Abstract
This article discusses our investigations into the structural and spectroscopic properties of Nd3+ co-doped alumino-silicate glass prepared by an in-situ sol-gel method. Structural characterization was carried out using X-ray powder diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) techniques. The XRD analysis reveals that the material is still amorphous even after being heated to 900 °C. FTIR analysis was used to identify the functional groups of the produced sol-gel silicate glass. The optical absorption spectra from the ground state 4I9/2 show seven peaks in the UV-VIS and NIR regions. The optical absorption spectrum of Nd3+ co-doped alumino-silicate glass-ceramic was used to determine the Judd-Ofelt (JO) intensity parameters (Ω2, Ω4 and Ω6). The photoluminescence (PL) spectrum was recorded with a 2W diode laser source of 808 nm excitations. From the larger stimulated emission cross-section (3.80 x 10−20 cm2) of the 4F3/2 → 4I11/2 transition, it is concluded that the SiNdAl glasses could be highly useful for the development of solid state laser materials. From the observed refractive indices at three different wavelengths, non-linear parameters for the glass, such as the Abbe number (υAb) and non-linear refractive index (n2), are derived.
Graphical Abstract
Highlights
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Nd3+ ions co-doped with alumino-silicate glass is prepared by in-situ sol-gel methods.
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Red-shift in absorption peaks observed after annealing due to nephelauxetic effect. The Judd–Ofelt parameter Ω2 increased and Ω6 decreased with annealing.
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PL intensity increases with annealing. PL intensity increases with increasing Al content.
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Various physical parameters like density, refractive index and non-linear polarizability are measured to investigate possible device applications of the samples.
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1 Introduction
Recently, the study of rare earth (RE) ions doped amorphous or crystalline solids materials have attracted much attention because of their attractive optical characteristics, high transition temperature, and low thermal expansion coefficients [1,2,3]. These materials hold promise for diverse applications such as optical communications, biosensors, optical amplifiers, and light-emitting diodes (LEDs) [4, 5]. Rare earth-doped materials are essential components for low-cost integrated laser sources, integrated optical amplifiers, 3D display devices, sensors, up-conversion fibers, and low-loss components [6,7,8], among other current optical technology products [8, 9], because of their fluorescence in the near IR region at 1.06 μm after the introduction of the first glass laser by Snitzer [10]. The choice of a suitable glass matrix as a host for the development of efficient optical devices doped with lanthanide ions is an active area of research. Even hosts with higher phonon energies can exhibit fluorescence spectra effectively due to the relatively large energy gap in the transition from the lanthanide ion’s 4F3/2 level to the next lower 4I15/2 level [9]. SiO2 glass is an excellent host for lanthanide ions because of its low cost, high optical transmission, low thermal expansion, excellent chemical and thermal stability, good mechanical strength and good moisture resistance [11]. However, the exceptional thermal stability of SiO2 glass poses challenges in conventional synthesis methods, as silica typically required processing temperatures above 2000 °C [12]. Such doped silica glasses can be created using the sol-gel process at significantly lower temperatures. Additionally, while still preserving an amorphous character, it allows the incorporation of larger dopant concentrations than traditional melt glasses [13, 14]. However, a variety of factors prevent them from being used as effective optical materials. In the sol-gel glass hosts, lanthanide ions tend to cluster, which causes concentration quenching [15]. Additionally, there is quenching brought on by hydroxyl (-OH) groups that were left over from the initial preparation procedure. Prolonged heat treatment can lower the hydroxyl concentration. Heating affects the physical parameters of the system, such as density, refractive index, and other structural aspects, in addition to removing hydroxyls [16, 17]. Vibrations within the host glass provide a non-radiative relaxation path for excited ions, resulting in energy loss via phonon in the glass network [18]. SiO2 glass has a rather high maximum phonon energy (1100 cm−1) and energy loss occurs via multi-phonon relaxation [19]. Hence, photoluminescence (PL) is typically only observed from excited states with significant energy gaps. Additionally, the energy level structure of the lanthanide ions makes it susceptible to cross-relaxation as concentration increases, which tends to result in Nd3+ clustering. It has been demonstrated that co-doping aluminum with lanthanide ions in doped sol-gel glasses increases fluorescence output [20, 21]. Non-bridging oxygen’s (NBOs) are believed to be introduced into the matrix by aluminum doping [22]. With silicon or aluminum, the NBOs only form one bond, leaving another open to form a bond with the lanthanide ions. Al species surround each lanthanide ions in this way, separating them from one another. Hence, cross-relaxation is decreased and PL efficiency is raised.
