1 Introduction

Most studies on greenhouse gas (GHG) mitigation potentials of technologies or policies approach the subject in terms of cumulative emissions, or even future annual emissions (for example Edmonds et al. 2004; Riahi et al. 2005). However, the ultimate purpose of low-carbon technologies is not the abatement of emissions itself, but the avoidance of damages expected from climate change. Between emissions and damages, there is a causal chain of factors such as GHG concentrations in the atmosphere, radiative forcing, global warming, and sea level rise, amongst others. Further down this causal chain,Footnote 1 quantities become successively better proxies for damages from climate change (Udo de Haes et al. 1999), however they also become more uncertain (Lenzen 2006). This is well exemplified in the European Commission’s ExternE study of monetary externalities from electricity generation (Krewitt 2002).

This recognition has led the Brazilian Government to propose a methodology that measures the responsibility of countries for abating GHG emissions in terms of global warming rather than (cumulative) GHG emissions (Federative Republic of Brazil 1997). In essence, because of the long-term lags between emissions and warming effects, this methodology takes into account historical emissions, and hence penalises developed countries with a long and significant emissions history, but favours developing countries that have only recently started to increase their GHG emissions as a consequence of their development trajectory. Although the results of this methodology are associated with additional uncertainty stemming from the emissions-to-impacts conversions,Footnote 2 its benefits lie in the fact that the temperature metric is much more relevant to decision-making than the emissions metric (as explained by Rosa et al. 2004 and Muylaert de Araújo et al. 2007). This aspect forms the main focus of this article.

In order to allocate global warming contributions to countries, one has to formulate an approximation of carbon cycle and climate models, where the temperature increase ΔT(t) at a time t is an additive function of distinct (historical or future) emissions “parcels” ε(t′):

$$ \Delta {\text{T}}\left[ {{\varepsilon_1}\left( {{\text{t}}\prime } \right) + {\varepsilon_2}\left( {{\text{t}}\prime } \right),{\text{t}}} \right] = \Delta {\text{T}}\left[ {{\varepsilon_1}\left( {{\text{t}}\prime } \right),{\text{t}}} \right] + \Delta {\text{T}}\left[ {{\varepsilon_2}\left( {{\text{t}}\prime } \right),{\text{t}}} \right] $$
(1)

Whilst the Brazilian Government had a distinction between countries primarily in mind, the idea of this work is to use the above mathematical formulation of the Revised Brazilian Proposal (RBP; Meira and Miguez 2000) to distinguish energy technologies with regard to their past and potential future contributions to global warming.

Whilst we go to great length in assembling realistic data for specifying future electricity sector scenarios, and justify our assumptions about baselines and excluded emissions, we stress that the purpose of this paper lies less in the actual mitigation potentials that we report, but more in eliciting the differences in mitigation potentials and technology comparisons stemming from emissions and temperature metrics, and therefore in demonstrating how the conclusions suggested to decision-makers depend critically on the choice of metric.

The remainder of this paper proceeds as follows: The next Section will introduce the methodology of the RBP, the scenarios that we apply the RBP to, and our eight technology case studies—various electricity generation technologies, and carbon capture and storage. We define a reference scenario and a low-carbon scenario involving all eight technologies, and through these two scenarios we define our ‘mitigation potentials’. We place particular emphasis on our data sources and the calibration of the RBP climate model. Section 3 contains the mitigation potentials for all eight technologies, broken down into historical (1900–2006) and potential future (2009–2100) contributions. We undertake several analyses to demonstrate the sensitivity of our model. Section 4 discusses the results found and concludes.

2 Methodology

We follow the RBP in decomposing global temperature increase ΔT(t) at a time t into contributions by historical emissions “parcels” ε(t′) . The calculus proceeds in three steps: from historical emissions ε g (t″) of gases g to their atmospheric concentrations Δϱ g (t′) above pre-industrial levels, then to mean radiative forcings ΔQ g (t′), and then to contributions ΔT g (t′) to temperature increases (see Meira and Miguez 2000)

$$ \Delta {T_g}\left( {t\prime } \right) = \frac{1}{C}\int_{{ - \infty }}^t {\left[ {{{\overline \sigma }_g}\left( {{\beta_g}\int_{{ - \infty }}^{{t\prime }} {{\varepsilon_g}\left( {t\prime \prime } \right)} \sum\limits_{{r = 1}}^R {{f_{{gr}}}{e^{{ - \frac{{t\prime - t\prime \prime }}{{{\tau_{{gr}}}}}}}}dt\prime \prime } } \right)} \right]} \sum\limits_{{s = 1}}^S {\frac{{{l_s}}}{{{\tau_{{cs}}}}}{e^{{ - \frac{{t - t\prime }}{{{\tau_{{cs}}}}}}}}dt\prime }, $$
(2)

where

  • ε g (t″) are emissions of gas g avoided by a certain technology in the past, or under a certain future scenario;

