Abstract
But-2-yne-1,4-diylbis(triphenylphosphonium) diiodide reacts with 2-sulfanylethan-1-ol in the presence of triethylamine to form a 1 : 1 adduct. Under similar conditions, ethane-, butane- and 2-methylbutane- 1-thiols form [4-(alkylsulfanyl)buta-1,3-dien-1-yl]triphenylphosphonium iodides, probably via β-cleavage of the original salt involving vinylethynyl intermediate. Features of the reaction of but-2-ynebisphosphonium salt with 3,5-dimethylpyrazole, hydrazine and its derivatives have been studied.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
Ovakimyan, M.Zh., Gasparyan, G.Ts., Bichakhchyan, A.S., Pogosyan, A.S., Kinoyan, F.S., Tamazyan, R.A., and Aivazyan, A.G., Russ. J. Gen. Chem., 2014, vol. 84, no. 6, p. 1126. DOI: 10.1134/S1070363214060127.
Plenat, F., Bennamara, A., Chiche, L., and Christol, H., Phosphorus, Sulfur, 1986, vol. 84, no. 26, p. 39. DOI: 10.1080/030866486080884568.
Ovakimyan, M.Zh., Movsisyan, M.L., Gasparyan, G.Ts., and Indzhikyan, M.G., Russ. J. Gen. Chem., 2011, vol. 81, no. 2, p. 444. DOI: 10.1134/S1070363211020344.
Ovakimyan, M.Zh., Gasparyan, G.Ts., Pogosyan, A.S., Bichakhchyan, A.S., and Aivazya, A.G., Khim. Zh. Armenii, 2013, vol. 66, no. 1, p. 63.
Ovakimyan, M.Zh., Gasparyan, G.Ts., and Bichakhchyan, A.S., Khim. Zh. Armenii, 2012, vol. 65, no. 4, p. 574.
Cristau, H.J., Plenat, F., Duc, G., and Bennamara, A., Tetrahedron, 1985, vol. 41, no. 13, p. 2717. DOI: 10.1016/S0040-4020(01)96372-0.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.S. Bichakhchyan, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 5, pp. 777–781.
Rights and permissions
About this article
Cite this article
Bichakhchyan, A.S. Reactions of but-2-yne-1,4-diylbis(triphenylphosphonium) dihalides with SH- and NH-nucleophiles. Russ J Gen Chem 86, 1041–1045 (2016). https://doi.org/10.1134/S1070363216050108
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363216050108