Abstract
Relaxation techniques have been used to study the kinetics of the rapid interaction of Cr(III) with iodate and sulfite. Rate data and H+-catalysis indicate that complex formation occurs via an oxygen exchange mechanisms which does not involve Cr(III)-O bond breaking.
Abstract
Техника релаксации была использована для изучения кинетики быстрого взаимодействия Cr(III) с иодатом и сульфитом. Данные скорости и H+-каталиэ укаэывают на то, что комплексообразование протекает согласно механизму кислородного обмена, который, однако, не включает в себя разрыв связи Cr(III)-o.
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Bazsa, G., Diebler, H. Kinetics of the rapid interaction of chromium(III) with iodate and sulfite. React Kinet Catal Lett 2, 217–227 (1975). https://doi.org/10.1007/BF02068194
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DOI: https://doi.org/10.1007/BF02068194