  • f gr is the rth of R fractions of gas g decaying in the atmosphere with characteristic time τ gr normalised through \( \sum\limits_{{r = 1}}^R {{f_{{gr}}} = 1} \);

  • β g is the above-pre-industrial atmospheric concentration of gas g per unit annual emission of that gas;

  • the term in the round brackets is the atmospheric concentration Δϱ g (t′);

  • \( {\overline \sigma_g} \) is the change in mean radiative forcing by gas g per unit atmospheric concentration of that gas;

  • the term in the square brackets is the mean radiative forcing ΔQ g (t′);

  • l s is the sth of S fractions of radiative forcing that adjusts with characteristic time τ cs normalised through \( \sum\limits_{{s = 1}}^S {{l_{{cs}}} = 1} \); and

  • C is the heat capacity of the climate system.

Meira and Miguez (2000) point out that Equation 2 ignores non-linearities in the warming response to emissions due to saturation of carbon fertilisation and ocean surface uptake (meaning f gr is a function of t″), and due to saturation of radiative forcings (meaning \( {\overline \sigma_g} \) is a function of Δϱ g (t′)). In their review of the RBP, Enting 1998) and of Den Elzen et al. 1999) note that the calculus considers oceanic but not terrestrial carbon dynamics, and that the atmospheric lifetime of GHGs are concentration-dependent. In response to these criticisms, Rosa et al. (2004) show that the omission of terrestrial processes in the RBP has only a small effect on modelled CO2 concentrations, and that considering non-linear effects reduces contributions both from Annex-I as well as Annex-II countries, and that the balance of effects on absolute and relative contributions is relatively small, and, as such, does not alter the main conclusions from the RBP calculus (Den Elzen 2002; Höhne 2002).

This work focuses on the contribution of electricity-generating technologies to temperature increases. Assume that the GHG emissions resulting from the deployment of technology i over time are ε i,g (t″). Then, the temperature increase at time t′ attributable to the use of this technology over the period [t 0, t′] is calculated using Equation 2, but with technology-specific emissions ε i,g (t″). We also set the two lower integral bounds from −∞ to t 0, in order to restrict the evaluation of the mitigation potential to post-1900 periods with significant emissions. However, most current assessments characterise technology scenarios in terms of their mitigation potentials with respect to a reference scenario (for example Edmonds et al. 2004; Riahi et al. 2005). Assume that in this reference scenario, technology-specific emissions are \( \varepsilon_{{i,g}}^{\text{ref}}\left( {t\prime \prime } \right) \). Then, the mitigation potential \( M_i^{\text{ref}}\left( {t\prime } \right) \) of technology i at time t′ and with respect to reference scenario ‘ref’ is

$$ M_i^{\text{ref}}\left( {t\prime } \right) = \sum\limits_g {\frac{1}{C}} \int_{{{t_0}}}^t {\left[ {{{\overline \sigma }_g}\left( {{\beta_g}\int_{{{t_0}}}^{{t\prime }} {\left\{ {{\varepsilon_{{i,g}}}\left( {t\prime \prime } \right)} - \varepsilon_{i,g}^{\bf ref}(t \prime \prime) \right\}\sum\limits_{{r = 1}}^R {{f_{{gr}}}{e^{{ - \frac{{t\prime - t\prime \prime }}{{{\tau_{{gr}}}}}}}}dt\prime \prime } } } \right)} \right]} \sum\limits_{{s = 1}}^S {\frac{{{l_s}}}{{{\tau_{{cs}}}}}{e^{{ - \frac{{t - t\prime }}{{{\tau_{{cs}}}}}}}}dt\prime } $$
(3)

2.1 Case studies

We investigate eight technologies. Seven of these are electricity-generating technologies: hydro, nuclear, wind, photovoltaic (PV), concentrating solar (CSP), geothermal and biomass power. The remaining technology is carbon capture and storage (CCS). This selection is fairly representative of technologies that are increasingly being considered important in terms of their potential capacity to contribute to a lower-carbon world economy. Currently, only nuclear and hydropower generate significant low-carbon portions of global electricity.

