1 Introduction

Maritime transportation has seen a significant surge in the last century, currently amounting to the biggest share of international trade. Its environmental consequences are significant. Exhaust emissions, oil and fuel vapors, asbestos and lead compounds, metal and plastic particles, solid, liquid, and gas wastes damage human health and the natural environment. In its fourth greenhouse gas (GHG) study (IMO: Fourth IMO GHG Study 2020), International Maritime Organization (IMO) presented an updated inventory of maritime-related greenhouse gas emissions for the period 2012–2018 and developed emission projections for the period 2018–2050. According to this report, CO2 emissions increased 8.4% from 2012 to 2018. Moreover, the share of shipping emissions in global anthropogenic emissions has increased from 2.76% in 2012 to 2.89% in 2018. IMO and the European Union (EU) had already undertaken measures to combat this challenge, for example, the creation of Special Emission Areas (SEA) which imposes restrictions on the most harmful gas’ emissions such as nitrogen oxide (NOx), sulfur oxides (SOx), particulate matter (PM), volatile organic compounds (VOC), and carbon dioxide (CO2). More measures and more effective implementation are always needed.

This study contributes to our understanding of ship-based emissions by studying emissions from one vessel on its 37-day voyage in 2019. We calculated the emissions of the most harmful six gases, namely NOx, non-methane volatile organic compounds (NMVOC), PM, SOx, carbon monoxide (CO), and CO2. These are the gases that especially impact air quality in territorial waters, inland seas, canals, straits, bays, and port regions. They also lead to acid rains. Unlike most studies which use data from a large number of ships, this research uses just one ship during one voyage which adds to the preciseness of calculations which is not possible to achieve when using a big data set. The study uses two different methods (one fuel-based, the other activity-based) to measure the emissions. We came to the conclusion that relying on data from just one ship might lead to more accurate estimations than relying on a huge data set given how much uncertainties and aggregations go to the latter. We also concluded that methods that used fuel consumption data (bottom-up) rather than the ship activity data (top-down) likely yield more accurate results.

The paper is structured as follows: First is a review of current literature on the ship-based emission estimation methods; next, we provide detailed information on the released gases that we measure and their effects; third section is devoted to the vessel and voyage information, as well as calculations of estimates with two methods; in the fourth, we discuss the results of the calculations. Our conclusion highlights the future possible practical uses of this study and its scholarly contribution.

2 Literature review

Studies which estimate gas emissions from the ships use methods based on the information they have access to. We can broadly categorize them according to the data they use: the studies that use fuel consumption data (top-down) and those that rely on data from ship activities (bottom-up). In recent times, bottom-up methods have gained more prominence.

The authors of this study recently published an article using different bottom-up methods, Ekmekçioğlu et al. (2021). The authors of this study followed Turkey’s four major ports for one year and calculated ship emissions. They proposed emission estimation analysis methodology based on gross tonnage (GT) for container ships. Previously, Ekmekçioğlu et al. (2019) studied exhaust gas emissions from ships sailing to Turkey’s Mersin and Izmir ports during the period of a year. As a result of the calculations using actual ship data and the real duration of the stay at a given port (bottom-up method), they compared the emissions released in the two ports. In another study using a similar method, Ekmekçioğlu et al. (2020) calculated ship emissions arriving at Turkey’s Kocaeli and Ambarlı ports for a year by using ENTEC company’s method. They determined the effect of ship emissions by the U.S. Environmental Protection Agency (EPA) Regulatory Model (AERMOD) and compared their results with the results of the air quality measurement station. In their work, these authors have been inspired by the important studies of (Ünlügençoğlu et al., 2019; Feng et al., 2018; Rødseth et al., 2018; H. Song et al., 2017; Kilic & Tzannatos, 2014).

In scenarios where the scientists do not have access to ship’s engine power and load information, they instead use the top-down methods, which estimate emissions by using the fuel consumption data and the fuel type (Kanberoğlu & Kökkülünk, 2021; Kılıç et al., 2020; Fameli & Assimakopoulos, 2015; Endresen et al., 2007; Corbett et al., 1999). For example, Kuzu et al. (2020) estimated emissions of ships arriving at the port of Bandırma, Turkey, and built air quality modeling using AERMOD.

