559 (2001).
K. S.W. Sing, Pure. Appl. Chem., 54, 2201 (1982).
Y. Guo, S. Yang and Z. Wang, Mater. Chem. Phys., 74, 320 (2002).
V. Fierro, G. Muñiz, A.H. Basta, H. El-Saied and A. Celzard, J. Hazard. Mater., 181, 27 (2010).
Z. Zhu, Y. Hu, H. Jiang and C. Li, J. Power Sources, 246, 402 (2014).
E. Jeong, M. J. Jung and Y. K. Lee, J. Fluorine Chem., 150, 98 (2013).
W. T. Tsai, C.Y. Chang, M. C. Lin, S. F. Chien, H. F. Sun and M. F. Hsieh, Chemosphere, 45, 51 (2001).
T. Adinaveen, L. J. Kennedy, J. J. Vijaya and G. Sekeran, J. Ind. Eng. Chem., 19, 1470 (2013).
V. Subramanian, C. Luo, A.M. Stephan, K. S. Nahm, S. Thomas and B. Wei, J. Phys. Chem. C, 111, 7527 (2007).
W. J. Si, X. Z. Wu, W. Xing, J. Zhou and S. P. Zhuo, J. Inorg. Mater., 26, 107 (2011).
X. Z. Wu, J. Zhou, W. Xing and S. P. Zhuo, J. North Uni. China, 33, 179 (2012).
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Thambidurai, A., Lourdusamy, J.K., John, J.V. et al. Preparation and electrochemical behaviour of biomass based porous carbons as electrodes for supercapacitors — a comparative investigation. Korean J. Chem. Eng. 31, 268–275 (2014). https://doi.org/10.1007/s11814-013-0228-z
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DOI: https://doi.org/10.1007/s11814-013-0228-z