Equation 3 shows that mitigation potentials depend critically on the baseline, and hence the choice of baseline needs to be justified, as well the sensitivity on this choice investigated and explained.Footnote 3

For each technology, we calculate one historical mitigation potential \( M_{{{\text{hist}},i}}^{\text{coal}}\left( {t\prime } \right) \) with t 0 = 1900 and t′ ≤ 2006, where we contrast the historical deployment of this technology with a hypothetical scenario ‘coal’, in which all historically generated electricity would have been produced using coal-fired power plants. We chose this baseline because of a number of reasons: a) it represents a case study that performs worse than all technology scenarios, so that all technology-specific mitigation potentials have the same sign, and are hence easy to interpret for the reader, b) it is relatively easy to establish since it involves only one technology, and c) it is underpinned by high-quality data (as opposed to a biomass power / land-clearing baseline).

To calculate future mitigation potentials, we use two prominent IPCC SRES scenarios (Nakićenović and Swart 2000). We model future evolution of technology deployment to be consistent with SRES storyline B1,Footnote 4 and then contrast this with SRES storyline A2Footnote 5 as reference scenario. The baseline results of this future scenario are time-dependent mitigation potentials \( M_{{{\text{B}}1,i}}^{\text{A2}}\left( {t\prime } \right) \) with t 0 = 2009 and t′ ∈ [2010, 2100]. In addition, we carry out a sensitivity analysis in Section 3. 3. 3 where we contrast storyline B2 with reference A1. The rationale for these choices is as follows: Amongst the SRES scenarios, A2 is associated with the highest emissions, followed by A1, then B2, and finally B1. First, the baseline should always be associated with higher emissions than the future scenario. Second, in order to be comprehensive, the sensitivity analysis should cover large variations in baseline/scenario profiles. Amongst all possible pairs, the storyline pairs A2-B1 and A1-B2 are most varied in their emission profiles, that is, A2-B1 exhibits the largest difference between baseline and scenario, and A1-B2 the smallest difference, thus providing us with the largest variations under which our temperature-based mitigation potentials can be tested for sensitivity.

We calculate emissions ε i,g (t″) in a bottom-up assessment of each technology as

$$ {\varepsilon_{{i,g}}}\left( {t\prime \prime } \right) = {E_i}\left( {t\prime \prime } \right){\eta_{{i,g}}}\left( {t\prime \prime } \right) = {P_i}\left( {t\prime \prime } \right)8760{\text{h}}\,{\lambda_i}\left( {t\prime \prime } \right)\left[ {\eta_{{i,g}}^{\text{ons}}\left( {t\prime \prime } \right) + \eta_{{i,g}}^{\text{ind}}\left( {t\prime \prime } \right)} \right], $$
(4)

where at time t″, for technology i,

  • E i,g (t″) is the annual electricity generated,

  • η i,g (t″) are the emissions of GHG g per unit of electricity generated,

  • P i (t″) is the nameplate capacity installed,

  • λ i (t″) is the average capacity factor,Footnote 6

  • \( \eta_{{i,g}}^{\text{ons}}\left( {t\prime \prime } \right) \) are the on-site emissions of GHG g per unit of electricity generated, and

  • \( \eta_{{i,g}}^{\text{ind}}\left( {t\prime \prime } \right) \) are the indirect (off-site, embodied, life-cycle) emissions of GHG g per unit of electricity generated.

  • there are 8760 h in a year, which is used to convert between power in units of kW and electricity output in units of kWh

Note that we do not model the time lags between indirect emissions and direct emissions, because these time lags are in the order of magnitude of the construction phase of power plants (<10 years), which is much shorter than the atmospheric lifetime of CO2 (which is in the order of centuries). Also, we do not model the temporal profile of indirect emissions; i. e. we do not distinguish between the pulses of emissions occurring during plant construction and decommissioning, and the tails of emissions occurring during operation and maintenance. This is, once again, because these fluctuations occur during the comparatively short lifetime of plants (≈30 years), but also because they are evened out through the overlap of successive plant generations. Further, some technologies, such as CCS and geothermal power, feature a significant part of their indirect emissions throughout their operation phases. We made an exception for hydropower, where we modelled emissions from dams with exponential functions of 7 years half-life (Rosa and Schaeffer 1995) parametrised on the basis of reservoir measurements (Dos Santos et al. 2006). The rationale for making this exception is the fact that these emissions are, to a large part, in the form of CH4, a GHG with a relatively high Global Warming Potential (GWP ≈ 21) but with a short atmospheric lifetime (10–14 years; IPCC 2007). The gases we include—CO2 and CH4 from dams—form the vast majority of emissions from electricity supply systems. We have therefore excluded emissions of other greenhouse gases, and CH4 from sources other than dams. We recognize that aerosols from coal burning in thermal power plants play a role, but because, in contrast to CO2 emissions, they are highly dependent on the different burning technologies utilised, and providing such level of detail was out of the scope of our work.

