Abstract
In the present work, dielectric spectra of mixtures of diethylsulfoxide (DESO) and water are presented, covering a concentration range of 0.2-0.3 molar fraction of DESO. The measurements were performed at frequencies between 1Hz and 10MHz and for temperatures between 150 and 300K. It is shown that DESO/water mixtures have strong glass-forming abilities. The permittivity spectra in these mixtures reveal a single relaxation process. It can be described by the Havriliak-Negami relaxation function and its relaxation times follow the Vogel-Fulcher-Tammann law, thus showing the typical signatures of glassy dynamics. The concentration dependence of the relaxation parameters, like fragility, broadening, and glass temperature, are discussed in detail.
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S.A. Markarian, S. Bonora, K.A. Bagramyan, V.B. Arakelyan, Cryobiology 49, 1 (2004).
S.A. Markarian, A.L. Zatikyan, S. Bonora, C. Fagnano, J. Mol. Struct. 665, 285 (2003).
S.A. Markarian, L.S. Gabrielyan, Phys. Chem. Liq. 47, 311 (2009).
L.S. Gabrielyan, S.A. Markarian, H. Weingärtner, J. Mol. Liq. 159, 201 (2011).
C.A. Angell, K.L. Ngai, G.B. McKenna, P.F. McMillan, S.W. Martin, J. Appl. Phys. 88, 3113 (2000).
J.C. Dyre, Rev. Mod. Phys. 78, 953 (2006).
P.G. Wolynes, V. Lubchenko, Structural Glasses and Supercooled Liquids: Theory, Experiment, and Applications (Wiley, Hoboken, 2012).
F. Kremer, A. Schönhals, Broadband Dielectric Spectroscopy (Springer, Berlin, Heidelberg, 2003).
P. Lunkenheimer, U. Schneider, R. Brand, A. Loidl, Contemp. Phys. 41, 15 (2000).
P. Lunkenheimer, A. Loidl, Chem. Phys. 284, 205 (2002).
U. Kaatze, R. Pottel, M. Schaefer, J. Phys. Chem. 93, 5623 (1989).
U. Kaatze, Int. J. Thermophys. (2014) DOI:10.1007/s10765-014-1658-5.
Z. Lu, E. Manias, D.D. Macdonald, M. Lanagan, J. Phys. Chem. A 113, 12207 (2009).
S.M. Puranik, A.C. Kumbharkhane, S.C. Mehrotra, J. Chem. Soc. Faraday Trans. 88, 433 (1992).
L.-J. Yang, X.-Q. Yang, K.-M. Huang, G.-Z. Jia, H. Shang, Int. J. Mol. Sci. 10, 1261 (2009).
S.S.N. Murthy, J. Phys. Chem. B 101, 6043 (1997).
S.A. Lusceac, C. Gainaru, D.A. Ratzke, M.F. Graf, M. Vogel, J. Phys. Chem. B 115, 11588 (2011).
S.A. Markarian, N. Tadevosyan, Method of purification of diethyl sulfoxide, Patent of Republic of Armenia, No 20010041 (2002).
P. Lunkenheimer, A. Loidl, J. Chem. Phys. 104, 4324 (1996).
P. Sippel, D. Denysenko, A. Loidl, P. Lunkenheimer, G. Sastre, D. Volkmer, Adv. Funct. Mater. 24, 3885 (2014).
C.J.F. Böttcher, P. Bordewijk, Theory of Electric Polarization, Vol. II (Elsevier, Amsterdam, 1973).
S. Havriliak, S. Negami, J. Polymer Sci. C 14, 99 (1966).
D.W. Davidson, R.H. Cole, J. Chem. Phys. 18, 1417 (1950).
L. Leheny, S.R. Nagel, Europhys. Lett. 39, 447 (1997).
U. Schneider, P. Lunkenheimer, R. Brand, A. Loidl, Phys. Rev. E 59, 6924 (1999).
U. Schneider, R. Brand, P. Lunkenheimer, A. Loidl, Phys. Rev. Lett. 84, 5560 (2000).
Th. Bauer, P. Lunkenheimer, S. Kastner, A. Loidl, Phys. Rev. Lett. 110, 107603 (2013).
H. Sillescu, J. Non-Cryst. Solids 243, 81 (1999).
M.D. Ediger, Annu. Rev. Phys. Chem. 51, 99 (2000).
C.T. Moynihan, L.P. Boesch, N.L. Laberge, Phys. Chem. Glasses 14, 122 (1973).
Th. Bauer, M. Köhler, P. Lunkenheimer, A. Loidl, C.A. Angell, J. Chem. Phys. 133, 144509 (2010).
M.D. Ediger, C.A. Angell, S.R. Nagel, J. Phys. Chem. 100, 13200 (1996).
P.G. Debenedetti, F.H. Stillinger, Nature 310, 259 (2001).
Th. Bauer, P. Lunkenheimer, A. Loidl, Phys. Rev. Lett. 111, 225702 (2013).
H. Vogel, Phys. Z. 22, 645 (1921).
G.S. Fulcher, J. Am. Ceram. Soc. 8, 339 (1923).
G. Tammann, W. Hesse, Z. Anorg. Allg. Chem. 156, 245 (1926).
C.A. Angell, in Relaxations in Complex Systems, edited by K.L. Ngai, G.B. Wright (NRL, Washington, DC, 1985) p. 3.
C.A. Angell, J. Non-Cryst. Solids 102, 205 (1988).
C.A. Angell, W. Sichina, Ann. N.Y. Acad. Sci. 279, 53 (1976).
R. Böhmer, K.L. Ngai, C.A. Angell, D.J. Plazek, J. Chem. Phys. 99, 4201 (1993).
C.A. Angell, J. Phys. Chem. Solids 49, 863 (1988).
R. Böhmer, C.A. Angell, in Disorder Effects on Relaxational Processes, edited by R. Richert, A. Blumen (Springer, Berlin, 1994) p. 11.
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Gabrielyan, L., Markarian, S., Lunkenheimer, P. et al. Low temperature dielectric relaxation study of aqueous solutions of diethylsulfoxide. Eur. Phys. J. Plus 129, 245 (2014). https://doi.org/10.1140/epjp/i2014-14245-5
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DOI: https://doi.org/10.1140/epjp/i2014-14245-5