Studies using both methods provide additional contributions to the field by comparing existing methods and/or suggesting new ones. A good example of this is the innovative study of Trozzi (2013). They worked on different complex levels of predictability methodologies of emissions from ships. In their manual, they explained the emission estimation complexity in three different ways (Tier). Their methodology was based on fuel consumption as in the top-down method. In cases where fuel consumption was unknown, they calculated emissions based on installed power. Finally, in cases where installed power and fuel consumption were unknown, they calculated emissions by estimating gross tonnage. The functions were calculated from the Lloyd’s register database using information from different ship types for 100,000 ships. Bilgili and Çelebi (2018) used three years of operational data of nine bulk carriers to calculate the emissions released from these ships employing different existing methods (Fameli et al., 2020).

A significant portion of the studies in this field is regional. They measure emissions in a certain port, strait, city, etc., and therefore estimate emissions based on a large number of ships. However, there are also studies in which a single ship or only a limited number of ships are examined in depth in the ship-based emission inventory, see for example (Sui et al., 2020; Ammar, 2019; Merien-Paul et al., 2018; Jahangiri et al., 2018; Bilgili & Çelebi, 2018). Similar to the study presented here, Moreno-Gutiérrez et al. (2019) studied only one ship (though ours is a container vessel while theirs is a passenger ship). They compared the results of existing calculation methods and proposed an altogether new activity-based method. They applied the existing and proposed methods to a roll-on/roll-off passenger-ship/ferry (Ro-Pax) as a case study.

Most of the studies thus far conducted in the field of gas emissions, especially the bottom-up method, use AIS, that is, the automatic identification system, see for example (Chen et al., 2016; Jalkanen et al., 2012; Huang et al., 2020; Chen et al., 2017; Ng et al., 2013; Weng et al., 2020; Song, 2014; Goldsworthy et al., 2019; Simonsen et al., 2019). IMO requires AIS on large ships. AIS transmits a ship’s position so that other ships are aware of its position. It also reports static data (ship name, type, length, etc.) and dynamic data (ship’s speed, position, port of arrival/departure, etc.).

While AIS and other such sources are highly valuable to these studies and have their specific uses, they aggregate data, have many assumptions, and lead to significant uncertainties. For example, while these calculations consider the load factor, they ignore important determinants such as the wind, waves, and general weather conditions. They calculate the load factor by dividing the ship speed by maximum speed (Weng et al., 2020; Chen et al., 2017). When scientists do not have access to the technical specifications of the vessel, they estimate the engine power either by using the ship’s size (Ng et al., 2013; Chen et al., 2016) or by interpolation and regression approaches (Weng et al., 2020). Some studies take the main and auxiliary engine’s fuel types as “assumptions” which then lead to uncertainties in the selection of the right emission factor.

As opposed to these studies, the case presented here uses real data which leaves nearly no room for uncertainties. This is because the calculations we make are based on just one ship (as opposed to using AIS reports which aggregate many ship’s results) and its data entry regarding fuel consumption, main and auxiliary engine power, load factors, operating mode, and the different types of fuel that vessel uses in different ports (per port legal requirements) are exact numbers, not estimations. Most importantly, sea and weather conditions which significantly influence the load of engines and fuel consumption, as well as the load factor, are accurate numbers rather than estimates or aggregations. Therefore, we claim that our method contributes to the already established large inventory of gas emissions by enabling future comparisons. In addition to regional studies, studies like ours that use minimum uncertainties add to the inventory of gas emissions.

3 Released gases and their effects

This study calculated ship emissions of six gases: NOx, NMVOC, PM, SOx, CO, and CO2.

Volatile organic compounds (VOCs), which are petroleum-derived emissions, react with NOx in sunlight to form ozone. This compound is often referred to as NMVOC. NMVOCs diffuse into the atmosphere from multiple sources, including combustion activities, solvent use, and production processes. NMVOCs are directly dangerous to human health. Annex VI, 15. rule of the International Convention for the Prevention of Pollution of the Seas by Ships (MARPOL), one of the IMO codes, introduced regulations for the VOC emissions. These regulations are only valid for tanker-type ships. VOC are ship-based emissions from fuels that evaporate during filling of petroleum products into tankers, during fuel intake by a ship, and in the fuel tanks. These are dangerous in loading ports and mix into the atmosphere (“VOC—Regulation 15” n.d.).

