Abstract
The implementation of the Water Framework Directive (EU 2000) requires a groundwater quality monitoring. It is used for characterisation of the ‘good’ chemical status of each groundwater body and for the restoration or protection purposes of those bodies already at ‘good’ status. Interpretative aspects are lying in the design of monitoring network and in the way of building global indicators. Attention is given here to the global chemical status of the groundwater bodies and to the role of diffuse pollution, much of which is brought via groundwater to surface water. Monitoring ‘local’ pollution associated with individual sites is not addressed. Groundwater bodies with different contrasted hydrogeology conditions, land use and topography have been considered to establish an approach for choosing an optimised monitoring network. Then, a quality assessment system has been developed and applied for qualifying the general status of each groundwater body. The use of non-dimensional indexes allows us to process with all kinds of chemical parameters in a normalised way and, by means of adequate aggregation rules, to qualify the general quality status of a groundwater body. The obtained diagnostic, even if not fully validated, is closely linked to the pragmatic objectives contained in the EU Water Directive.
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Introduction
Groundwater is an essential component of the hydrological cycle. It supplies up to 80% of public water demand in Walloon Region of Belgium. Indeed, it also provides critical support to the wider aquatic environment and associated ecosystems. Like in many countries, much of the recent improvement in river water quality can be attributed to the reduction in the direct discharge of pollutants from point sources of contamination. The attention is now turning to the role of diffuse pollution, much of which occurs via groundwater (Ward et al. 2004).
The European Water Directive 2000/60/CE establishing a framework for Community actions in the field of water policy aims at coordinating the Member states’ water management within the international river basin districts. The directive sets three general objectives concerning groundwater: (1) to prevent deterioration, (2) to enhance and restore in order to achieve good water status at the latest in 2015, and (3) to reverse any significant and sustained upward trend of any pollutant. Member States are requested to establish monitoring programmes to characterise groundwater chemical and quantitative status. All substances resulting from the impact of human activity must be controlled.
Understanding the spatial distribution of groundwater quality and determination of temporal groundwater quality trends is essential to design the monitoring tools, to decide about the required networks, and to choose aggregation techniques for providing reliable ‘indicators’ at the groundwater body scale.
A strategic framework has been recently designed for groundwater quality monitoring in the Walloon Region of Belgium. The methodology that has been applied for optimising the monitoring of network and to calculate aggregated indicators at the groundwater body scale is described hereafter and illustrated on the example of the Hesbaye aquifer located near the city of Liège in Belgium.
Objectives
Natural groundwater quality is mainly dependent on the geochemical processes that take place when rain or surface water infiltrates the ground and reacts with the soils and rock-forming minerals. Impacts of human activities and the release of pollutants to the aquatic environment are superimposed on this natural quality status. However, it should be noted that the quality of rainwater may have already been strongly affected by human activities. Pollutants are various in nature and include synthetic organic chemicals, hydrocarbons, inorganic cations and anions, pathogens, radionuclides, etc. It is beyond the scope of this work to discuss about monitoring well design, equipment installation, well sampling in depth averaged conditions or multi-level sampling, and quality assurance of the chemical analysis, but all these issues may strongly influence chemical results. Within the framework described here, mainly the two following questions will be addressed. How can we select the sampling points in order to obtain a representative monitoring network? How can we aggregate the results in simplified but reliable indicators readable by decision makers?
Groundwater quality cannot be interpreted from a static point of view, i.e. assuming stationary conditions both at the site of infiltration and along the possible flow line, without reversals of flow patterns in time (Appelo and Postma 1993). It varies spatially in relation to residence time, aquifer mineralogy, chemical environment, spatial variation in land use and associated polluting activities. To understand the temporal as the spatial groundwater quality changes, a reliable understanding of the groundwater body is needed. So, hydrogeological characterisation is required before ‘optimising’ the monitoring network.
