Abstract
Reactions of sodium 3,4,5-triphenyl-1,2-diphosphacyclopentadienide with primary alkyl bromides, secondary alkyl iodides, and silicon and tin chlorides gave stable 1-substituted 1,2-diphospholes. In a solution of 3,4,5-triphenyl-1-trimethylstannyl-1,2-diphosphacyclopenta-2,4-diene, the Me3Sn group migrates between two phosphorus atoms.
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Dedicated to Academician I. L. Eremenko on the occasion of his 60th birthday.
Institut für anorganische Chemie der Universität Leipzig, 29 Johannisallee, D-04103 Leipzig, Deutschland.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1206–1210, June, 2010.
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Milyukov, V.A., Bezkishko, I.A., Zagidullin, A.A. et al. Reactions of sodium 3,4,5-triphenyl-1,2-diphosphacyclopentadienide with alkyl halides and silicon and tin chlorides. Russ Chem Bull 59, 1232–1236 (2010). https://doi.org/10.1007/s11172-010-0226-9
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DOI: https://doi.org/10.1007/s11172-010-0226-9