NOx is the general name of nitrogen oxide (NO) and nitrogen dioxide (NO2) emissions released from diesel engines and other nitrogen–oxygen combinations. NOx gases react in the atmosphere to form ozone (Pulkrabek & W.W. 2004; Kökkülünk, 2010). Nitrogen oxide, which is an odorless and colorless gas, is released during the combustion of all fossil fuels. It is produced in the combustion chamber of the diesel engine. The process consists of the reaction of oxygen and nitrogen during the combustion phase. The NOx production is largely dependent on the temperature inside the cylinder. This gas has many negative effects on human health due to its characteristic and concentration in the atmosphere. Nitrogen oxides are poisonous for living things, causes eye and ear discomfort, and affect the nervous system (Hasançebi, 2002). NOx restrictions are mentioned in Annex VI of MARPOL, which was adopted by IMO in 1973. Tier 1-2-3 NOx limits were determined according to engine revolution per minute (rpm) and construction year.

PM are solid or liquid particles suspended in the air that have a grain size in the 0.002–500 μm range and have various densities. In diesel engines, both air–fuel ratio and fuel type cause the formation of PM. When a large amount of fuel is sent to the combustion chamber to increase power, there will be some amount of soot in the exhaust gases since there is not enough O2. If there is not enough temperature, O2, and time in the combustion chamber, PM is discharged from the exhaust outlet. The greatest effect on health is from particles with a diameter of 2.5 μm or smaller. Fine particulate matter is PM with a diameter of 2.5 μm and less (denoted as PM2.5). Fine particulate exposure has been associated with many serious health effects, including early death. Children and the elderly are considered the most susceptible to PM effects, as well as those with asthma, cardiovascular, or lung disease. PM is also responsible for environmental influences such as corrosion, contamination, damage to vegetation, and reduced visibility (“Fine Particulate Matter” n.d.).

CO is an air pollutant resulting from incomplete combustion reaction in ship diesel engines. CO gas emission is lower in high-power diesel engines than in low-power diesel engines. The reason for this is that combustion temperature is high in high-power diesel engines. However, the CO emission amount increases on ships, especially during the maneuver operation mode, due to the reduced power of the ship’s main engine. (Saraçoğlu et al., 2013; Sinha et al., 2003). CO has a negative effect on the human respiratory system. CO attaches itself to blood cells and prevents oxygen intake.

CO2 absorbs the solar energy reflected from the ground and causes the temperature of the atmosphere to increase in what is referred to as greenhouse gas effect. Fossil fuel use is the primary source of CO2 emissions. It may also result from human activities involving agriculture and other land uses, such as forest reduction and land degradation. Approximately, 76% of all greenhouse gases in the atmosphere is CO2. Approximately, 21% of the total CO2 emitted worldwide originates from the transportation sector (Muntean et al., 2018). The amount of CO2 emissions largely depends on the fuel consumption in the ship’s main and auxiliary engines. In addition, the carbon–hydrogen ratio in the fuel is an important factor that determines the amount of CO2 emissions (Haglind, 2008). As is well-known, CO2 has an important effect on global warming.

Sulfur dioxide (SO2) is the most common pollutant emissions of land and marine vehicles. Many fuels used in diesel engines contain a small amount of sulfur. In ship diesel engines, this ratio is quite high compared to land vehicles. The sulfur content in the world has been limited to various levels. MARPOL ANNEX VI, rule 14, sets limits on SOx and PM emissions. IMO has set emission limits for Emission Control Areas (ECA) and the regions within and outside these areas to control SOx emissions from maritime transportation. The SOx limits for 2019 require that the sulfur content in the fuel used in diesel ship engines be less than 3.5% outside ECA and less than 0.1% inside ECA. In regions other than ECA, the SOx limit has been reduced to 0.5% as of 01.01.2020. A decrease in this fraction will force international traders to meet new machinery technologies and use different types of fuel (“Sulfur oxides (SOx) and Particulate Matter (PM) – IMO, Marpol Annex VI, Regulation 14” n.d.).

4 Material and method

There are two main ship-based emission calculation methods for estimating emission values of air pollutants. Both were used in this study. First method, called “the bottom-up or activity-based approach,” extracts data from a ship’s main and auxiliary engine powers, engine revolution, and fuel type. This method uses the ship’s installed power and the time spent by ships in different operating conditions to determine emissions from ships. Emission amounts are determined by multiplying the generated engine power by the time it remains at this power by the emission factor.

