Abstract
Phosphine isocyanide complexes cis-[PtCl2(CNMes)(P)] with mesitylisocyanide and phoshine ligands were synthesized in yields of 92‒98%. The products were characterized by mass spectrometry, IR and 1H NMR, COSY, NOESY, HSQC, and HMBC spectroscopy, and X-ray diffraction analysis. The solid-state and solution structures of the complexes and their stability in isomerization and ligand disproportionation reactions were studied.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
Kinzhalov, M.A. and Boyarskii, V.P., Russ. J. Gen. Chem., 2015, vol. 85, no. 10, p. 2313. doi 10.1134/S1070363215100175
Mikherdov, A.S., Tyuftyakov, N.Yu., Polukeev, V.A., and Boyarskii, V.P., Russ. J. Gen. Chem., 2018, vol. 88, no. 4, p. 713. doi 10.1134/S1070363218040151
Jin, M., Seki, T., and Ito, H., Chem. Commun., 2016, vol. 52, no. 52, p. 8083. doi 10.1039/C6CC03541H
Ito, H., Maeda, T., and Sawamura, M., Bull. Chem. Soc. Jpn., 2007, vol. 80, no. 10, p. 1981. doi 10.1246/bcsj.80.1981
Ivanov, D.M., Kinzhalov, M.A., Novikov, A.S., Ananyev, I.V., Romanova A.A., Boyarskiy, V.P., Haukka, M., and Kukushkin, V.Y., Cryst. Growth Des., 2017, no. 17, p. 1353. doi 10.1021/acs.cgd.6b01754
Naik, A., Meina, L., Zabel, M., and Reiser, O., Chem. Eur. J., 2010, vol. 16, no. 5, p. 1624. doi 10.1002/chem.200901560
Mancuso, J. and Lautens, M., Org. Lett., 2003, vol. 5, no. 10, p. 1653. doi 10.1021/ol034284e
Islamova, R.M., Dobrynin, M.V., Vlasov, A.V., Eremina, A.A., Kinzhalov, M.A., Kolesnikov, I.E., Zolotarev, A.A., Masloborodova, E.A., and Luzyanin, K.V., Catal. Sci. Technol., 2017, vol. 7, no. 24, p. 5843. doi 10.1039/C7CY02013a
Vicenzi, D., Sgarbossa, P., Biffis, A., Tubaro, C., Basato, M., Michelin, R.A., Lanza, A., Nestola, F., Bogialli, S., Pastore, P., and Venzo, A., Organometallics, 2013, vol. 32, no. 23, p. 7153. doi 10.1021/om400859q
Gao, H. and Angelici, R.J., Organometallics, 1999, vol. 18, no. 6, p. 989. doi 10.1021/OM980829A
Kinzhalov, M.A., Buldakov, A.V., Petrov, A.V., Mahmudov, K.T., Ivanov, A.Yu., and Suslonov, V.V., Russ. J. Gen. Chem., 2017, vol. 87, no. 11, p. 2605. doi 10.1134/S1070363217110159
Shavaleev, N.M., Monti, F., Scopelliti, R., Baschieri, A., Sambri, L., Armaroli, N., Gratzel, M., and Nazeeruddin, M.K., Organometallics, 2013, vol. 32, no. 2, p. 460. doi 10.1021/om300894m
Tsai, J.L.-L., Zou, T., Liu, J., Chen, T., Chan, A.O.-Y., Yang, C., Lok, C.-N., and Che, C.-M., Chem. Sci., 2015, vol. 6, no. 7, p. 3823. doi 10.1039/C4SC03635B
Fuertes, S., Chueca, A.J., Perálvarez, M., Borja, P., Torrell, M., Carreras, J., and Sicilia, V., ACS Appl. Mater. Interfaces, 2016, vol. 8, no. 25, p. 16160. doi 10.1021/acsami.6b03288
Boyarskiy, V.P., Bokach, N.A., Luzyanin, K.V., and Kukushkin, V.Y., Chem. Rev., 2015, vol. 115, p. 2698. doi 10.1021/cr500380d
