Abstract
Fullerenen-propylamine platinum, rhodium complex have been prepared from C60 via amination withn-propylamine, then reacting respectively with potassium chloroplatinite or rhodium chloride. The two noble metal complexes can effectively catalyze hydrosiiylation of olefins with triethoxysilane. The Pt complex exhibits high regioselectivty for styrene, nearly 100% branched product is obtained.
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Nagashima H, Nakaoka A, Saito Y,et al. C60Pdn: The first organometallic polymer of buckminsterfullerene.J Chem Soc, Chem Commun, 1992(4):377–379
Izumi Y, Hikazudani S, Aika K I. Ruthenium catalyst on fullerence C60 for ammonia synthesis.Shokubai, 1995,37(6): 466–468
Ymag S, Yanagawa M, Nakamura E. Tertiary phosphines and p-chiral phosphinities bearing a fullerene substituent.J Chem Soc, Chem Commun, 1994(18):2093–2094
Liu Ying, Chen Yuanyin, Sheng Rongshen. C60Ptn as the catalyst for hydrosilylation of olefins.Chinese J Catal, 1997,18(2):91–92(Ch)
Chen Yuanyin, Sheng Ronyshen, Liu Ying. C60 Pt (PPh3)2 as the catalyst for hydrosilylation of olefins.Chem Res Chinese Universities, 1994,10(4):338–340(Ch)
Sakakura T, Lautenschlager H T, Tanaka M. Hydrosilylation catalyzed by organoneodymium complexes.J Chem Soc, Chem Commun, 1991(1):40–41
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Supported by the National Natural Science Foundation of China (Grant 29573115)
Fang Pengfei: born in 1971, Ph. D
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Pengfei, F., Yuanyin, C., Ling, H. et al. Synthesis, characterization and catalytic hydrosilylation activity of [60] fullerene n-propylamine platinum, rhodium complex. Wuhan Univ. J. Nat. Sci. 4, 82–84 (1999). https://doi.org/10.1007/BF02827629
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DOI: https://doi.org/10.1007/BF02827629