Finally, we do not include wider, systemic effects of future transitions into account. Whilst effects of future technological changes in the power sector would clearly be felt in all other industry and end-use sectors of any economy, there does to date not exist a comprehensive enough methodological and data foundation to allow their quantification. For example, consequential Life-Cycle Assessment is a method aimed at covering the marginal effects of implementing a technology, and displacing and changing the operation of other technologies, as reflected by market dynamic interactions between technologies and industries.Footnote 7 However, as the IPCC Special Report on Renewable Energy Sources and Climate Change (Sathaye et al. 2011) concludes, “consequential LCAs form the minority of studies in the literature and are so context-dependent as to be incomparable to others such that even the limited results currently available are not included in the broad assessment of this section.”

Amongst the input parameters P, λ, η ons and η ind, the installed capacity P undergoes by far the most significant changes over a period of a century. In this work, the effects of technological change and economies of scale on λ, η ons and η ind were parametrised as linear functions in time, according to

$$ {\lambda_i}\left( {t\prime \prime } \right) = {\lambda_i}\left( {{t_0}} \right) + \left[ {{\lambda_i}\left( {t\prime } \right) - {\lambda_i}\left( {{t_0}} \right)} \right]\frac{{t\prime \prime - {t_0}}}{{t\prime - {t_0}}}, $$
(5a)
$$ \eta_{{i,g}}^{\text{ons}}\left( {t\prime \prime } \right) = \eta_{{i,g}}^{\text{ons}}\left( {{t_0}} \right) + \left[ {\eta_{{i,g}}^{\text{ons}}\left( {t\prime } \right) - \eta_{{i,g}}^{\text{ons}}\left( {{t_0}} \right)} \right]\frac{{t\prime \prime - {t_0}}}{{t\prime - {t_0}}}. $$
(5b)

In addition to changes in technology itself, indirect emissions intensities \( \eta_{{i,g}}^{\text{ind}}\left( {t\prime \prime } \right) \) depend on the overall energy mix of the economies in which the components for power plants are manufactured (Lenzen and Wachsmann 2004). Therefore, as the global energy mix is decarbonised, these intensities decrease. In order to capture this effect, we included in the iterative calculation of future intensities \( \eta_{{i,g}}^{\text{ind}}\left( {t\prime \prime } \right) \) a scaling with the ratio of the carbon intensities χ of electricity mixes in year t″-1 and t 0:

$$ \eta_{{i,g}}^{\text{ind}}\left( {t\prime \prime } \right) = \left( {\eta_{{i,g}}^{\text{ind}}\left( {{t_0}} \right) + \left[ {\eta_{{i,g}}^{\text{ind}}\left( {t\prime } \right) - \eta_{{i,g}}^{\text{ind}}\left( {{t_0}} \right)} \right]\frac{{t\prime \prime - {t_0}}}{{t\prime - {t_0}}}} \right)\frac{{\chi \left( {t\prime \prime - 1} \right)}}{{\chi \left( {{t_0}} \right)}}. $$
(6)

For some technologies, indirect GHG emissions do not only result from plant manufacture, but in part from natural processes such as biomass decay in hydro reservoirs, or increased venting of CO2 from geothermal reservoirs. In these cases, the decrease in future indirect GHG emissions shall reflect a less carbon-intensive background economy, as well as improved technological means to capture natural emissions (DiPippo 2008a; Lima et al. 2008). We model future installed capacity P using time-dependent growth rates r:

$$ {P_i}\left( {t\prime \prime } \right) = {P_i}\left( {{t_0}} \right)\left[ {1 + {r_i}\left( {t\prime \prime } \right)} \right]. $$
(7)

