Abstract
Flexible pressure sensors have received wide attention due to their potential applications in wearable electronics and electronic skins. It is still a challenge to manufacture high-sensitivity flexible pressure sensors in a low-cost and efficient way. In this study, a low-cost and simple method for preparing a flexible pressure sensor with porous structure based on physical foaming is proposed. The sensitivity of the flexible pressure sensor is 0.796 kPa−1 (applied pressure ≤ 2 kPa). In addition, the flexible pressure sensor has a low limit of detection of 4 Pa and a fast response time of 65 ms, and its performance remains unchanged after 1000 loading/unloading tests. This high performance enables flexible pressure sensors to detect touch and limb movement. Considering the good performance of the device, we expect that the sensor will provide broad application prospects in the fields of smart electronics and artificial intelligence.
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Introduction
Recently, electronic skin (e-skin) has demonstrated broad development prospects in applications such as intelligent robots,1,2 human–computer interaction,3,4 human health monitoring,5,6,7 and wearable mobile devices.8,9,10 As the core of e-skin, the performance of the flexible pressure sensor (FPS) determines the overall performance of the electronic skin. In general, pressure sensors can be divided into four types according to their sensing mechanism: piezoresistive,11,12,13 capacitive,14,15 piezoelectric,16,17,18 and triboelectric.19,20,21 The capacitive pressure sensor has the advantages of simple structure, low manufacturing cost, and low power consumption compared with other types of sensors. Capacitive pressure sensors generally consist of two parallel electrodes and a dielectric layer. The capacitance can be effectively tuned by changing the distance between the electrodes. In other words, the goal is to produce large spacing variations within small pressure ranges. Therefore, the dielectric layer is a key component to improve the sensitivity of the capacitive pressure sensor. Polydimethylsiloxane (PDMS) is the most widely used dielectric material for capacitive pressure sensor because it is highly deformable, eco-friendly, transparent, and biocompatible, which makes it especially suitable as artificial skin. Some studies have shown that dielectric layers with structures which are easily compressed can effectively improve the sensitivity and corresponding characteristics of FPS. Therefore, the structure of the dielectric layer becomes the key to improving the sensitivity of the sensor.
In recent years, various dielectric layer structures have been studied to improve sensor performance, such as pyramids,14,22,23 porous structures,24,25,26,27 and micro-pillar structures,28 which can induce large deformation under subtle external stimuli. For example, researchers use photolithography to carve pyramid-shaped and cone-shaped templates on silicon wafers, and use PDMS inverted molds to obtain pyramid- and cone-shaped microstructure films; the tips of these patterns are easily deformed. However, although the sensitivity of the sensor made by the microstructure pattern method has been improved, the pattern will collapse rapidly under low pressure, so the measurement range is low (0–1 kPa). In addition, the procedure for preparing silicon templates is more complicated and more costly. On the other hand, the porous structure has a large specific surface area, and large volume changes can occur under pressure, leading to high sensitivity and a wide range of detection; thus, it has been widely used in capacitive pressure sensors. At present, the porous structure is generally prepared by three methods: emulsion template, particle template, and chemical foaming methods. Porous polydimethylsiloxane (P-PDMS) has been prepared simply by evaporating the dispersed phase using the emulsion template method.27,29 Kang et al.30 used microwaves to process the mixed solution of perfluorocarbon and PDMS to form a porous structure. These micropores are easily deformed under small external pressure, so the sensor prepared in this way can detect small forces. However, the micropores will close when subjected to a small force, so the measurement range of the sensor using the emulsion template method is relatively narrow. The particle template method is a traditional strategy which offers a simple and inexpensive means for preparing high-deformation PDMS with good reproducibility and repeatability. This method creates pores by adding solid particles such as polystyrene (PS) balls and salt or sugar crystals24,31 to uncured PDMS. For example, Wei et al.32 formed a porous structure by dissolving sodium chloride (NaCl) particles mixed in a PDMS–carbon conductive paste (CCP) composite material. The sensor made using this method has a wide measurement range, but the gap inside the PDMS is relatively large and requires high pressure to be completely closed, so the sensitivity of the sensor is low. In addition, it is difficult to completely remove the added particles. Another effective method for preparing porous structures is the chemical foaming process, which produces P-PDMS by creating bubbles during curing. For example, NaHCO3 and NH4Cl particles are added to uncured PDMS,33,34 and these particles are heated and decomposed to produce gas to form a porous structure. The disadvantage of this method is that it will produce some harmful gases, with adverse effects on the environment.