Specifically, the monitoring network must: (a) be compliant with Walloon and European commitments, (b) provide objective, reliable and comparable information, (c) define natural or ‘patrimonial’ groundwater conditions, (d) allow determination of trends, (e) provide early warning of groundwater pollution, and (f) identify hydraulic and geochemical interactions with surface water systems.
Selection of monitoring points
The EU working group on the implementation of the Water directive recommends a density of about 1 point/25 km2, where the groundwater body is expected to be ‘under pressure’, and 1 point/100 km2 otherwise. A spatial representativity within each body through scientific judgement is also recommended. A representativity index R U has been proposed and it should reach a value of 80% (WFD-GW 2001):
where d is the mean distance from any point of the groundwater body to the nearest sampling point, n, the number of sampling points, A, the total area of the groundwater body.
Rather than applying blind geostatistics, it is here preferred to give more importance to the conceptual model/understanding of the groundwater system and how pressures interact with that system. The proposed criteria for selection of sampling points are among others, the following:
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upward or downward position of the measurement point (with respect to the piezometric gradient);
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integrating/representative character of the measurement/sampling point;
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natural (or man induced) variability of already available historical measured data;
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absence of point contamination sources;
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accessibility of the measurement/sampling point;
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knowledge and reliability about the well equipment (position and length of the screens); and
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present status and ownership of the well.
The groundwater body of the Geer basin can be taken as an example. It provides about 60,000 m3/day of drinking water for the city of Liege and its suburbs (Dassargues and Monjoie 1993). The Hesbaye plateau extends over about 350 km2. Altitudes range from 206 m in the southwest to 80 m in the north-eastern part of the region. From top to bottom, the substratum is made up of (Brouyère et al. 2004):
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a Quaternary loess of variable thickness, up to 20 m;
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a maximum of 10 m of a flint conglomerate, highly heterogeneous geological formation made of dissolved chalk residues (flints, sand, clay and local phosphate);
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locally, several meters of Tertiary sand deposits, mostly in the north of the Geer basin, where they take the place over the flint conglomerate;
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Cretaceous chalks forming the main reservoir of the Hesbaye aquifer, showing depths ranging from a few meters in the south up to 100 m in the north-eastern part of the basin; and
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at the bottom, several meters of smectite clay of low hydraulic conductivity, considered as the aquifer base.
The mean hydraulic gradient in the aquifer is north oriented, ranging from 0.01 in the south to 0.003 in the north, close to the Geer River (Dassargues and Monjoie 1993). The groundwater table is located at depths ranging from 10 m to more than 40 m below the land surface.
Most of the aquifer is unconfined, except in the north, where semi-confined conditions prevail under the Geer alluvial deposits. Fractured zones in the chalk also correspond to dry valleys visible in the surface morphology. Finally, dug in the lower part of the chalk, 40 km of galleries belonging to a local water company play a key role in the shape of the piezometric surface. Groundwater is drained in most portions of the galleries but an important quantity of water is also recharged from the galleries into the aquifer in other zones, depending on local differences between water levels in the aquifer and in the galleries. Apart from the galleries, the aquifer is exploited by pumping wells owed by water companies, local industries and agricultural settlements.
Since 1960, nitrate concentrations have risen annually at a rate ranging from 0.1 mg/l (as NO3) in the semi-confined to 1 mg/l in the unconfined part of the aquifer. Presently, the mean concentration is around 35 mg/l, from 20 mg/l at the aquifer bottom to more than 175 mg/l in the contaminated zones from the upper aquifer (Brouyère et al. 2003).
According to the guidelines (Eurowaternet 1998), about 14 points were required. These 14 selected sampling points, among 556 available points, are selected through a scientific hydrogeological judgement based on previous studies of this aquifer (Dassargues et al. 1988; Dassargues and Monjoie 1993; Hallet 1998; Brouyère 2001, Brouyère et al. 2003). The obtained spatial distribution is shown in Fig. 1.
