Abstract
Synthesis and characterization of a mononuclear nickel(II) complex [NiL] · CH3OH (I) and a dinuclear manganese(III) complex [Mn2L2(NCS)2] (II) derived from the bis-Schiff base N,N'-bis(5-methoxysalicylidene)-1,2-ethanediamine (H2L) are reported. The complexes were characterized by elemental analyses, IR spectra and molar conductivity. Single crystal X-ray structures of the complexes have been determined (CIF files CCDC nos. 1056778 (I) and 1056688 (II)). The Ni atom in I is in a square planar coordination, and the Mn atom in II is in an octahedral coordination. Catalytic property for epoxidation of styrene by the complexes using PhIO and NaOCl as oxidant has been studied. As a result, complex II is efficient for the styrene epoxidation.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
Kal, S., Ayensu-Mensah, L., and Dinolfo, P.H., Inorg. Chim. Acta, 2014, vol. 423, p. 201.
Ebrahimipour, S.Y., Khabazadeh, H., Castro, J., et al., Inorg. Chim. Acta, 2015, vol. 427, p. 52.
Han, S. and Wang, Y., J. Chil. Chem. Soc., 2014, vol. 59, no. 4, p. 2753.
Cristovao, B. and Miroslaw, B., Inorg. Chem. Commun., 2015, vol. 52, no. 1, p. 64.
Novoa, N., Justaud, F., Hamon, P., et al., Polyhedron, 2015, vol. 86, no. 1, p. 81.
Upadhyay, A., Das, C., Meera, S.N., et al., J. Chem. Sci., 2014, vol. 126, no. 5, p. 1443.
Marinescu, G., Madalan, A.M., and Andruh, M., J. Coord. Chem., 2015, vol. 68, no. 3, p. 479.
Maiti, M., Thakurta, S., Sadhukhan, D., et al., Polyhedron, 2013, vol. 65, no. 1, p. 6.
Kuai, H.W., Cheng, X.-C., and Zhu, X.-H., Polyhedron, 2013, vol. 50, no. 1, p. 390.
Nagesh, G.Y. and Raj, K.M., J. Mol. Struct., 2015, vol. 1079, p. 423.
Ebrahimipour, S.Y., Mohamadi, M., Castro, J., et al., J. Coord. Chem., 2015, vol. 68, no. 4, p. 632.
Begum, A.B., Rekha, N.D., Kumar, B.C.V., et al., Bioorg. Med. Chem. Lett., 2014, vol. 24, no. 15, p. 3559.
Martinez, A., Hemmert, C., and Meunier, B., J. Catal., 2005, vol. 234, no. 2, p. 250.
Erdem, O. and Guzel, B., Inorg. Chim. Acta, 2014, vol. 418, p. 153.
Louloudi, M., Nastopoulos, V., Gourbatsis, S., et al., Inorg. Chem. Commun., 1999, vol. 2, no. 10, p. 479.
Srinivasan, K., Michaud, P., and Kochi, J.K., J. Am. Chem. Soc., 1986, vol. 108, no. 9, p. 2309.
Adam, W., Roschmann, K.J., Saha-Moller, C.R., et al., J. Am. Chem. Soc., 2002, vol. 124, no. 18, p. 5068.
Majumder, S., Hazra, S., Dutta, S., et al., Polyhedron, 2009, vol. 28, no. 12, p. 2473.
Ourari, A., Baameur, L., Bouacida, S., et al., Acta Crystallogr., Sect. E: Struct. Rep. Online, 2012, vol. 68, no. 6, p. o1760.
Sheldrick, G.M., SAINT (version 6.02), SADABS (version 2.03), Madison (WI, USA): Bruker AXS Inc., 2002.
Sheldrick, G.M., SHELXL-9, A Program for Crystal Structure Solution, Göttingen: Univ. of Göttingen, 1997.
Geary, W.J., Coord. Chem. Rev., 1971, vol. 7, no. 1, p. 81.
Kondo, M., Nabari, K., Horiba, T., et al., Inorg. Chem. Commun., 2003, vol. 6, no. 2, p. 154.
Shimazaki, Y., Yajima, T., Tani, F., et al., J. Am. Chem. Soc., 2007, vol. 129, no. 9, p. 2559.
Bhargavi, G., Rajasekharan, M.V., Costes, J.-P., et al., Polyhedron, 2009, vol. 28, no. 7, p. 1253.
Mandal, S., Rosair, G., Ribas, J., et al., Inorg. Chim. Acta, 2009, vol. 362, no. 7, p. 2200.
Author information
Authors and Affiliations
Corresponding author
Additional information
The article is published in the original.
Rights and permissions
About this article
Cite this article
Wei, F.Y. A mononuclear nickel(II) complex and a dinuclear manganese(III) complex derived from N,N'-bis(5-methoxysalicylidene)-1,2-ethanediamine: Synthesis, crystal structures and catalytic epoxidation property. Russ J Coord Chem 42, 44–49 (2016). https://doi.org/10.1134/S1070328416010073
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070328416010073