Abstract
6N(N′-formyl-D-phenylalanyl)-deoxyamino-β-cyclodextrin and 6N(N′-formyl-L-phenylal-anyl)-deoxyamino-β-cyclodextrin (I andII) were prepared. These new hosts formed ‘intramolecular host-guest complexes’ and included naphthyl derivatives preferentially with a stoichiometry of 1:1. The inclusion behavior was different between I and II because the cavity shape formed with the CD cavity and the phenylalanine moiety of I was different from that of II.
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Takahashi, K., Ohtsuka, Y., Nakada, S. et al. Syntheses of 6N(N′-formyl-D-phenylalanyl)-deoxyamino-β-cyclodextrin and 6N(N′-formyl-L-phenylalanyl)deoxyamino-β-cyclodextrin and their inclusion behavior. J Incl Phenom Macrocycl Chem 10, 63–68 (1991). https://doi.org/10.1007/BF01041640
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DOI: https://doi.org/10.1007/BF01041640