Abstract.
The zinc(II) complex with tridentate thiohydrazone ligand have been prepared by metal template reaction. The metal template reaction was used to prepare the zinc (II) complex with tridentate thiohydrazone ligand. The reaction of diacetylmonoxime and, morpholine N-thiohydrazidewith Zn(OAc)2 \(\cdot\)2H2O under reflux yielded the formation of the [Zn(Hdmmthiol )2]\(\cdot\)2H2O complex. The complex was characterized by a combination of protocols including elemental analysis, UV+vis, FT-IR, TG and PXRD. The temperature dependence of the electrical conductivity and the optical property of the [Zn(Hdmmthiol )2] \(\cdot\)2H2O complex is called H2dammthiol was studied. Powder X-ray diffraction (PXRD) method was used to investigate the crystal structure of the sample. The zinc complex was shown to be a member of the triclinic system. The zinc complex was determined to have n-type conductivity as demonstrated in the hot probe measurements. The complex was determined to display direct optical transition with band gaps of 2.52eV as determined by the optical absorption analysis.
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References
S.S. Djbbar, B.O. Benali, J.P. Deloume, Polyhedron 16, 2175 (1997)
P. Bhattacharya, J. Parr, A.T. Ross, A.M.Z. Slawin, J. Chem. Soc. Dalton Trans. 19, 3149 (1998)
L. He, S.H. Gou, Q.F. Shi, J. Chem. Crystallogr. 29, 207 (1999)
J.C. Wu, N. Tang, W.S. Liu, M.Y. Tan, A.C.S. Chan, Chin. Chem. Lett. 12, 757 (2001)
C.M. Liu, R.G. Xiong, X.Z. You, Y.J. Liu, K.K. Cheung, Polyhedron 15, 4565 (1996)
A. Galdes, B.L. Vallee, Zinc and its Role in Biology and Nutrition, edited by H. Sigel (Marcel Deckker, New York, 1983)
R. Klement, F. Stock, H. Elias, H. Paulus, P. Pelikan, M. Valko, M. Mazur, Polyhedron 18, 3041 (1999)
K.D. Karlin, J. Zubbieta, Biological and Inorganic Copper Chemistry (Adenine Press, New York, 1983)
G.G. Mohamed, Spectrochim. Acta A 64, 188 (2006)
L. Shi, W.J. Mao, Y. Yang, H.L. Zhu, J. Coord. Chem. 62, 3471 (2009)
M.A. Phaniband, S.D. Dhumwad, Trans. Met. Chem. 32, 1117 (2007)
S. Biswas, S. Sarkar, I.M. Steele, G. Mostafa, B.B. Bhaumik, K. Dey, Polyhedron 26, 5061 (2007)
S. Biswas, G. Mostafa, I.M. Steele, S. Sarkar, K. Dey, Polyhedron 28, 1010 (2009)
S. Biswas, G.P.A. Yap, K. Dey, Polyhedron 28, 3094 (2009)
F. Dagdelen, A. Aydogdu, Sci. Eng. J. Firat. Univ. 18, 291 (2006)
Y.S. Ocak, M.A. Ebeoglu, G. Topal, T. Kiliçoglu, Physica B 405, 2329 (2010)
S. Sarkar, Y. Aydogdu, F. Dagdelen, B.B. Bhaumik, K. Dey, Mater. Chem. Phys. 88, 357 (2004)
W.J. Liu, G.X. Xiong, W.P. Wang, Appl. Organometall. Chem. 21, 83 (2007)
J.D. Chellain, J. Johnson, Spectrochim. Acta Part A 127, 396 (2014)
S. Biswas, F. Dagdelen, Y. Aydogdu, K. Dey, Mater. Chem. Phys. 129, 1121 (2011)
F. Dagdelen, Investigation of the Electronic Properties of Metal-Complex Semiconductor Schottky Diodes, Firat University, PhD Thesis (2004)
R.S. Joseyphus, E. Viswanathan, C.J. Dhanaraj, J. Joseph, J. King Saud Univ. Sci. 24, 233 (2012)
N. Singh, S. Gupta, Synth. Metals 110, 207 (2000)
P.E. Werner, L. Eriksson, M. Westdahl, J. Appl. Cryst. 18, 367 (1985)
S. Sarkar, S. Biswas, K. Dey, B.B. Bhaumik, J. Coord. Chem. 60, 1057 (2007)
M.A. Ali, R.N. Bose, Polyhedron 3, 517 (1984)
F. Gutmann, Organic Semiconductors (Wiley, New York, 1967)
G.B. El-Hefnawey, M.M. Ayad, A.E. El-Trass, Thermochim. Acta 198, 345 (1992)
K.Y. El-Baradie, M. Gaber, M.M. Abou-Sekkina, Thermochim. Acta 246, 175 (1994)
J.I. Pankove, Optical Processes in Semiconductors (Prentice-Hall Inc, New Jersey, 1971)
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Dagdelen, F., Aydogdu, Y., Dey, K. et al. Synthesis, characterization and solid-state properties of [Zn(Hdmmthiol)2]\(\cdot\)2H2O complex. Eur. Phys. J. Plus 131, 143 (2016). https://doi.org/10.1140/epjp/i2016-16143-2
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DOI: https://doi.org/10.1140/epjp/i2016-16143-2