Growth rates are modelled on an annual basis, using a geometric progression \( r(t\prime \prime ) = \gamma r\left( {t\prime \prime - 1} \right) \).Footnote 8 Growth evolves starting at historical values P i (t 0) and r i (t 0), and the parameter γ is chosen in order to realise assumed future outcomes, so that \( {P_i}(t\prime \prime = t\prime ) \) assumes a certain target capacity P i (t′). In summary, a complete emissions scenario ε i,g (t″) for any power technology i is defined by a set of parameters \( \left\{ {{P_i}\left( {{t_0}} \right),{r_i}\left( {{t_0}} \right),\gamma \,{\text{or}}\,{P_i}\left( {t\prime } \right),{\lambda_i}\left( {{t_0}} \right),{\lambda_i}\left( {t\prime } \right),\eta_{{i,g}}^{\text{ons}}\left( {{t_0}} \right),\eta_{{i,g}}^{\text{ons}}\left( {t\prime } \right),\eta_{{i,g}}^{\text{ind}}\left( {{t_0}} \right),\eta_{{i,g}}^{\text{ind}}\left( {t\prime } \right)} \right\} \).

We model the reference scenarios in the same way as in Equation 4, but characterising only total generation E ref(t″) and average emissions coefficients \( \eta_g^{\text{ref}} \):

$$ \varepsilon_g^{\text{ref}}\left( {t\prime \prime } \right) = {E^{\text{ref}}}\left( {t\prime \prime } \right)\eta_g^{\text{ref}}\left( {t\prime \prime } \right) = {E^{\text{ref}}}\left( {t\prime \prime } \right)\left[ {\eta_g^{{{\text{ref,ons}}}}\left( {t\prime \prime } \right) + \eta_g^{{{\text{ref,ind}}}}\left( {t\prime \prime } \right)} \right]. $$
(8)

Finally, we undertake several sensitivity analyses (documented in Section 3.1), by varying the fractions f gr and l s , and their corresponding characteristic times τ gr and τ cs , and by varying GHG emissions coefficients η (documented in Section 3.2).

2.2 Data sources

Our sources of data are summarised in Badcock and Lenzen 2010. Appendix A gives an abbreviated overview.

3 Results

3.1 Historical mitigation potentials

Historical electricity generation data (Fig. 1) can be converted into historical emissions from the power sector (Fig. 2) by applying Equation 4, supported by historical emissions coefficients ε. Emissions in 2006 amounted to 11.4 Gt CO2, which corresponds with data given in IEA 2008).

Fig. 1
figure 1

Historical trends in electricity generation

Fig. 2
figure 2

Historical trends in CO2 emissions; annual (left) and cumulative (right)

Applying Equation 3 to the historical avoided emissions “pulse” \( {\varepsilon_{{i,g}}}\left( {t\prime \prime } \right) - \varepsilon_{{i,g}}^{\text{coal}}\left( {t\prime \prime } \right) \) calculated from the emissions profiles in Fig. 2 yields mitigation potentials \( {\text{M}}_{{{\text{hist}}i}}^{\text{coal}}\left( {t\prime } \right) \) in Fig. 3. The vertical axis shows the negative contributions of the various conventional power technologies to global temperature increase, or in other words, avoided temperature increase. These contributions are with respect to a hypothetical past where all electricity would have been generated using coal. As a result, coal does not exhibit any mitigation potential.

Fig. 3
figure 3

Historical mitigation potential \( M_{{{\text{hist,i}}}}^{\text{coal}}\left( {t\prime } \right) \), carried forward to 2100

The avoided emissions pulse occurs between 1900 and 2006, and drives a sharp increase of the avoided temperature increase until 2006. After this, avoided emissions cease, and avoided temperature increase declines according to the weighted response functions as in the integral calculus in Equation 3. Due to the additivity property of the RBP formulation (Equation 1), the contributions of the technologies can be added to yield a total \( \sum\limits_i {{\text{M}}_{{{\text{hist}}i}}^{\text{coal}}\left( {2006} \right)} \) of about −0.1°C. Past usage of low-carbon technologies such as nuclear and hydropower, but also fuel switching to natural gas has a clear mitigation effect far beyond the deployment period of the technologies, amounting to 0.06°C avoided temperature increase in 2100.

