Abstract
We report the influence of the type of organosilica precursors on the growth of organosilica domains and the interfacial interaction between polyimide (PI) and organosilica in PI/organosilica hybrid composite films. The organosilica precursors used are tetraethoxysilane (TEOS), triethoxy(ethyl)silane (TEES), and 1,2-bis(triethoxysilyl)ethane (BTSE). The hybrid composite films were prepared by thermal imization of the precursor films that were made via sol-gel process of the mixture of poly(4,4’-oxydianiline benzenetetracarboxamic acid) (PMDA-ODA PAA) and organosilica precursors. The hybrid composite films were characterized using Fourier transform infrared (FT-IR) spectra, 29Si cross polarization (CP) MAS-NMR spectra, field emission-scanning electron microscopy (FE-SEM), UV-visible spectra, small angle x-ray scattering (SAXS), dynamic mechanical analysis (DMA), and thermogravimetric analysis (TGA). The results showed that the TEES precursor was more pronounced in improving the interaction of corresponding organosilica with PI than other precursors.
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References
Seino H, Mochizuki A, Ueda M (1999) J Polym Chem 37:3584
Hedrick JL, Cha HJ, Miller RD, Yoon DY, Brown HR, Srinivasan S, Di Pietro R (1997) Macromolecules 30:8512
Ha CS, Cho WJ (2000) Polym Adv Technol 11:145
Huang JC, He CB, Xiao Y, Mya KY, Dai J, Siow YP (2003) Polymer 44:4491
Wu KH, Chang TC, Yang JC, Chen HB (2001) J Appl Polym Sci 79:965
XD, Zhong ZX, Jin G (2006) Macrmol Res 14(3):257
Jang YM, Seo JY, Chae KH, Yi M H (2006) Macrmol Res 14(3):300
Mathews AS, Kim I, Ha CS (2007) Macromol Res 15(2):114
Ogoshi T, Chujo Y (2005) Compos Interf 11:539
Salomone JC (1996) Polymeric Materials Encyclopedia, CRC Press, New York, 8:6253
Takeichi T, Tanikawa M, Zuo M (1997) J Polym Sci Part A: Polym Chem 35:2395
Wahab MA, Kim I, Ha CS (2003) Polymer 44:4705
Choi SW, Kim YK, Kim I, Ha CS (2007) J Appl Polym Sci 103:2507
Im JS, Lee JH, An SK, Song KW, Jo NJ, Lee JO, Yoshinaga KJ (2006) J Appl Polym Sci 100:2053
Zhu ZK, Yin J, Cao F, Shang XY, Lu QH (2000) Adv Mater 12:1055
Cornelius CJ, Marand E (2002) Polymer 43:2385
Kioul A, Mascia L (1994) J Non-Cryst Solids 175:169
Kim Y, Lee WK, Cho WJ, Ha CS, Ree M, Chang T (1997) Polym Int 43:129
Choi SW (2006) M. S. Thesis, Pusan National University, Korea
Mascia L, Kioul A (1995) Polymer 36:3649
Ha Y, Kim Y, Ha CS (2008) Polymer Bulletin 59:833
Chang CC, Chen WC (2002) Chem Mater 14:4242
Srinivasan SA, Hedrick JL, Miller RD, Di Pietro R (1997) Polymer 38:3129
Glaser RH, Wilkes GL, Bronnimann CE (1989) J Non-Cryst Solids 113:73
Joseph R, Zhang S, Ford WT (1996) Macromolecules 29:1305
Young SK, Jarrett WL, Mauritz KA (2002) Polymer 43:2311
Kim Y (1996) Ph.D. Dissertation, Pusan National University, Korea
Kim Y, Ree M, Chang T, Ha CS, Nunes TL, Lin LS (1995) J Polym Sci Part B: Polym Phys 33:2075
Kim Y, Goh WH, Chang T, Ha CS, Ree M (2004) Adv Eng Mater 6:39
Jeng U, Hsu CH, Lai YH, Chung WT, Shen HS, Lee HY, Song YF, Liang KS, Liu TL (2005) Macromol Res 13(6):506
Russel TP, Brown HR (1987) J Polym Sci: Part B: Polym Phys 25:1129
Ochi M, Takahashi R (2001) J Polym Sci: Part B: Polym Phys 39:1071
Kweon JO, Noh ST (2001) J Appl Polym Sci 81:2471
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Son, M., Han, S., Han, D. et al. Organic/Inorganic Hybrid Composite Films from Polyimide and Organosilica: Effect of the Type of Organosilica Precursors . Polym. Bull. 60, 713–723 (2008). https://doi.org/10.1007/s00289-008-0904-z
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DOI: https://doi.org/10.1007/s00289-008-0904-z