Second method, called “fuel-based or top-down approach,” uses ship fuel consumption values and relies on ship movements (maneuver-cruise-port-anchorage). This method uses the ship’s fuel consumption data to determine the total emissions, as well as emissions per unit of fuel. In the studies carried out using this method, the fuel consumed by the ship is determined from the marine fuel sales statistics. The amount of fuel consumed by the ship is multiplied by the emission factor. The emission volumes from the ship are thus determined.

While most similar studies rely on estimations for fuel and engine data, we used actual data from a real container ship.

4.1 Vessel and voyage

Built in 2003, the oceangoing container ship from which this study’s data originates is 207.98 m long and 32.24 m wide. With 30,024 gross ton (GT), it has a low-speed main engine at 21,735 kW and 91 rpm and four auxiliary engines at 1260 kW and 720 rpm. Main and auxiliary engines can use either heavy fuel oil (HFO) or marine diesel oil (MDO) as fuel. Throughout the voyage, 380 centistokes (cSt) viscosity, 0.975 tons/m3 density (density), 3.29% sulfur content bunker fuel oil (BFO) and 3.091 cSt viscosity, 0.8554 tons/m3 density, and 0.089% sulfur content MDO were used.

We examined “noon reports” of the ship during a voyage in 2019. “Noon reports” are reports that ship operators send to their companies on a daily basis. These reports contain information such as the daily fuel and oil consumption, as well as data regarding the cruise, maneuver, and length of stay in the port.

As shown in Fig. 1, the container ship started its itinerary at the port of Tanger of Morocco (A point) located on the Strait of Gibraltar and continued with Algeciras Port of Spain (D point). Afterward, it passed through the Strait of Gibraltar to the Atlantic Ocean and docked at Congo’s Pointe Noire port (H point), Gabon’s Libreville port (L point), and Cameroon’s Douala port (P point). G, K, and O points in Fig. 1 are anchorage points of Pointe Noire, Libreville, and Douala, respectively. The ship returned to the port of Tanger and completed the voyage.

Fig. 1
figure 1

Voyage and route of the ship (Google Earth, 2019)

The ports, cruising-maneuvering-anchorage times, main and auxiliary engine loads, number of auxiliary engines used in the relevant mode and fuel consumptions of the container ship are shown in Table 1.

Table 1 Voyage data of the container ship

The ship used MDO as an auxiliary engine fuel during arrival/departure maneuvers and during port time in Spain’s Algeciras port as it is an EU country and needs to abide by IMO low-sulfur rules (“Cleaner Air in 2020” n.d.). In the other ports, auxiliary engines and main engine used HFO since they are not from EU member states or in the ECA/Sulfur Emission Control Areas (SECA) region.

4.2 Calculations using the top-down (fuel-based) method

We made calculations by using the Tier 3 method in (Trozzi’s, 2013) study and formulas 1 and 2 (Trozzi, 2013).

$$E_{{{\text{Trip}}}} = E_{{{\text{Port}}}} + ~E_{{{\text{Cruising}}}} + ~E_{{{\text{Manouvering}}}} + ~E_{{{\text{Anchorage}}}}$$
(1)
$$E_{{{\text{Trip}},i,j,m}} = \mathop \sum \limits_{P} \left( {{\text{FC}}_{{j,m,p~}} \times ~~{\text{EF}}_{{i,j,m,p~}} } \right)$$
(2)

where\({E}_{\mathrm{T}\mathrm{r}\mathrm{i}\mathrm{p}}\) = Emission of complete trip (tonnes).FC = fuel consumption (tonnes).EF = emission factor (kg/tonne).i = pollutant.m = fuel type.j = engine type (slow-, medium-, high-speed diesel).P = operation mode of trip (port, cruising, maneuvering, anchorage).

Table 2 shows emission factors for different engine types, different fuel types, and different modes of operation. Note that, the source sites the fuel type as “BFO” which is similar to HFO in terms of its characteristics. While the container ship in question used HFO, the similarities between the two fuels make BFO parameters accurate substitutions for HFO.

Table 2 Emission factors for fuel-based approach (kg/tonne) (Trozzi, 2013)(Cooper et al., 2004)

Since the sample ship was built in 2003, the NOx emission factor was taken from 2005. NOx, NMVOC, and PM Tier 3 emission factors were taken from Trozzi’s study (Trozzi, 2013), SOx, CO, and CO2 emission factors were taken from Cooper and Gustafsson’s study (Cooper et al., 2004).