The highly efficient 4F3/2 → 4I11/2 lasing transition occurring at 1058 nm positions Nd3+ as one of the most extensively studied RE3+ ions when combined with various hosts, particularly for its application in solid-state lasers. The presence of absorption bands across the UV-VIS-NIR spectrum further enhance its suitability, facilitating the pumping of the Nd-laser systems through either broad-band sources such as xenon lamps or diode lasers [10, 20]. Laser efficiency primarily relies upon factors like emission cross-section and luminescence decay rates, which are significantly influenced by non-radiative decays within the system, including multi-phonon relaxation processes [9, 10]. In hosts derived from sol-gel techniques, the phenomenon of dopant clustering where luminescent species aggregate through oxygen linkage can lead to a reduction in luminescence intensity due to cross-relaxation and energy transfer processes [20]. However, these limitation can be mitigated to a considerable extent by incorporating small quantities of co-dopant like Al, TiO2, borate and tellurite [1, 2, 6, 9], as well as utilizing organic salts as glass precursors instead of mineral acid salts, in addition to optimizing the concentrations of RE3+ ions and hosts.
We describe in this paper the physical, structural and optical properties of (99-x)SiO2 + 1NdF3 + xAl2O3 (here x = 0.0, 1.2, 2.0 and 3.0 mol%)(i.e. SiNdAl0, SiNdAl1.2, SiNdAl2 and SiNdAl3) prepared by using a sol-gel technique. The structure of the as-prepared samples was examined using Fourier-transform infrared spectroscopy (FTIR) and X-ray powder diffraction (XRD). A potential process involved in the development of platelet morphology has been proposed based on the examination of the scanning electron microscopy (SEM) images. Using the optical absorption and fluorescence spectra, the spectroscopic parameters of the nanocrystals, such as radiative transition probability and branching ratio, were qualitatively analyzed and discussed. To verify the usefulness of the created glass samples, the physical properties are also measured.
2 Experimental
2.1 Precursor
All chemicals used in this study were of analytical grade and were used without further purification. Aluminum nitrate nona-hydrate (Al(NO3)3·9H2O, Merck, 99.5%), tetraethyl orthosilicate (TEOS; Sigma-Aldrich 99%), neodymium (III) fluoride (NdF3, Sigma-Aldrich 99.99%), methanol (MeOH; Merck, 99.8%), nitric acid (HNO3; Sigma-Aldrich 70%) and banana trunk sap were purchased and used as received.
2.2 Samples preparation synthesis of Nd3+ co-doped Al samples
The composition of the bulk glasses (in mol%) (99-x)SiO2 + 1NdF3 + xAl2O3 (here x = 0.0, 1.2, 2.0 and 3.0 mol%)were prepared by using a sol-gel technique with TEOS as the main precursor, methanol (CH3OH) as the solvent, nitric acid (HNO3) as the catalyst, and Al(NO3)3·9H2O and NdF3 as the source of dopants. For specific concentrations of Nd3+ and Al3+ dopant in a particular sample, the required amounts of NdF3 and Al(NO3)3·9H2O were dissolved in a mixture of methanol, nitric acid and banana trunk sap (a natural product containing more than 90% of water) and stirred for 50 min using a magnetic stirrer. TEOS was then added dropwise, and the resulting mixture was stirred for 2 h [23]. The final solutions contained TEOS, banana trunk sap, methanol, and HNO3 in the following molar ratios: 1: 5.5: 3.5: 0.1. The final sol is then transferred to a plastic vessel sealed to prevent evaporation. After the sol has gelled and been sealed at room temperature for 26 days, some pinholes were made in a plastic container’s lid to allow for slow evaporation. After that, the container was left standing for a few weeks. To make dense glass samples in the shape of discs, the gels were further dried in an electric muffle furnace by gradually heating to 40 °C and then annealing up to 1060 °C at a heating rate of 1 °C min−1.