Among those 14 selected points, 7 correspond to pumping wells or outlets of draining galleries belonging to water companies, 7 are sampling piezometers.
Groundwater quality assessment system
All substances resulting from the impact of human activity must be controlled. A groundwater quality assessment system named SEQ-ESO (for ‘Système d’Evaluation de la Qualité des Eaux Souterraines’), originally developed by the French Water Agencies (Agences de l’Eau 2002) has been adopted. The main principles of this system will be described hereafter. In order to satisfy the requirements of the Water Framework Directive, this system has been developed for qualifying the general hydrochemical status of groundwater bodies by means of aggregation techniques of groundwater quality measurements from a representative monitoring network.
In order to examine all compounds with a normalised scale, each value is converted into a non-dimensional index according to simple interpolation lines and curves between the thresholds. The parameters are then grouped together into consistent packages called ‘alterations’. The quality class for each alteration is given by the index of the most problematic compound of the group (security choice) for this considered alteration. This allows synthesising greatly the concept of groundwater quality. Not entering in to too much detail, the following alteration groups have been distinguished:
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mineralisation and salinity (pH, hardness, Cl, SO4, ...);
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organic matter and nutrients (N, P, TOC, ...);
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filterable elements and particles (NTU, Fe, Mn, Al, ...);
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mineral micro-pollutants (Cu, Zn, As, B, Cn, Cd, ...);
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pesticides; and
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PAH (Polycyclic Aromatic Hydrocarbons) and other organic pollutants (PCE, TCE, HCB index, ...).
Basically, the SEQ-ESO provides an interpretation grid of a complete protocol analysis related to a single water sampling point. The system is based on the establishment of parameter thresholds defining quality classes.
Groundwater quality assessment is a relative concept depending on water use. As far as groundwater is concerned, the SEQ-ESO system considers three essential functions for groundwater:
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1.
Water use: the quality of water compared to the standards or needs corresponding to various uses is defined. The principal use introduced into the SEQESO is the aptitude for Drinking Water Use (DWU). Other uses of water in such areas as industry, energy, the irrigation and the drenching can also be evaluated.
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2.
Patrimonial status (PS): It expresses the degree of degradation of groundwater due to impacts of human activities without reference to any specified use. This scale of deterioration of the groundwater quality is based on indicating solute concentrations not present at the natural state (organic and mineral micro-pollutants) or clearly identified as a result of specific human activities when lying above known thresholds (nitrates and pesticides).
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3.
The chemical aptitude of groundwater for biology needs in surface water biotopes (BIO): In this function, different surface water physico-chemical quality status are taken into account for assessing the required groundwater quality. It thus makes the assumption of a 100% feeding of the river by groundwater.
At this stage of the research, this third function of water is not discussed. For each of the two other functions DWU and PS, specific threshold concentration values are chosen following the guidelines given in Table 1. Results of an application of theses guidelines for the particular case of nitrates are shown in Fig. 2.
A major advantage of the SEQ-ESO consists in the possibility of combining two functions. Combining the DWU and PS functions, to obtain a general expression of the Groundwater Quality (GWQ), as illustrated in Fig. 2 for nitrate, it is observed that the two first thresholds for Groundwater Quality are dictated by the PS function when the others are prescribed by the DWU function.
Each GWQ threshold is then converted by interpolation into a general quality index (I g) ranging from 100 (best quality) to 0 (worst quality).
Application of the SEQ-ESO system to the Geer groundwater body is illustrated in Fig. 3. At each sampling point of the monitoring network, the limitating compound with respect to the Drinking Water Use (DWU, Fig. 3a), to the PS (Fig. 3b) and finally to the general Groundwater Quality (GWQ, Fig. 3c) can be identified.