Kinzhalov, M.A., Novikov, A.S., Luzyanin, K.V., Haukka, M., Pombeiro, A.J.L., and Kukushkin, V.Y., New J. Chem., 2016, vol. 40, no. 1, p. 521. doi 10.1039/C5NJ02564H
Anisimova, T.B., Kinzhalov, M.A., Kuznetsov, M.L., Guedes da Silva, M.F.C., Zolotarev, A.A., Kukushkin, V.Y., Pombeiro, A.J.L., and Luzyanin, K.V., Organometallics, 2016, vol. 35, no. 20, p. 3569. doi 10.1021/acs.organomet.6b00635
Bertani, R., Mozzon, M., Michelin, R.A., Benetollo, F., Bombieri, G., Castilho, T.J., and Pombeiro, A.J.L., Inorg. Chim. Acta, 1991, vol. 189, no. 2, p. 175. doi 10.1016/s0020-1693(00)80186-3
Hashmi, A.S.K., Lothschutz, C., Bohling, C., Hengst, T., Hubbert, C., and Rominger, F., Adv. Synth. Catal., 2010, vol. 352, no. 17, p. 3001. doi 10.1002/adsc.201000472
Hubbert, C., Breunig, M., Carroll, K.J., Rominger, F., and Hashmi, A.S.K., Austral. J. Chem., 2014, vol. 67, no. 3, p. 469. doi 10.1071/ch13546
Chay, R.S., Luzyanin, K.V., Kukushkin, V.Y., Guedes da Silva, M.F.C., and Pombeiro, A.J.L., Organometallics, 2012, vol. 31, p. 2379. doi 10.1021/om300020j
Boyarskiy, V.P., Luzyanin, K.V., and Kukushkin, V.Y., Coord. Chem. Rev., 2012, vol. 256, p. 2029. doi 10.1016/j.ccr.2012.04.022
Slaughter, L.M., ACS Catal., 2012, vol. 2, p. 1802. doi 10.1021/cs300300y
Luzyanin, K.V., Pombeiro, A.J.L., Haukka, M., and Kukushkin, V.Y., Organometallics, 2008, vol. 27, no. 20, p. 5379. doi 10.1021/om800517c
Chay, R.S., Rocha, B.G.M., Pombeiro, A.J.L., Kukushkin, V.Y., and Luzyanin, K.V., ACS Omega, 2018, vol. 3, no. 1, p. 863. doi 10.1021/acsomega.7b01688
Rocha, B.G.M., Valishina, E.A., Chay, R.S., da Silva, M., Buslaeva, T.M., Pombeiro, A.J.L., Kukushkin, V.Y., and Luzyanin, K.V., J. Catal., 2014, vol. 309, p. 79. doi 10.1016/j.jcat.2013.09.003
Chatt, J., Richards, R.H., and Royston, G.H.D, Inorg. Chim. Acta, 1972, vol. 6, no. 4, p.669.
Miss, E.M.B., Chatt, J., and Richards, R.L., J. Chem. Soc. A, 1971, p. 21. doi 10.1039/J19710000021
Michelin, R.A., Facchin, G., and Uguagliati, P., Inorg. Chem., 1984, vol. 23, no. 7, p. 961. doi 10.1021/ic00175a033
Manojlovicmuir, L., Muir, K.W., and Solomun, T., J. Organomet. Chem., 1977, vol. 142, no. 2, p. 265. doi 10.1016/s0022-328x(00)94349-3
Crociani, B. and Richards, R.L., J. Organomet. Chem., 1978, vol. 144, no. 1, p. 85. doi 10.1016/s0022-328x (00)98093-8
Briggs, J.R., Crocker, C., and Shaw, B.L., Inorg. Chim. Acta, 1981, vol. 51, no. 1, p. 15. doi 10.1016/s0020-1693(00)88309-7
Knorr, M., Jourdain, I., Crini, G., Frank, K., Sachdev, H., and Strohmann, C., Eur. J. Inorg. Chem., 2002, no. 9, p. 2419. doi 10.1002/1099-0682(200209) 2002:9<2419::AID-EJIC2419>3.0.CO;2-U
Yakimanskiy, A., Boyarskaya, I., and Boyarskiy, V., J. Coord. Chem., 2013, vol. 66, no. 20, p. 3592. doi 10.1080/00958972.2013.847185
Kinzhalov, M.A., Zolotarev, A.A., and Boyarskiy, V.P., J. Struct. Chem., 2016, vol. 57, no. 4, p. 822. doi 10.1134/s0022476616040302.