2.3 Techniques of characterization
Optical properties were recorded using a Horiba iHR320 imaging spectrometer. Optical absorption and photoluminescence spectra were recorded in the UV-VIS & NIR regions at room temperature (RT). The photoluminescence studies make use of an 808 nm diode laser source. X-ray diffraction (XRD, Empyrean, PANanalytical), using CuKα (λex= 1.54Å) radiation, was used to determine the phase compositions of the powders. FTIR spectra were acquired with a IRAffinity-1S (SHIMADZU). Using the Archimedes principle and xylene as an immersion liquid, glass densities were calculated. An Abbe refractometer with a coating of monobromonaphthalene (C10H7Br) was used to determine the transparent glass’ refractive index with an accuracy of (n ± 0.001). All measurements were performed at room temperature.
3 Result and discussions
3.1 X-ray powder diffraction studies
The powder X-ray diffraction spectrum of SiNdAl0 and SiNdAl3 in sol-gel glasses after annealing at 900 °C is shown in Fig. 1. Instead of sharp crystalline peaks, distinct broad peaks are seen, confirming the glass samples’ glassy amorphous nature. The amorphous nature of silica glass is thought to be responsible for the broad peak at 2θ = 22 [23].
3.2 FTIR analysis
FTIR spectra of SiNdAl3 of glasses is annealed at different temperatures (room temperature, 350, and 750 °C), are shown in Fig. 2, in the 400–4000 cm−1 wavenumber range, while the corresponding band assignments are given in Table 1. A number of peaks can clearly be seen at about 417, 441, 471, 588, 671, 771, 964, 1065, 1219, 1335, 1397, and 3363 cm−1. To create a 3-D silica network, TEOS is hydrolyzed and condensed with the help of water and alcohol. This process also yields Si-OH groups. The gel stage of the sol-gel glass consists mostly of water and other organic species. As the sintering temperature is increased, the broad peak between 3363 and 3723 cm−1 vanishes as a result of the removal of OH- and water molecules (H2O), which are responsible for the sample’s O-H stretching vibration [24]. The band’s intensity is greatest for glass at room temperature and gradually decreases as the temperature rises. As temperatures increased, the peak associated with stretching of Si-OH bands and the appearance of absorbed water became less intense, according to the FTIR spectra [24]. The peak’s broadening and shift to the low wavenumber side indicate a decrease in phonon energy. The aluminum ion modifies the network by creating non-bridging Al-O groups, such as Si-O-Al, which can also coordinate with lanthanide ions [25]. When the Si-O-Si bond breaks, the NBO of Nd-O-Si may also form [25]. Octahedrally coordinated Al(III)is associated with the bending mode around 487–548 cm−1. Si-OH group polymerization results in Si-O-Si bonds with wavenumber of 1335–1397 cm−1 and 1057–1065 cm−1, respectively [26]. The intensity of the Si-OH peak at 964 cm−1 decrease with increasing annealing temperature. Hence, annealing of the glass sample leads the components to gradually vanish from the glass host matrix, leading to the development of a stiff glassy network, which is evident from the FTIR spectra.
3.3 Characteristic physical properties
Selected physical properties of SiNdAl0, SiNdAl1.2, SiNdAl2, and are shown in Table 2. These values were obtained as outlined in our earlier research [27].
The variations in the sol-gel glasses’ density (g/cm3), refractive index, average molecular weight (MT), inter ionic distance (Ri), and field strength (x1013 cm−2) as a function of Al content are shown in Fig. 3a, b [27]. The tendency of decreasing inter ionic distance in these glasses shows that the atoms are becoming more densely packed as the Al3+ ion concentration in the glasses increases [27]. Figure 3a shows that the refractive index of SiNdAl in sol-gel glasses rises as the concentration of dopant ions increases. As the density of the SiNdAl in sol-gel glasses rises along with the concentration of the dopant ions, the medium’s refractive index will rise as well. It is also evident from Fig. 3b that the field strength values rise as the concentration of Al3+ ions does. This is clear from the fact that when the concentration of aluminum ions in glass rises, more ions will be made available per unit volume, increasing the field strength. The electronic polarizability of these glasses is of the order 10–25, which is surprisingly low [27], as shown in Table 2.