4.3 Calculations using the bottom-up (activity-based) method

We made calculations based on installed power and time spent in the different navigation phases by using the method in Trozzi’s, 2013 study and formula III.

$$E_{{{\text{Trip}},i,j,m}} = \mathop \sum \limits_{p} \left[ {T_{P} \mathop \sum \limits_{e} \left( {P_{e} \times {\text{LF}}_{e} \times {\text{EF}}_{{e,i,j,m,p}} } \right)} \right]$$
(3)

where\({E}_{\mathrm{T}\mathrm{r}\mathrm{i}\mathrm{p}}\) = Emission of complete trip.EF = Emission factor (g/kWh).LF = Engine load factor (%).P = Engine nominal power (kW).T = Time spent (hours).e = Engine category (main, auxiliary).i = Pollutant.j = Engine type (slow-, medium-, high-speed diesel).m = Fuel type (BFO, MDO).p = operation mode of trip (port, cruising, maneuvering, anchorage).

Table 3 shows emission factors in g/kWh for different engine types, different fuel types, and different modes of operation. Since the container ship was built in 2003, the NOx emission factor was taken from 2005. NOx, NMVOC, and PM Tier 3 emission factors were taken from Trozzi’s study (Trozzi, 2013), SOx, CO, and CO2 emission factors were taken from Cooper and Gustafsson’s study (Cooper et al., 2004).

Table 3 Emission factors for activity-based approach (g/kWh) (Trozzi, 2013; Cooper et al., 2004)

5 Results

During a voyage between 03.01.2019 and 04.06.2019, the ship spent 517 h in cruising, 180 h in anchorage, 129 h in port, and 19.5 h in maneuvering mode. The main engine spent 1146.2 tons of HFO, auxiliary engines spent 265.3 tons of HFO and 4.7 tons of MDO.

5.1 Results of the top-down method

We calculated the NOx, NMVOC, PM, SOx, CO, and CO2 emissions in the port, maneuver, cruising, and anchorage modes according to the fuel-based approach. Results are shown in Table 4.

Table 4 Total emission amounts by ship operating modes for top-down method (ton)

For every pollutant, total absolute emissions are the highest in the cruising mode. The reason for this is that the cruising mode is the longest operating mode and the engines work at high power. For NOx, SOx, CO, and CO2, it is followed by anchorage, port, and maneuvering operation modes, respectively. For PM and NMVOC emissions, it is followed by maneuvering, anchorage, and port modes, respectively.

The total gas emissions amount to 4705 tons. The CO2 emission amount is 4501.8 tons. It is clear that CO2 emission forms the major part of the total emissions and therefore treated separately in this paper as follows.

When the sum of NOx, NMVOC, PM, SOx, and CO emissions is calculated, their percentage ratios are 58.8%, 1.9%, 5.4%, 32%, and 1.9%, respectively. NOx and SOx emissions are higher than other emissions in percentage because of higher sulfur content of the diesel fuel (MDO) used in ships (diesel engines of ships release higher NOx than land diesel vehicle engines).

For human health, emissions during the waiting period at the port are even more important given the closeness to coastal human habitation. Therefore, we also calculated the same gas emissions, while the container ship was at the ports. Results are shown in Table 5 starting from the highest emissions going to the lowest.

Table 5 NOx, NMVOC, PM, SOx, CO, and CO2 emission values (ton) released in ports (Top-down method)

In absolute numbers, emissions are highest at the Douala port, followed by Pointe Noire, Algeciras, Tanger, and Libreville. However, the order changes if we consider the time spent at the port. When we divide the amount of emissions by duration (thus reaching a unit of emission), we see that the ship emitted the lowest gas (for all gases) at the Algeciras port. This is because being an EU country, Spain has to use fuel with lower sulfur level. In accordance with IMO rules, the ship used MDO in Algeciras as fuel in auxiliary engines for a total of 2 h of berthing and leaving maneuver, 22 h of harbor waiting, and 0.5 h of cruising. A total of 4.7 tons of MDO was used. In the other ports, the main and the auxiliary engines used HFO since they are not from EU member states or in the ECA/SECA region.