3.2 Future mitigation potentials

Using the various constraints described in Appendix A, and prescribing total electricity demand according to the SRES B1 scenario (Nakićenović and Swart 2000), a technology scenario can be fitted “into” the SRES B1 (Fig. 4). Since this work is aimed at demonstrating the translation from emissions to temperature increase, and not at investigating the SRES scenarios, we did not attempt at exactly reproduce the B1 scenario (inset in Fig. 4), but rather incorporated recent developments such as strong renewables growth. As a result, renewables “take off” more rapidly especially between 2030 and 2050 (except geothermal at 2070), but fossil-fuel power catches up around 2070 due to strong demand growth.

Fig. 4
figure 4

Future electricity generation scenario modelled according to the constraints described in Appendix 1, and by electricity demand prescribed by the SRES B1 scenario (inset)

The electricity generation scenario (Fig. 4) can be converted into a CO2 emissions scenario from the power sector (Fig. 5) by applying Equation 4, supported by emissions coefficients η.

Fig. 5
figure 5

Future CO2 emissions; annual (left) and cumulative (right). Net emissions for CCS and biomass are split into positive (combustion) and negative (capture/sequestration) components

Even though the power mix is more and more penetrated by low-carbon sources, annual and cumulative emissions dominate due to fossil-fuel combustion. Emissions from nuclear and renewable power sources are indirect emissions only. In contrast to Fig. 3, capture and biomass sequestration of CO2 are shown in Fig. 5 as negative contributions. Carbon capture and storage CO2 is net of CO2 expended for manufacture of infrastructure, and operation of all capture, transport and storage facilities.

Applying Equation 3 once again to the future avoided emissions “pulse” \( {\varepsilon_{{i,g}}}\left( {t\prime \prime } \right) - \varepsilon_{{i,g}}^{\text{A2}}\left( {t\prime \prime } \right) \) calculated from the emissions profiles in Fig. 5 yields mitigation potentials \( {\text{M}}_{{{\text{B1,}}i}}^{\text{A2}}\left( {t\prime } \right) \) in Fig. 6. These are now with respect to a more emissions-intensive SRES A2 scenario.

Fig. 6
figure 6

Future mitigation potentials \( {\text{M}}_{{{\text{B}}1,i}}^{{{\text{A}}2}} \)

This time, coal exhibits a positive contribution to temperature increase, because the SRES A2 scenario is less carbon-intensive than a power generation system based purely on coal. In temperature anomaly terms, it causes a warming offset of about 0.1°C by 2100, which all other technologies have to compensate. Biomass is shown inclusive of natural sequestration. As low-carbon technologies penetrate the generation system, significant avoided temperature increase start developing after 2040. Once again, due to the additivity property of the RBP formulation (Equation 1), the contributions of the technologies can be added to yield a total \( \sum\limits_i {{\text{M}}_{{{\text{B1,}}i}}^{\text{A2}}\left( {2100} \right)} \) of about −0.76°C.

A comparison of technologies yields interesting insights about the significance of expressing the mitigation potential of technologies in terms of annual emissions, cumulative emissions, or avoided temperature increase (Tables 1 and 2).Footnote 9 The selection of technologies comprises a group of established technologies such as gas, nuclear and hydro, and a set of “newcomers” such as non-hydro renewable and carbon capture and storage. Some of these new technologies start making a significant contribution to emissions reductions only after 2030.

Table 1 Summary of annually and cumulatively avoided CO2–equivalent emissions, and contributions to global temperature increase, including CH4 effects for hydro reservoirs
Table 2 Summary of annually and cumulatively avoided CO2–equivalent emissions, and contributions to global temperature increase, including CH4 effects for hydro reservoirs (in % of total effects for all technologies)

Take, for example, hydropower. The 2030 percentage contributions in terms of annual avoided emissions (39%) and cumulatively avoided emissions (55%) are significantly lower than those in terms of avoided the 2030 temperature increase (62%). This discrepancy demonstrates that emissions are deficient in representing contributions to global warming. Similarly, nuclear power avoids 28% of annual emissions in 2030, 43% of cumulative emissions up to 2030, but avoids 51% of the 2030 temperature increase. In contrast, wind power avoids 29% of annual emissions in 2030, 22% of cumulative emissions up to 2030, but avoids only 19% of 2030 temperature increase.

These results demonstrate the benefit of early technology deployment. Hydropower is avoiding emissions at significant scales at the scenario outset (Fig. 3), and those early avoided emissions are “worth” more in terms of the response functions in the integral formulation (Equation 4). Similar observations can be made for gas and nuclear power.