3.4 Absorption spectra
The absorption spectra of SiNdAl3 following annealing at 150 or 1060 °C are shown in Fig. 4a, b, respectively. The relative intensities of the various absorption peaks shift as the heat treatment is varied, leading to associated changes in the physical characteristics of the material. The low-temperature sample quickly reabsorbs atmospheric moisture because it is extremely porous, has a low density of about 1.34 g/cm3, and is exposed to the atmosphere. The sample loses the majority of its porosity after being annealed at 1060 °C and reaches a density of around 2.32 g/cm3 which is comparable to melt glass. As seen in Fig. 4, there are seven bands in the absorption spectra that correspond to the transitions between the ground state (GS) 4I9/2 and the excited states (ES) of the 4f3 configuration of lanthanide ions [23]. The band at 512, 523, 579, 679, 742, 795 and 870 nm correspond to the transitions from the 4I9/2 → level to 4G9/2, 2K13/2 + 4G7/2, 4G5/2 + 2G7/2, 4F9/2, 4F7/2 + 4S3/2, 4F5/2 + 2H9/2 and 4F3/2 respectively [28]. One transition in particular, 4I9/2 → 4G5/2 + 2G7/2, is more intense than others in the dense glass and has high oscillator strengths across all the glasses being studied. [28]. The selection rules |ΔJ| ≤ 2; |ΔL| ≤ 2 and |ΔS| = 0 are valid for this transition, which is also referred to as a hypersensitive transition [28]. As the material is heated to higher temperatures, the redshift in the absorption peaks that occurs is another interesting result. In Fig. 4a, b, the major near-infrared peaks shift from 795 nm and 871 nm to 806 nm and 879 nm [29]. The redshift seen after annealing is caused by the nephelauxetic effect, which occurs as the Nd3+ starts becoming incorporate into the covalent glass network [29].
3.5 Photoluminescence spectra
The photoluminescence spectra of SiNdAl0, SiNdAl1.2, SiNdAl2 and SiNdAl3 glasses annealed at 1060 °C, were recorded using an excitation wavelength of λex = 808 nm in the 830–1100 nm range as shown in Fig. 5. Two broad, asymmetric bands in the emission spectra are located around 879 and 1058 nm. These emission bands correspond to the RE3+ ion transitions 4F3/2 → 4I9/2 and 4F3/2 → 4I11/2, respectively. With increasing concentrations of aluminum ions and an associated decrease in concentration quenching, an increase in the intensity of a broad peak at about 1058 nm may be seen [29]. The most intense transition gives rise to a peak at 879 nm, with increasing Al3+ concentration leading to an associated increase in the emission intensity [30, 31] The increase in NBO changes the electronic structure of glasses, promoting transitions with lower energy [25]. In silicate sol-gel glasses, it has been reported that SiNdAl0, SiNdAl1.2, SiNdAl2 and SiNdAl3 results in PL spectra with splitting (Stark splitting), which is consistent with the host being altered by the presence of Al (Table 3) [32].
3.6 Effect of annealing temperature of PL intensity
Using an excitation wavelength of 808 nm, the photoluminescence spectra of SiNdAl3 sol-gel glasses was measured at various annealing temperatures. NBO (Si-O-Al), whose phonon energy is lower than that of the Si-O-Si bond, is formed and causes asymmetry [25]. This is confirmed by the observed FTIR spectra. The sample quenched by the hydroxyl (OH) group after being annealed at 650 °C exhibits low PL intensity, since the OH group quenches the PL of Nd3+ ions [29]. Energy transfer to the Nd3+ ions in silica xerogel is inhibited by the creation of electrons and holes through defect recombination. As a result, the elimination of the OH group increases the PL intensity for glasses that are annealed at higher temperatures (Fig. 6) [29]. As a result, PL enhancement is due to host matrix asymmetry and OH group elimination at high annealing temperatures. Stark splitting at the Nd3+ 4I9/2 transitions in the glass is observed in the photoluminescence spectra of SiNdAl0, SiNdAl1.2, SiNdAl2 and SiNdAl3 (Table 3), which is consistent with the host being modified at the higher temperature (1060 °C) [33]. A comparison of the stark-split energy levels of Nd3+ in various crystalline lattices is included in Table 4.
For the cross-relaxation of two ions that are close to one another, the energy level structure of Nd3+ provides a very effective pathway [30]. With increasing concentration, the possibility of cross-relaxation increases because Nd3+ clusters are more likely to form. Both Nd3+ ions may occupy the intermediate 4I15/2 state before relaxing non-radiatively to the ground state as a result of one RE ion in the excited 4F3/2 state transferring some of its energy to the neighboring ion in the ground state (Fig. 7) [29].