Kinzhalov, M.A., Luzyanin, K.V., Boyarskaya, I.A., Starova, G.L., and Boyarskiy, V.P., J. Mol. Struct., 2014, vol. 1068, p. 222. doi 10.1016/j.molstruc.2014.04.025
Martinez-Martinez, A.J., Chicote, M.T., and Bautista, D., Inorg. Chim. Acta, 2012, vol. 382, p. 203. doi 10.1016/j.ica.2011.11.038
Anisimova, T.B., Kinzhalov, M.A., Guedes da Silva, M.F.C., Novikov, A.S., Kukushkin, V.Y., Pombeiro, A.J.L., and Luzyanin, K.V., New J. Chem., 2017, vol. 41, no. 9, p. 3246. doi 10.1039/C7NJ00529F
Sluch I.M., Miranda A.J., and Slaughter L.M., Cryst. Growth Des., 2009, vol. 9, no. 3, p. 1267. doi 10.1021/cg801116q
Michelin, R.A., Zanotto, L., Braga, D., Sabatino, P., and Angelici, R.J., Inorg. Chem., 1988, vol. 27, no. 1, p. 85. doi 10.1021/ic00274a019
Johansson, M.H. and Otto, S., Acta Crystallogr., Sect. C, 2000, vol. 56, p. e12. doi 10.1107/S0108270199012147
Klingenberg, M.A., Bogachenkov, A.S., Kinzhalov, M.A., Vasilyev, A.V., and Boyarskiy, V.P., New J. Chem., 2016, vol. 40, no. 4, p. 3336. doi 10.1039/c5nj03038b
Luzyanin, K.V., Pombeiro, A.J.L., Haukka, M., and Kukushkin, V.Y., Organometallics, 2008, vol. 27, p. 5379. doi 10.1021/om800517c
Tskhovrebov, A.G., Luzyanin, K.V., Haukka, M., and Kukushkin, V.Y., J. Chem. Crystallogr., 2012, vol. 42, no. 12, p. 1170. doi 10.1007/s10870-012-0371-0
Palatinus, L. and Chapuis, G., J. Appl. Crystallogr., 2007, vol. 40, p. 786. doi 10.1107/s0021889807029238
Palatinus, L. and van der Lee A., J. Appl. Crystallogr., 2008, vol. 41, p. 975. doi 10.1107/s0021889808028185
Sheldrick, G.M., Acta Crystallogr., 2015, vol. 71, p. 3. doi 10.1107/s2053273314026370
Sheldrick, G.M., Acta Crystallogr., Sect. A, 2008, vol. 64, p. 112. doi 10.1107/S0108767307043930
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., Howard, J.A.K., and Puschmann, H., J. Appl. Crystallogr., 2009, vol. 42, p. 339. doi 10.1107/S0021889808042726
Spek, A.L., Acta Crystallogr., Sect. C, 2015, vol. 71, p. 9. doi 10.1107/s2053229614024929
CrysAlisPro. A.T., Version 1.171.36.20 (release 27-06-2012).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © M.A. Kinzhalov, M.V. Kashina, A.S. Mikherdov, S.A. Katkova, V.V. Suslonov, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 6, pp. 1000–1007.
Rights and permissions
About this article
Cite this article
Kinzhalov, M.A., Kashina, M.V., Mikherdov, A.S. et al. Synthesis of Platinum(II) Phoshine Isocyanide Complexes and Study of Their Stability in Isomerization and Ligand Disproportionation Reactions. Russ J Gen Chem 88, 1180–1187 (2018). https://doi.org/10.1134/S107036321806021X
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S107036321806021X