5.2 Results of the bottom-up method

Emissions according to the activity-based approach while in the port, maneuver, cruising, and anchorage modes are shown in Table 6.

Table 6 Total emission amounts by ship operating modes for bottom-up method (ton)

All gas emissions were the highest in the cruising mode, followed by maneuvering, anchorage, and port modes, respectively. The total gas emissions are 6207.4 tons. CO2 emission forms the major part of the total emissions with 5936.9 tons.

When the sum of NOx, NMVOC, PM, SOx, and CO emissions is calculated, their percentage ratios are 58.8%, 2%, 5.5%, 31.8%, and 1.9%, respectively. NOx and SOx emissions are higher in percentage.

Results using the activity-based method for gas emissions during the waiting period are shown in Table 7.

Table 7 NOx, NMVOC, PM, SOx, CO, and CO2 emission values (ton) released in ports (Bottom-up method)

Table 7 shows that the order of gases reached by the bottom-up method is the same. Douala is where the highest emission occurred but it is because of the length of the time spent in the port. When checked for time, it is Algeciras where unit emissions are the lowest. For all other ports, unit emissions are the same. This is because, as it is seen in Formula 3, n the activity-based method calculations main and auxiliary engine powers, engine load, and unit port durations are kept as constant. Emission factor is chosen depending on the type of fuel. Since the ship used a different kind of fuel in Algeciras (MDO), the estimated emissions in this port are different and lower from the other ports. The ship used HFO in all other ports; therefore, in this calculation, all other four ports showed the same exact amount of emissions.

5.3 Comparison of the results from the two methods

The acquired data allow to estimate the release of the different pollutant gases, as well as to perform comparisons between the predictions of the top-down and bottom-up models. Such a comparison could help understand the level of accuracy of the two models.

Fig. 2 shows a comparison of the sum of NOx, NMVOC, PM, SOx, CO, and CO2 emissions calculated according to the top-down and bottom-up methods for this ship voyage.

Fig. 2
figure 2

Comparison of the total NOx, NMVOC, PM, SOx, CO, and CO2 emissions according to top-down and bottom-up methods

Figure 2 shows that for all six gases, the calculations based on main and auxiliary engine powers are higher than the calculations based on fuel consumption data.

Regarding the differences in the estimates reached via the two different methods, it is apparent that the biggest discrepancy is in CO2, NOx, and SOx emissions, respectively. What is noteworthy here is that the discrepancy between the results in terms of percentages is quite similar: for NOx 24.8%, for NMVOC 29%, for PM 26%, for SOx 24.3%, for CO 24%, and for CO2 24%. This also indicates that the relative emissions between the gas types are very similar between the two predictive models.

According to both methods, CO2 emission constitutes the major amount of the total emissions. During cruising, CO2 emissions are significantly higher because the duration of cruising is significantly longer than port, maneuvering, and anchorage times. Just to give an idea, the ship’s longest cruise times during this voyage was between Algeciras and Pointe Noire Port which was 251 h (E–F points) and between Douala and Tanger Port (R-S points) with 220.5 h. During these cruises, the main engine consumed 470 tons of 24.

Figure 3 shows the CO2 emissions calculated using the top-down and bottom-up methods in different operation modes. For the top-down method, CO2 emissions were calculated as 86.5 tons for port mode, 59 tons for maneuver mode, 123.6 tons for anchorage mode, and 4232.6 tons for cruising mode. For the bottom-up method, CO2 emissions were calculated as 93.3 tons for port mode, 141 tons for maneuver mode, 130 tons for anchorage mode, and 5571.7 tons for cruising mode.

Fig. 3
figure 3

Comparison of the total CO2 emission according to top-down and bottom-up methods at port, maneuver, anchorage, and cruising modes

Figure 3 shows that for CO2 emissions, there is a remarkable difference for the maneuvering mode (%58) but not a real difference in the port (7%), anchorage (%5.6), and cruising (%24) modes. This is because the load of the ship’s engines is not constant during maneuvering unlike it is during port and anchorage. Therefore, there is a significant difference between calculations using fuel consumption and load. In port and anchorage, the main engine does not work while auxiliary engine’s work balanced.

Regarding the emissions in ports, Fig. 4 shows all gas emissions calculated with both methods in all five ports.

