Summary
Some new crystalline copper(I) complexes of rhodanine (HL) have been prepared and studied by i.r. and conductometric methods. The neutral ligand is bonded to the metal atom through the thiocarbonylic sulphur atom. The Cu(HL)2OH · 0.5 H2O complex has a dimeric tetrahedral hydroxyl-bridged structure as have the isostructural halides Cu(HL)2X (X = Cl, Br and I) for which the halide-bridged stretching bands have been identified. The Cu(HL)3A (A = ClO4, BF4, 0.5 SO4 and CF3CO2) complexes have monomeric distorted tetrahedral structures with the anion bonded to the metal.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
F. G. Moers and J. J. Steggerda,J. Inorg. Nucl. Chem., 30, 3217 (1968).
W. J. Geary,Coord. Chem. Rev., 7, 81 (1971).
A. C. Fabretti and G. Peyronel,Transition Met. Chem., 2, 224 (1977).
G. C. Pellacani, G. Peyronel, T. Feltri and L. Menabue,Spectrochim. Acta, 32A, 285 (1976).
A. Pignedoli and G. Peyronel,Spectrochim. Acta, 32A, 1739 (1976).
R. Bartistuzzi, G. Peyronel and G. Debbi,Z. Anorg. Allg. Chem., 427, 274 (1976).
K. Nakamoto,Infrared Spectra of Inorganic and Coordination Compounds, Wiley, New York, 1970, p. 167.
G. L. Bottger and A. L. Geddes,Spectrochim. Acta, 23A, 1551 (1967).
J. R. Ferraro,Low-Frequency Vibrations of lirorganic and Coordination Compounds, Plenum Press, New York, 1971, pp. 175, 179, 75.
B. K. Teo and D. M. Barnes,Inorg. Nucl. Chem. Lett. 12, 681 (1976).
W. R. McWhinnie and V. Rattanaphani,Inorg. Chim. Acta, 9, 153 (1974).
L. Volponi, B. Zarli and G. G. De Paoli,Inorg. Nucl. Chem. Lett., 8, 309 (1972).
M. J. Campbell, R. Grzeskowiak and M. Goldstein,Spectrochim. Acta, 24A, 1149 (1968).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Fabretti, A.C., Peyronel, G. & Franchini, G.C. Copper(I) complexes of rhodanine. Transition Met Chem 3, 125–127 (1978). https://doi.org/10.1007/BF01393525
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01393525