In 2100, nuclear avoids less emissions than geothermal power, and until then has avoided about the same amount of cumulative emissions. However, due to the late start of geothermal, nuclear power’s avoided temperature increase is 7% higher at 17% than that of geothermal power (10%). The stark difference between nuclear and hydropower in terms of 2009–2030 avoided temperature increase is due to significant CH4 emission from newly commissioned hydro reservoirs. Due to the short impact lifetime of CH4, the difference between the technologies virtually disappears by 2100.

Similarly, relative to 2006, hydropower was an established technology compared to the more recent nuclear power, and hence hydro’s 2006 historical mitigation potential is higher in terms of avoided temperature increase than in terms of cumulative emissions, and vice versa for nuclear power. These effects, even though illustrative for this particular scenario only, demonstrate the conflicting conclusions derived from different measures for mitigation potential.

In percentage terms, long-term (2100) mitigation potentials converge towards long-term cumulative emissions, because the differences between technologies in start-up now fall into the tail periods of the response functions, so that the distinction between early and late technologies becomes blurred.

3.3 Sensitivity analyses

3.3.1 Using different carbon cycle and global warming models

We investigated the sensitivity of our results with regard to the parameters used in the climate model as expressed in Eqs. 2 and 3. Due to the lack of standard deviation estimates for the various parameters, we resorted to substituting the ‘Bern TAR’ paramater setFootnote 10 for the RBP parameter set,Footnote 11 and recalculated all results. These two parameter sets are quite different in both characteristic times and fractions, thus our sensitivity analysis could be regarded as conservative.

Moving from the RBP set to the Bern TAR set, the mitigation potentials of established technologies such as gas, nuclear and hydropower decrease by about 5%, and the mitigation potentials of new technologies such as CSP, CCS and geothermal increase by between 5% and 25% (Table 3). This behaviour is due to the fact that the Bern TAR set places more emphasis on long-term responses, which is mainly facilitated by \( {\tau_{{{\text{C}}{{\text{O}}_2},1}}} = \infty \). Technologies with intermediate temporal profiles such as wind are unaffected. Similarly, the overall mitigation potential of all technologies increases only slightly from \( \sum\limits_i {{\text{M}}_{{{\text{B}}1,i}}^{{{\text{A}}2}}\left( {2100} \right) = 0.76^\circ {\text{C}}} \) to \( \sum\limits_i {{\text{M}}_{{{\text{B}}1,i}}^{{{\text{A}}2}}\left( {2100} \right) = 0.77^\circ {\text{C}}} \).

Table 3 Comparison of mitigation potentials calculated using ‘RBP’ or ‘Bern TAR’ parameter sets

3.3.2 Emission coefficients

A sensitivity analysis of emission coefficients is best carried out on those coefficients that could undergo potentially large changes. One such candidate are life-cycle CO2 emissions associated with nuclear power. In their analysis of emissions from the nuclear fuel cycle, Storm van Leeuwen and Smith (2005) arrived at significantly higher values than listed in Table 7, which for low ore grades of about 0.01% U are about 530 g/kWh, and hence would place nuclear power into the vicinity of advanced natural gas plants. As Lenzen et al. (2006) show, this discrepancy is mainly the result of practices assumed by Storm van Leeuwen and Smith (2005) (but not applied currently, see p. 18 in OECD NEA and IAEA (1999) for the final disposal of large volumes of low-level ore, waste rock, and mill tailings. The worst case in Lenzen et al. (2006) results in emissions of 248 g/kWh, which also agrees with the maximum value found by Sovacool (2008), but even this case is still below the estimate made by Storm van Leeuwen and Smith (2005).

Applying the RBP calculus under quadrupling of life-cycle emissionsFootnote 12 reduces nuclear’s mitigation potential for the century by about 10% (Table 4). This shows that considering the objective of limiting global warming, nuclear’s mitigation potential is relatively insensitive to even extreme changes in life-cycle emissions.

Table 4 Comparison of mitigation potentials of nuclear power, under variations of life-cycle emissions

A sensitivity analysis of CH4 emission factors for hydropower is interesting because emissions from hydro reservoirs have not been measured often and well, and are also highly dependent on the biomass density at the reservoir location. Varying the values of 200 g CO2-e/kWh and 7 years half life given by Dos Santos et al. (2006) and Rosa and Schaeffer (1995) yields that the mitigation potential of hydro decreases with increasing CH4 emissions intensity and half-life (Table 5).9

Table 5 Comparison of mitigation potentials of hydropower, under variations of CH4 emissions

Since characteristic times of anaerobic decay and CH4 atmospheric lifetime (around 10 years) are short compared to the characteristic times of the climate system, mitigation potentials for temperature increase due to hydropower deployment are relatively weakly affected by assumptions about reservoir emissions. Nevertheless, the differences in sensitivity between the three quantities clearly show once again that annual or cumulative emissions are deficient yardsticks when comparing technologies with respect to their impact on global warming.