3.7 Oscillator strength-Judd-Ofelt analysis
As the ions around the RE have an impact on the transition probabilities between 4f states, it is essential to understand a number of spectroscopic factors while designing a suitable RE doped glass [34]. Typically, the Judd-Ofelt (JO) theory [35, 36] is used to approximate the transition probabilities using data on the absorption spectra of various f-f transitions. Using J-O theory, the calculated oscillator strengths (fcal) for the f-f transitions of RE ions from their GS |ΨJ〉 to the ES |Ψ‘J’〉 may be written as,
where the J-O intensity parameters, on which the oscillator strength depends, are Ωλ for λ = 2, 4, and 6. Planck’s constant, electron mass, refractive index, speed of light in a vacuum, and average transition wavelength are all represented in Eq. (1) by me, n, c, and h, respectively, whereas J is the initial transition states of the total angular momentum quantum number. In this calculation, the host independent RME values, ||Uλ||, as obtained by Carnal et al. [37], are employed. For λ = 2, 4, and 6, the reduced unit tensor operators are ||Uλ||, and the remaining symbols have their normal meanings. The following formula is used to correlate the measured oscillator strengths (fexp) of the observed bands,
whereε(ν) is the molar absorptivity at frequency in cm−1. The forced electronic dipole transitions “solution to the correlation matrix” is derived with the help of MATLAB (MATLABR12) commands [38]. Least square fit analysis is used to calculate the three J-O intensity parameters. An approximate method of intermediate coupling is used to determine the reduced unit tensor operators [38]. Values of ||Uλ|| for Nd3+ ions according to Carnall et al. [39], which are independent of hosts for these operators, are used in these calculations and the index of refraction, n = 1.478 (porous glass), and n = 1.674 (dense glass) of SiNdAl3 were both utilized.
The JO intensity parameters are in the order Ω6> Ω2> Ω4 (in porous glass) and Ω2> Ω4> Ω6 (in dense glass). The large number of Ω6 reasonably indicates that the hosts [Nd-O, Nd-Al] [40,41,42] and Nd3+ ions have covalent bonds with the other two metals. The Ω2 value in the present study increases from 2.12 × 10−20 cm2 in the sample treated at lower temperature to 4.93 × 10−20 cm2 for the high-temperature sample, while the corresponding Ω6 value decreases from 3.32 × 10−20 cm2 to 2.21 × 10−20 cm2. This might be because as the temperature increases, more Nd3+ ions are incorporated into the strong covalent glass network and hydroxyl ions are removed. A reduced centrosymmetric coordination environment around Nd3+ ions in the silica host is also suggested by the large value of Ω2. Although the JO analysis and the Ωλ parameters [43] have a significant inherent error, a pattern is seen where the Ω2 value rises as the sample processing temperature rises (Table 5a, b). Similar patterns were seen in the emission spectra of the RE3+ ion in sol-gel glass by Qiao et al. [44] and Reisfeld et al. [45], both of which showed that Al may reduce the site symmetry of the RE3+ ion. Due to the bond between the ligand atoms and RE3+ ions, the values of Ω4 and Ω6 produce vibronic transitions, which are dependent on the dielectric and viscosity characteristics of the medium (glass) [46]. Table 6 compares the spectroscopic quality factor (Ω4/Ω6) [47] and J-O intensity values in various hosts. The local structure and bonding around Ln3+ ions are revealed by the J-O parameter [42]. A significant value of Ω2 indicates a strong covalency of the metal-ligand bonding, whereas a large value of Ω6 indicates a high stiffness. The parameter Ω2 is known to be structure/environment sensitive and to depend on the covalency and asymmetry of ion sites near Ln3+ ions, in contrast to Ω6, which is dependent on vibronic effects [48]. Due to the nephelauxetic effect, covalent bonding reduces the electronic levels of free ions and raises Ω2 values. It is found that for hypersensitive transitions with |ΔJ| = 2, Ω2 becomes more significant [49]. The hosts’ structural characteristics have a significant impact on the transitions’ intensities.
3.8 Radiative properties from Ωλ
The measured PL spectra of the fluorescence level 4F3/2 of fixed Nd3+ doped alumino-silicate (SiNdAl3) glass are combined with phenomenological JO parameters calculated from absorption spectra in order to estimate various radiative values [50]. The emission cross-section of peaks [σP(λP)] between an initial manifold (ΨJ) and a terminal manifold (Ψ′J′) is used to determine these parameters [51].
