Summary
Electrochemical oxidation of nickel in an acetonitrile solution containing 2-pyrrole-[N-(2-hydroxy-4-methyl-phenyl)methylimine] (H2L) and 1,10-phenanthroline (phen) yielded Ni(HL)2·phen, whose crystal structure was determined by XRD. The nickel atom has a distorted octahedral geometry, and is coordinated to the phenolic oxygen and imino nitrogen atoms of two Schiff base ligands. The i.r. and u.v.-vis. spectra of the complex are discussed and related to the structure.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
N. M. Atherton, D. E. Fenton, G. I. Hewson, C. L. McLean, R. Bastida, J. Romero, A. Sousa, E. E. Castellano, J. Chem. Soc., Dalton Trans., 1059 (1988).
A. Castiñeiras, J. Castro, M. L. Durán, J. A. García-Vázquez, A. Macías, J. Romero and A. Sousa, Polyhedron, 8, 2549 (1989).
J. A. Castro, J. Romero, J. A. García-Vázquez, M. L. Durán, A. Castiñeiras, A. Sousa and D. E. Fenton, J. Chem. Soc., Dalton Trans., 3255 (1990).
M. L. Durán, J. A. García-Vázquez, A. Macías, J. Romero, A. Sousa and E. B. Rivero, Z. Anorg. Allg. Chem., 573, 215 (1989).
T. Sogo, J. Romero, A. Sousa, A. de Blas, M. L. Durán and E. E. Castellano, Z. Naturforsch., Teil B, 43, 611 (1988).
C. Oldhan and D. G. Tuck, J. Chem. Ed., 59, 420 (1982).
B. A. Frenz in H. Schrenk, R. Oltof-Hazenkamp, H. van Koningsveld and G. C. Bassi (Eds), Computing in Crystallography, Delft University Press, Delft, 1978.
N. Walker and D. Stuart, Acta Crystallogr., A39, 158 (1983).
C. M. Sheldrick, SHELXS-86: A Program for the Solution of Crystal Structures from X-ray Diffraction Data, University of Göttingen, Göttingen, 1986.
W. H. Zachariasen, Acta Crystallogr., 16, 1139 (1963).
International Tables for X-ray Crystallography, Vol. IV, Kynoch Press, Birmingham, 1974.
E. Keller, SCHAKAL. Program for Plotting Molecular and Crystal Structures, University of Freigburg, Freigburg, 1988.
K. R. Butler and M. R. Snow, J. Chem. Soc. A., 565 (1971).
M. di Vaira and P. L. Orioli, Inorg. Chem., 6, 490 (1967).
J. A. Castro, J. Romero, J. A. García-Vázquez, A. Castiñeiras and A. Sousa, Z. Anorg. Allg. Chem., 619, 601 (1993).
J. A. Castro, J. E. Vilasánchez, J. Romero, J. A. García-Vázquez, M. L. Durán, A. Sousa, E. E. Castellano and J. Zukerman-Schpector, Z. Anorg. Allg. Chem., 612, 83 (1992).
J. A. Castro, J. Romero, J. A. García-Vázquez, A. Macías, A. Sousa and U. Englert, Polyhedron, 12, 1391 (1993).
G. C. Percy and D. A. Thorton, J. Inorg. Nucl. Chem., 34, 3357 (1972).
A. A. Schilt and R. C. Taylor, J. Inorg. Nucl. Chem., 9, 211 (1959).
A. B. P. Lever, Inorganic Electronic Spectroscopy, 2nd Edit., Elsevier, Amsterdam, 1984.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Castro, J., Romero, J., García-Vázquez, J.A. et al. Synthesis and structure of 1,10-phenanthroline bis{[2-(2-pyrrole)-methylimino]4-methylphenolato}nickel(II). Transition Met Chem 19, 343–346 (1994). https://doi.org/10.1007/BF00139109
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00139109