Abstract
This article describes the ion exchange of a heavy metal Ni(II) from aqueous solutions onto a Dowex HCR-S, cationic resin. Batch adsorption studies were conducted to evaluate the effect of various parameters such as pH, resin dose, stirring speed, temperature, contact time and initial Ni(II) concentration on the removal of Ni(II). Adsorption rate increased with the increase in initial nickel concentration, stirring speed and temperature. Equilibrium adsorption isotherms were measured for the single component system, and the experimental data were analyzed by using Langmuir, Freundlich, Elovich, Temkin, Khan, Sips, Toth, Koble-Corrigan and Radke-Prausnitz isotherm equations. The Sips equation appears to fit the equilibrium data. Different models were tested for their applicability. Adsorption kinetic data were modeled using the Lagergren pseudo-first-order, Ho’s pseudo-second-order and Elovich models. It was found that Ho’s pseudo-second-order model could be used for the prediction of the system’s kinetics. Thermodynamic activation parameters such as ΔG*, ΔS* and ΔH* of the adsorption of Ni(II) on Dowex HCR-S cationic resin were also calculated.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
A. H. Konsowa and A. H. Elshazly, Desalination, 158, 189 (2003).
N. Dizge, B. Keskinler and H. Barlas, J. Hazard. Mater., 167, 915 (2009).
M. Iqbal, N. Akhtar and J. Iqbal, J. Hazard. Mater., 108, 85 (2004).
S. Chiarle, M. Ratto and M. Rovatti, Water Res., 34, 2971 (2000).
B. Son, K. Park, S. Song and Y. Yoo, Korean J. Chem. Eng., 21, 1168 (2004).
S. Kim, K. Lim, Y. Park, J. Kim and S. Cho, Korean J. Chem. Eng., 18, 686 (2001).
S. Rengaraj, Y. Kim, C. Joo, K. Choi and J. Yi, Korean J. Chem. Eng., 21, 187 (2004).
S. Rengaraj, C. K. Joo, Y. Kim and J. Yi, J. Hazard. Mater., B102, 257 (2003).
C. C. Tay, H. H. Liew, C.-Y. Yin, S. Abdul-Talib, S. Surif, A. A. Suhaimi and S. K. Yong, Korean J. Chem. Eng., 28, 825 (2011).
S. Yang, G. Sheng, X. Tan, J. Hu, J. Du, G. Montavon and X. Wang, Geochimica et Cosmochimica Acta, 75, 6520 (2011).
G. Sheng, S. Yang, J. Sheng, J. Hu, X. Tan and X. Wang, Environ. Sci. Technol., 45, 7718 (2011).
S. Yang, J. Li, D. Shao, J. Hu and X. Wang, J. Hazard. Mater., 166, 109 (2009).
X. Tan, M. Fang, C. Chen, S. Yu and X. Wang, Carbon, 46, 1741 (2008).
C. Chen and X. Wang, Ind. Eng. Chem. Res., 45, 9144 (2006).
S. Yang, J. Li, Y. Lu, Y. Chen and X. Wang, Appl. Radiation and Isotopes, 67, 1600 (2009).
Q. Fan, D. Shao, Y. Lu, W. Wu and X. Wang, Chem. Eng. J., 150, 188 (2009).
C. Chen, J. Hu, D. Shao, J. Li and X. Wang, J. Hazard. Mater., 164, 923 (2009).
D. Xu, X. Zhou and X. Wang, Appl. Clay Sci., 39, 133 (2008).
X. Tan, C. Chen, S. Yu and X. Wang, Appl. Geochemistry, 23, 2767 (2008).
P. Chang, X. Wang, S. Yu and W. Wu, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 302, 75 (2007).
Q. H. Fan, D. D. Shao, J. Hu, W. S. Wu and X. K. Wang, Surface Sci., 602, 778 (2008).
APHA, in Standard methods for the examination of water and wastewater, Ed., APHA (1985).
B. Alyüz and S. Veli, J. Hazard. Mater., 167, 482 (2009).
S. Çoruh, Desalination, 225, 41 (2008).
I. H. Lee, Y.-C. Kuan and J.-M. Chern, J. Chinese Inst. Chem. Eng., 38, 71 (2007).
A. K. Meena, G.K. Mishra, P. K. Rai, C. Rajagopal and P. N. Nagar, J. Hazard. Mater., 122, 161 (2005).
H. Nollet, M. Roels, P. Lutgen, P. Van der Meeren and W. Verstraete, Chemosphere, 53, 655 (2003).
K. S. Rao, G. R. Chaudhury and B. K. Mishra, Int. J. Miner. Process., 97, 68 (2010).
I. Langmuir, J. American Chem. Soc., 1361 (1918).
H. M. F. Freundlich, J. Phys. Chem., 57, 385 (1906).
S.Y. Elovich and O.G. Larionov, Izv. Akad. Nauk. SSSR, Otd. Khim. Nauk, 2, 209 (1962).
M. I. Temkin, Zh. Fiz. Chim, 15, 296 (1941).
R. Sips, J. Chem. Phys., 16, 490 (1948).
A. R. Khan, R. Ataullah and A. Al-Haddad, J. Colloid Interface Sci., 194, 154 (1997).
C. J. Radke and J. M. Prausnitz, Ind. Eng. Chem. Fundam., 11, 445 (1972).
R. A. Koble and T. E. Corrigan, Ind. Eng. Chem., 44, 383 (1952).
J. Toth, Acta Chem. Acad Hung, 69, 311 (1971).
R. Rostamian, M. Najafi and A. A. Rafati, Chem. Eng. J., 171, 1004 (2011).
Y. S. Ho and G. McKay, Trans. I Chem. E, 76B, 332 (1998).
Y. S. Ho, D. A. J. Wase and C. F. Forster, Water SA, 22, 219 (1996).
G. McKay, Y. S. Ho and J. C. Y. Ng, Sep. Purif. Methods, 28, 87 (1999).
T. Furusawa and J. M. Smith, J. AIChE, 20, 88 (1974).
F.-C. Wu, R.-L. Tseng and R.-S. Juang, Chem. Eng. J., 153, 1 (2009).
M. Dogan, Y. Özdemir and M. Alkan, Dyes Pigm., 75, 701 (2007).
K. Laidler and J. H. Meiser, Physical chemistry, Houghton Mifflin New York, 852 (1999).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Fil, B.A., Boncukcuoğlu, R., Yilmaz, A.E. et al. Adsorption of Ni(II) on ion exchange resin: Kinetics, equilibrium and thermodynamic studies. Korean J. Chem. Eng. 29, 1232–1238 (2012). https://doi.org/10.1007/s11814-012-0012-5
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11814-012-0012-5