Here, λP represents the maximum emission wavelength, \({\Delta \lambda }_{{eff}}=\frac{\int I(\lambda )d\lambda }{{I}_{\max }}\) represents the effective bandwidth, and according to Table 7, A(ΨJ;Ψ′J′) represents the probability of emission for the specific transition. The radiative transition probability between the initial (ΨJ) and stimulated manifold (Ψ′J′) can only be calculated using the electric-dipole probability [50] and the average wavelength of the transition, as follows:
The total radiative probability (AS) is determined by summing the A(ΨJ; Ψ′J′) values for each state that takes part in the transition from the higher energy excited states (ΨJ) to the lower energy ground states (Ψ′J′) [51]. The radiative lifetime, which calculates the rate of population loss from a specific state, is the inverse of the total radiative probability (τR). Several transitions’ branching ratios can written as:
Calculations can be made to determine the radiative lifetime of an excited state (Ψ′J′):
In Table 5, the relationships outlined in Eqs. 4–6 are employed to compute a range of radiative parameters for SiNdAl3 glass. Additionally, Table 8 presents a comparative analysis of laser characteristic parameter pertaining to Nd3+ ions across various glass systems for the 4F3/2 → 4I11/2 transition.
3.9 Non-linear properties
The good optical quality of sol-gel SiO2 glass is reflected in the non-linear refractive index (n2), non-linear refractive index susceptibility (χe(3)), coefficient (γce), and suitably high Abbe number (υAb) [52]. These non-linear qualities, which were determined from optical parameters, as described previously [52], are shown in Table 9. The disparities in the non-linear refractive index (n2), susceptibility (χ) and coefficient (γ) of Nd3+ as influenced by diverse crystalline lattices are summarized in Table 10.
4 Conclusions
The effect of Al doping on the photoluminescence properties of Nd3+ in silicate glass prepared by a sol-gel method are reported. Both Al co-doping and the annealing temperature have a significant impact on the PL intensity of Nd3+. RE3+ ions are subjected to a modified vibrational coupling and RE3+ clustering is prevented by Al co-doping, and RE3+ are found in the aluminum-rich regions that have greater non-bringing Al-O groups available for coordination. The phonon energy of Al-O-Si bonds is lower than that of Si-O-Si bonds. XRD confirmed that the glass samples were amorphous. FTIR spectra showed that the sample annealed at higher temperatures had fewer the OH groups, together with NBO on the low phonon energy side. The JO intensities parameters are also estimated. The results indicate that an increase in Al concentrations strongly enhances the PL of the doped glasses. The branching ratio for 4F3/2 → 4I11/2 transition is larger than that of the 4F3/2 → 4I9/2 transition, which is usually true for Nd3+ doped laser materials. From the larger stimulated emission cross-section (3.80 × 10−20 cm2) of the 4F3/2 → 4I11/2 transition, it is concluded that the SiNdAl glasses could be highly useful for the development of solid state laser material. Physical characteristics such as the relatively high Abbe number (ϑd), low non-linear refractive index (n2), and non-linear susceptibility (χe(3)) value confirm the sample’s strong optical quality [53] and its superiority as a non-linear amorphous material.
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Acknowledgements
KMSD is thankful to Ministry of Tribal Affairs, Govt. of India for their financial support through NFST with Award letter 202122-NFST-MIZ-00237. We express their gratitude to the Department of Science and Technology, New Delhi (India) for their financial support under grant No. SR/S2/LOP-0039/2010.
Author contributions
KMSD: Writing-Original draft preparation, Formal analysis, Investigation, Data curation, Visualization, Conceptualization, Writing-Reviewing and Editing, Methodology, Resources. Lp: Investigation. ALF: Investigation, Formal analysis. RL: Investigation SR: Investigation, Methodology, Resources, Conceptualization, Visualization, Review, Editing, Supervision.
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Dawngliana, K.M.S., Puia, L., Fanai, A.L. et al. Effect of Al on photoluminescence properties of Nd3+ in silicate glass prepared by in-situ sol-gel method. J Sol-Gel Sci Technol (2024). https://doi.org/10.1007/s10971-024-06539-x
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DOI: https://doi.org/10.1007/s10971-024-06539-x