3.3.3 SRES scenarios

In the last sensitivity analysis, we examine the influence of the SRES scenarios on mitigation potentials. We changed both the scenario used to envelope future electricity demand (from B1 to B2Footnote 13), as well as the reference scenario (from A2 to A1F1Footnote 14). The main differences between the changed scenario settings are that: a) in B2 nuclear power plays a more important role, and renewables play a less important role than in B1; b) in B2 electricity generation and emissions are both higher than in B1, and c) in A1F1 reference CO2 emissions are lower than in A2 (Fig. 7). Note that the purpose of pairing these scenarios is not to examine the role of socio-economic-demographic drivers for mitigation potentials, but to obtain a large but realistic variation under which our temperature-based mitigation potentials can be tested for sensitivity, as explained in Section 2.1.

Fig. 7
figure 7

Future electricity generation scenario modelled according to the constraints described in Appendix 1, and by electricity demand prescribed by the SRES B2 scenario (inset)

With the obvious exceptions of nuclear power and coal, mitigation potentials change negligibly (Table 6). As nuclear power’s share is larger in B2 compared to B1, its mitigation potential almost doubles to −22.6 centigrades. With coal-based generation being calculated residually, coal’s negative mitigation potential (ie warming potential) almost halves to 7.0 centigrades. For the remaining technologies, the differences between the two scenario settings are due to the reference being changed from A2 to A1F1.

Table 6 Comparison of mitigation potentials calculated using the B1/A2 or B2/A1F1 scenario sets

4 Conclusions

Using the mathematical formalism of the Brazilian Proposal to the IPCC, we have analysed eight technologies—seven electricity generation technologies, and carbon capture and storage—with regard to their past and potential future contributions to global warming. We have defined the mitigation potential of each technology in terms of avoided temperature increase by comparing a “coal-only” reference scenario and an alternative low-carbon SRES scenario. We have taken into account detailed bottom-up technology characteristics such as life-cycle emissions and capacity factors.

Historically (1900–2006), hydro, nuclear, and gas-fired power have achieved the largest mitigation, at 0.03°C, 0.02°C, and 0.015°C avoided by 2100, respectively. This ranking is partly due to the magnitudes at which these technologies are deployed, but in part also due to their deployment histories. For example, the global capacity of gas-fired power plants is larger than that of hydropower plants, however significant hydropower capacity has been around for many more decades.

Similarly, potential future (2009–2100) contributions are influenced by the magnitude of future capacity as well as the temporal deployment profile. For example, even if geothermal power equalled hydropower capacity by 2050, the 2100 temperature increase avoided by hydropower would be larger because of its cumulative avoidance of radiative forcing over time. A general conclusion is that early technology deployment matters, at least within a period of 50–100 years. We undertake several analyses to demonstrate the robustness of these conclusions.

Our results show conclusively that avoided temperature increase is a better proxy for comparing technologies with regard to their impact on climate change. As we show in Table 2, comparisons based on cumulative emissions up to 2050 yield results that are significantly different to those obtained using the avoided temperature metric. Using annual instead of cumulative emissions may yield misleading results for mitigation potentials calculated even up to 2100. Appendix B shows that the literature contains numerous examples of mitigation potentials being calculated up to 2050, based on annual and cumulative emissions. The findings of this study indicate that such examples are less meaningful for decision-making than previously thought.

Our results support the Brazilian Proposal to the IPCC, and also extend its policy relevance in the sense that not only comparisons between countries, but also comparisons between technologies or technology portfolios could be undertaken on the basis of avoided temperature increase rather than on the basis of annual emissions as is practice today.

Whilst the aim of this paper is fulfilled by exemplifying technologies for electricity generation in order to highlight the role of metrics for establishing mitigation potentials, the same approach can be applied to comparisons of scenarios differing with regard to other criteria. This is essentially because ultimately the only input into calculating mitigation potentials are emission profiles. Hence, the avoided-temperature metric could also be applied to establishing mitigation potentials of different trajectories of population, economic development, or urban structure, amongst many other possibilities.