Fig. 4
figure 4

Percentage distributions of total NOx, NMVOC, PM, SOx, CO, and CO2 emissions in ports

Figure 4 shows that percentages are quite similar for both methods. Even though the percentage distribution of all gas emissions in the total is almost the same in the port period, the overall emissions calculated according to the activity-based (bottom-up) approach are higher than the emission values calculated according to the fuel-based approach. It is 33% higher for NOx emission, 41% higher for NMVOC emission, 35% higher for PM emission, and 32% higher for SOx CO, and CO2 emissions.

5.4 Discussion of the results from the two methods

The results of both methods show that the amount of gas released into the atmosphere from the ship’s machinery directly depends on the amount and type of fuel consumed. The amount of fuel consumption in ships is affected by various factors such as the form of the ship, the surface roughness, the condition and the load of machinery on the ship, as well as the weather and sea conditions in the voyage.

We have enough data to be able to claim that bottom-up method calculations are closer to the truth. Various previous studies rightfully claimed that given the use of real-time data pertaining to the ships’ activities, one can operate with the principle that bottom-up method yields better results (Chen et al., 2016); Ng et al., 2013; Jalkanen et al., 2012).

We need to take into account that human error has larger impact on estimates based on fuel consumption than other methods. In terms of fuel consumption data, the amount of fuel might not always be accurate because the flowmeter which provides these data might not be correct. Moreover, there is room for human mistake in tank measurements. The lead author of this study has worked in oceangoing ships for 10 years (3 of which as the chief engineer). Through experience, he knows that occasionally chief engineers might record the fuel consumption differently from the actual consumption in order to correct some other calculation and measurement mistakes or to make up for an abnormal fuel leak.

Even though we accept that fuel-based calculations include some uncertainties, we used both methods to be able to show the differences in results. By comparing the fuel-based method results with the activity-based method results, we observe a difference of about 25%. Even though it might not make too much of a difference for a single ship, it is a significant difference if we apply it to a whole maritime fleet. In order for the gas emission inventories to be built on nearly accurate data, the scientists and policymakers need to decide which method is more true to reality and calculate the emissions accordingly. In order to decide as to which method works better for this purpose, we need to have more that use date from only a single ship or a few ships (Ammar, 2019; Moreno-Gutiérrez et al., 2019; Merien-Paul et al., 2018). Similar to (Chen et al., 2016; Jalkanen et al., 2012; Ng et al., 2013), this study too shows that bottom-up method is better than top-down methods in terms of accuracy. Moreover, it makes an emission estimation with more reliable inputs than methods using AIS data in the bottom-up method.

6 Conclusion and implications

In this study, we present actual data from a container ship, which, in addition to allowing the analysis presented in the study itself, can become basis for future studies of ship emissions. The calculations performed with the top-down and bottom-up method show clear discrepancies at the 20–30% level. These differences could be because of possible inaccuracies in the fuel consumption numbers which are typically manually entered into the ship logs by the crew. Alternatively, these differences may indicate that one of the models is inaccurate in its estimates. This calls for future studies involving direct measurements of the exhaust gases (such as by using a measurement device attached to the ship’s funnel during voyage), which would allow for the validation of the said models or the development of more accurate models.

Regardless of the discrepancies, however, the data presented here show the level of environmental pollution just one container ship can cause. Yet it is possible to reduce their damage by minimizing ship-based emissions. It is a welcome development, therefore, that EU and IMO imposed major limitations on NOx, CO2, SOx, and PM emissions. In considering especially human health in coastal areas, governments should expand ECA regulations and make sure that sanctions are applied globally and not just in the EU and a few other states. The concepts of ‘Green Ship’ and ‘Green Harbour’ need to be brought to the fore to raise environmental awareness.

It is important to note that new technologies can be used to reduce fuel consumption. Moreover, electric propulsion systems should be preferred for the propulsion system for new ships. For the existing ships, their main and auxiliary engines’ exhaust systems should be equipped with exhaust gas scrubber systems (scrubber) and EGR (exhaust gas recirculation) which reduce emissions. Another way to reduce fuel consumption is to use “waste heat recovery systems” which increases energy efficiency, therefore, reducing emissions. These changes would inevitably push international trade ships to employ new machinery technologies and use different contents of fuel. The increase in the cost to the maritime industry might be a small cost to pay in considering the damage that the minimally regulated ship traffic causes to our ecosystem.