In this work, a simple and innovative method based on the physical foaming technique is proposed to spontaneously form a porous structure under heating. It does not require custom templates, complex processes, or expensive equipment, which opens an avenue for the low-cost and controllable commercial manufacture of microstructures economically and efficiently. Pressure sensors made using this method have a wide measurement range and high sensitivity. The sensitivity of the flexible capacitor pressure sensor is as high as 0.796 kPa−1, the response time is 65 ms, the detection limit is as low as 4 Pa, and the sensor can be reused at least 1000 times. In addition, the application of FPS in human motion and intelligent robots is investigated in this work, which illustrates that the FPS fabricated in our work has broad application prospects.
Experimental Section
Raw Materials and Fabrication Process
Polyethylene terephthalate-indium tin oxide (PET-ITO) flexible conductive substrate (square resistance: 30–35 Ω/sq, light transmittance: > 86%) was purchased from Zhuhai Kaiwei Optoelectronics Technology Co., Ltd. Deionized water was made by the laboratory. Paulownia, pine, and beech were purchased from Shandong Caoxian Tianlong Wood Products Factory. The conductive silver paste was purchased from Carson Co., Ltd. The PDMS elastomer (Sylgard 184) was purchased from Dow Corning Co., Ltd.
The preparation of the porous-structured sensor was carried out as follows: Firstly, a PDMS mixture was prepared with basic glue and curing agent in a mass ratio of 10:1. The pine was cut into small pieces of 1 cm × 1 cm × 0.5 cm, and the PDMS mixture was spin-coated on the surface of the wooden block (the rotational speed of the homogenizer was 650 rpm, the time was 15 s). The PDMS with a porous structure was stripped after curing at 120°C for 1 h. Subsequently, the P-PDMS surfaces were cleaned with deionized water and dried in an oven at 80°C. Next, the P-PDMS and the PET-ITO film were both cut into pieces of 0.7 cm × 0.7 cm, and the conductive silver paste was used to fix the wire on the conductive layer of the PET-ITO film. Then the PET-ITO film of the lead wire was used as the upper and lower electrodes of the sensor, and the P-PDMS was used as the dielectric layer. Finally, the edges were bonded together using 3M Scotch tape to assemble the sandwich-structured FPS.
Characterization
The surface morphology of the PDMS patterned layer was investigated by field emission scanning electron microscopy (SEM, JEOL JSM-6700F, Japan). The capacitance was measured using an inductance capacitance and resistance (LCR) meter (TongHui TH2830). External pressure was applied using a force gauge with computer-controlled stages (Shanghai Kanyan Testing Instrument Co., LTD). A laboratory-made electromagnet/relay test system was used for cyclic loading/unloading tests.
Results and Discussion
Properties of P-PDMS Composites as Dielectric Layers
Figure 1a shows the preparation process for the porous structure sensor: The PDMS pre-solidified liquid is spin-coated on the surface of the wood block, and the PDMS/wood block is heated and cured. During the curing process, the air in the gap of the wood block will be heated and will rise into the PDMS to form a porous structure. Finally, PET-ITO is used as the electrodes of the sensor. A photograph and schematic illustration of the sensors is presented in Fig. 1b and c. The prepared sensor dielectric layer becomes loose and opaque due to the existence of bubbles.
During the PDMS curing process, the air in the cracks of the wood blocks will be heated and will rise into the PDMS to form bubbles. The wood density and temperature can affect the number of bubbles in the PDMS. In order to explore the impact of different types of wood on the sensitivity of the sensor, we selected three kinds of wood for comparative experiments. The density of Paulownia is 2.72 g/cm3, and Young's modulus is 3740 MPa35; the density of pine is 0.5 g/cm3, Young's modulus is 986 MPa, and the Poisson ratio is 0.65136; the density of beech is 0.745 g/cm3, Young's modulus is 2240 MPa, and the Poisson ratio is 0.36.37 The capacitance change curves of the three densities are shown in Fig. 2a. We generally use sensitivity to evaluate the performance of the sensor. The sensitivity of a capacitive pressure sensor is defined as follows:
where \({C}_{0}\) is the initial capacitance, \(\Delta C\) is the relative change in capacitance. and \(P\) is the applied pressure.38 Therefore, the greater the change in capacitance per unit of pressure, the higher the sensitivity of the sensor. According to this formula, we can evaluate the sensitivity of the sensor by calculating the slope of the \((\Delta C/{C}_{0})-P\) curve, which can be divided into two linear regions. The variation in the capacitance of the P-PDMS capacitive pressure sensors increases logarithmically under applied pressure. When the pores close under pressure, the capacitance variation gradient is reduced.9,39 The porous structure sensor made of Paulownia has sensitivity of 0.796 kPa−1 when the pressure is lower than 2 kPa, and the sensitivity is 0.081 kPa−1 when the pressure is higher than 2 kPa. The porous sensor made of pine wood has sensitivity of 0.532 kPa−1 and 0.039 kPa−1 when the pressure is lower and higher than 2 kPa, and the porous structure sensor made of beech wood has sensitivity of 0.279 kPa−1 and 0.023 kPa−1 when the pressure is lower than and higher than 2 kPa, respectively. Paulownia has the lowest density (0.3 g/cm3) among these three wood blocks, so the number of pores in Paulownia is the greatest under the same area. Figure 2b shows a microscopic image of the surface of the three kinds of wood blocks. It can be seen that there are many pores on the surface of Paulownia wood, and there are almost no pores on the surface of beech wood. The sensor with the porous structure made of Paulownia has the highest sensitivity because the greatest number of air bubbles is in the PDMS templated with Paulownia. Therefore, we chose Paulownia as the template for the porous structure sensor. Figure 3 shows SEM images of the surface and cross-section of the P-PDMS. There are a large number of bubbles in the PDMS, and most of the bubbles are 150 μm in diameter. The bubbles are regular spherical and evenly distributed in the PDMS.