Building of an aggregated indicator
In order to satisfy the requirements of the EU Water Directive, the SEQ-ESO has been developed to assess the global quality of groundwater in the whole groundwater body. The SEQ-ESO uses aggregation techniques through a simple arithmetic mean as prescribed by the directive. Data from each site of the monitoring network must be aggregated into a single global quality indicator (with respect to the water function). The two first steps of the aggregation are the following:
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1.
Each measured compound concentration is normalised using an index between 0 and 100.
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2.
For each compound and in each point, an arithmetic mean is calculated over a considered period of time providing a PMI (Point Mean Index).
Then, two different techniques may be worked out. A first one can be qualified as a ‘compound aggregation technique’, where:
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(c1)
For each compound, averaging the PMI from the sampling points provides a BMI (groundwater Body Mean Index).
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(d1)
For each alteration, the minimum of BMI values provides the final indicator (an index value per alteration and per groundwater body).
A second aggregation technique can be qualified as an ‘alteration aggregation technique’:
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(c2)
For each point, the minimum among the PMI of a given alteration provides a PMA (Point Mean Alteration).
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(d2)
The PMA arithmetic mean over the whole monitoring network provides the indicator (an index value per alteration and per groundwater body).
A synthetic example is given in Table 2 with a monitoring network composed of four points (X1, X2, X3, X4) and an alteration evaluated from three compounds (P1, P2 et P3). All PMI obtained after the first two steps are given within the three first lines of Table 2. This example clearly illustrates the difference. Results would be similar only if an alteration contains only one parameter, in all other cases the second technique (alteration aggregation) is penalising. It can be demonstrated that the indicator calculated by this last technique will always be smaller than the one calculated by the first technique. Moreover, this effect is accentuated if the point measurement variability is high. The compound aggregation gives an insight of the global contamination problem, whereas the alteration aggregation emphasises a possible local contamination not necessarily representative of the whole groundwater body. Therefore, it seems to be consistent to adopt the ‘compound aggregation’ as the standard aggregation technique.
General groundwater quality indicator
Tests have been performed on five very different groundwater bodies belonging to the hydrographic district of the river Meuse in the Walloon Region of Belgium (Rentier et al. 2004) and with different contrasted geological and hydrogeological conditions: Cretaceous chalk, Carboniferous limestone and Pleistocene gravel of the alluvial plain of the river Meuse.
Results obtained with the SEQESO for Cretaceous chalks of the Hesbaye groundwater body are given in the example in Fig. 4 as a summary quality sheet. It appears that the minimum index is found for alteration ‘nutrients and organic matters’ due to relatively high monitored nitrate concentrations. This minimum index is automatically taken as the global index and a ‘medium status’ is assessed for this groundwater body.
Conclusions
A framework is described for designing a groundwater quality monitoring network. It is fully compliant with the EU commitments. The last step, leading to the “water quality characterisation” of a groundwater body in the frame of the EU Water Directive, can be performed with the use of a decision sheet as the one described in Fig. 5.
The SEQ-ESO system is a powerful tool to evaluate the chemical status of a groundwater body. From the examination of the groundwater uses and other functions, in particular the concept of PS, a general quality assessment scale has been built. The use of non-dimensional indexes allows the processing of all normalised concentration values gathering them into groups called ‘alterations’, and, by means of proper aggregation rules, to qualify the general status of a groundwater body from the data of a representative network of groundwater in the water-framework directive.
A first set of thresholds, corresponding to the different quality levels are now operational. However, the SEQ-ESO can be considered as an instrument that can evolve. For example, one can reinforce criteria for certain compounds accounting for the biodiversity in the dependent surface ecosystems. It is as obvious that the key thresholds could still be retuned in function (for example) of new groundwater quality standards.
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Rentier, C., Delloye, F., Brouyère, S. et al. A framework for an optimised groundwater monitoring network and aggregated indicators. Environ Geol 50, 194–201 (2006). https://doi.org/10.1007/s00254-006-0200-x
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DOI: https://doi.org/10.1007/s00254-006-0200-x