To explore the influence of curing temperature on the porous structure, we used Paulownia wood as a template to solidify PDMS at 60°C, 80°C, 100°C, 120°C, and 140°C. Figure 2d shows a microscopic image of the surface of the P-PDMS structure at different temperatures. The number of bubbles per unit area increases with increasing temperature, but no change is seen in the number of bubbles generated per unit area beyond a temperature of 100°C (Fig. 2c). As the heating causes the air to rise, the air rises faster and more bubbles enter the PDMS when the temperature is higher. At the same time, the curing speed of PDMS also accelerates with the rise in temperature, and the bubbles which enter the PDMS can remain in the PDMS. The rate of rising air is slower and fewer bubbles enter the PDMS when the temperature is lower. At the same time, the curing speed of PDMS is slower. The bubbles entering PDMS gradually rise into the air, and fewer bubbles remain in PDMS. When the temperature is increased to 100°C, the maximum rate of air and curing speed of PDMS are reached. With curing above 100°C, the number of bubbles in the P-PDMS remains unchanged, so we chose 100°C as the curing temperature for PDMS. The influence of bubbles in the P-PDMS structure on the sensitivity is mainly due to the following. The definition of capacitance is:
where \({\varepsilon }_{0}\) is the dielectric constant of air,\({\varepsilon }_{r}\) is the dielectric constant of the dielectric layer, \(A\) is the overlapping area of the two electrodes, and \(d\) is the distance between the two electrodes.40 The P-PDMS is more likely to deform than unstructured PDMS under the same pressure because it is composed of many pores (air).
The low dielectric constant of the pores (\({\varepsilon }_{0}\)=1) is replaced by the high dielectric constant of PDMS (\({\varepsilon }_{PDMS}\)= 2.7) as the pores close with increasing pressure.10 The effective dielectric constant of the P-PDMS composites is:
where \({V}_{\mathrm{air}}\) is the volume of air in P-PDMS, and \({V}_{PDMS}\) is the volume of PDMS in P-PDMS.31 When pressure is applied, \({V}_{air}\) decreases while \({V}_{PDMS}\) is almost constant, which causes \(\frac{{V}_{\mathrm{PDMS}}}{{V}_{\mathrm{air}}+{V}_{\mathrm{PDMS}}}\) to increase, thereby increasing the effective dielectric constant of P-PDMS. Therefore, the P-PDMS dielectric layer sensor with high porosity has high sensitivity.
Performance of the Sensor
In order to study the influence of the bubble structure on the performance of the sensor, unstructured PDMS with the same dielectric layer thickness was used as the dielectric layer of the sensor for comparison. Figure 4a shows the sensitivity of two types of sensors. The slope of the curve can be divided into two linear regions. The sensor with a bubble structure has sensitivity of 0.796 kPa−1 when the pressure is lower than 2 kPa and 0.081 kPa−1 when the pressure is higher than 2 kPa, and the unstructured sensor has sensitivity of 0.092 kPa−1 and 0.017 kPa−1 at pressures below and above 2 kPa, respectively. We can see from Fig. 4a that the porous structure improves the sensitivity significantly. There are two main reasons for this high sensitivity. The first is that P-PDMS is composed of many pores (air), so the P-PDMS is more easily deformed than unstructured PDMS under the same pressure. The second reason is that the high dielectric constant of PDMS (\({\varepsilon }_{PDMS}\)=2.7) replaces the low dielectric constant (\({\varepsilon }_{0}\)=1) of the pores during the process of pore closing with increasing pressure, which increases the capacitance change.
In addition, an object with a low weight (20 mg) was loaded on the sensor to explore the detection limit and the response time of the microstructure flexible pressure sensor (MFPS). As shown in Fig. 4b, the capacitance of the sensor increases rapidly within a response time of 65 ms and remains at a stable value when the pressure is loaded. The capacitance of the sensor drops rapidly and decays to the initial value within 117 ms as the pressure is unloaded (inset of Fig. 4b). This means that the sensor proposed in this work has sufficient practically in real-life applications.41 The loading response time is faster than the recovery time, which can be attributed to the structure deformed by external forces during the loading process and the dependence of the recovery process on the nature of the material itself. The viscoelastic behavior of the PDMS film may be another reason.42,43,44 The repeatability test instrument was made by the laboratory. We first placed the sensor on the electromagnet, then placed a thin iron sheet on the sensor, and used a timing relay to control the on and off cycles of the electromagnet, so that each on and off cycle of the electromagnet could complete a loading/unloading cycle. We carried out 1000 loading/unloading tests on the sensor. The illustration in Fig. 4c shows the signals of the three different stages of the repeated test, and the waveform is basically identical. The results show that there is no fatigue in the sensor over 1000 loading/unloading cycles due to the good elasticity of PDMS. In order to explore the stability of the sensor, the sensor was put into a constant temperature and humidity chamber at 85°C and 85% relative humidity for an aging test. As shown in Fig. 5, the sensitivity of the sensor remained unchanged after 72 h, indicating its good stability. In addition, a performance comparison between this work and sensors reported in recent years is shown in Table I. It can be seen that the sensor has good performance. From the above experimental results, we can see that our microstructural sensors have high sensitivity, a low detection limit, and good stability and reliability.
Application in Wearable Electronics
Based on the basic mechanism of the sensor and excellent sensing performance, Fig. 6 shows some applications in human motion detection and intelligent robots. As shown in Fig. 6a and b, the sensor is attached onto the surface of the left mouse button to monitor the human body for mouse clicks. Stable dynamic signals generated by the sensor can be seen by clicking and double-clicking the mouse, and the single-click and double-click signals can be distinguished, which provides an idea for the development of the mouse in the future. In addition, the sensor can be used in electronic skin, as the pressure sensor can provide feedback to the robot similar to “tactile” feedback, so that the robot can complete its work reliably and accurately. As shown in Fig. 6c and d, a sensor was installed on the thumb, and then the beaker was held by hand. The changes in pressure signals could be seen by adding 100 ml water at a constant rate and 20 ml water several times in the beaker. The pressure sensor could easily measure the force of the thumb, which shows that the sensor can play an important role in the tactile perception of the manipulator. Furthermore, the flexible sensor can also be used for daily monitoring of the human body. Figure 6f shows that the pressure sensor is installed at the index finger joint. A significant change in capacitance can be seen (Fig. 6e) with the different bending angles of the knuckle. The force on the sensor increases with the increase in the bending angle, so as the bending angle increases, the sensor generates stronger signals, increasing the variation. The bending radius can be calculated by the following expression:
where L defines the length of the sensor and d defines the distance between the ends of the sensor. From the above formula, it can be calculated that the bending radius is 3.7 mm when the bending angle is 120°, and the bending radius is 2.45 mm when the bending angle is 90°. This suggests that the flexible tactile sensor can be used as a skin-mountable wearable sensor to monitor human motion.
Conclusion
In conclusion, we propose a low-cost and simple method for preparing porous structures. The capacitive sensor uses P-PDMS as the dielectric layer and PET-ITO as the upper and lower electrodes. The sensitivity of the FPS is 0.796 kPa−1 (applied pressure < 2 kPa), which is significantly higher than that of an unstructured sensor. In addition, the FPS has a low detection limit of 4 Pa and fast response time within 65 ms, and its performance remains unchanged after 1000 loading/unloading tests. This high performance enables FPS to detect touch and limb movement. Considering the good performance of the device, we expect that the sensor will provide broad application prospects in the fields of smart electronics and artificial intelligence.
Data Availability
The authors declare that all data supporting the findings of this study are available within the article.
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This work is supported by the National Natural Science Foundation of China (Grant No. 52175525) and Science and Technology Project of Henan Province (No. 202102210277).
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All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by ZS, LZ, CC, YZ, SY and WA. The first draft of the manuscript was written by ZS, and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.
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Song, Z., Zhao, L., Chang, C. et al. A Flexible, Highly Sensitive Porous PDMS Tactile Sensor Based on the Physical Foaming Method. J. Electron. Mater. 51, 7173–7181 (2022). https://doi.org/10.1007/s11664-022-09956-2
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DOI: https://doi.org/10.1007/s11664-022-09956-2