Abstract
Heat-resistant ceramic materials have been prepared based on the zirconium boride-silicon carbide composition during oxidation in the air atmosphere. The effect of the evaporation of boric oxide on the oxidation kinetics has been revealed experimentally. The electrical resistivity and dilatometric properties of the composites were determined.
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Tripp, W.C. and Graham, H.C., Thermogravimetric study of the oxidation of ZrB2 in the temperature range of 800 to 1500°C, J. Electrochem. Soc., 1971, vol. 118, no. 7, pp. 1195–1199.
Zamora, V., Ortiz, A.L., Guiberteau, F., and Nygren, M., Crystal-size dependence of the sparkplasma-sintering kinetics of ZrB2 ultra-high-temperature ceramics, J. Eur. Ceram. Soc., 2012, vol. 32, no. 2, pp. 271–276.
Pimenoff, J.A., Coatings and Surface Doping-Nano-Sized Industrial Applications, Espoo, Finland: Beneq Oy. E-mail: joe.pimenoff@beneq.com, www.beneq.com.
Sazonova, M.V. and Efimenko, L.P., Thermal stability of MoSi2-SiC composites in air at temperatures of 1100–1400°C, Fiz. Khim. Stekla, 2009, vol. 35, no. 2, pp. 285–292.
Sazonova, M.V. and Efimenko, L.P., Thermal stability of MoSi2-SiC composites in air at temperatures of 1100–1400°C, Glass Phys. Chem., 2009, vol. 35, no. 2, pp. 219–224.
Sevast’yanov, V.G. Simonenko, E.P., Gordeev, A.N., Simonenko, N.P., Kolesnikov, A.F., Papynov, E.K., Shichalin, O.O., Avramenko, V.A., and Kuznetsov, N.T., Production of ultrahigh temperature composite materials HfB2-SiC and the study of their behavior under the action of a dissociated air flow, Russ. J. Inorg. Chem., 2013, vol. 58, no. 11, pp. 1269–1278.
Chunfeng Hu, Yoshio Sakka, Jinghui Gao, Hidehiko Tanaka, and Grasso, S., Microstructure characterization of ZrB2-SiC composite fabricated by spark plasma sintering with TaSi2 additive, J. Eur. Ceram. Soc., 2012, vol. 32, pp. 1441–1446.
Ban’kovskaya, I.B. and Kolovertnov, D.V., Effect of the thermal treatment mode on the composition and structure of ZrB2-SiC system composites, Fiz. Khim. Stekla, 2013, vol. 39, no. 5, pp. 816–828.
Ban’kovskaya, I.B. and Kolovertnov, D.V., Effect of the thermal treatment mode on the composition and structure of ZrB2-SiC system composites, Glass Phys. Chem., 2013, vol. 39, no. 5, pp. 579–588.
Kolovertnov, D.V. and Ban’kovskaya, I.B., Heat-resistant materials based on ZrB2 with additives of SiO2, SiC, and Si3N4, Fiz. Khim. Stekla, 2012, vol. 38, no. 6, pp. 931–933.
Ban’kovskaya, I.B., Kolovertnov, D.V., Salikova, A.P., Vasil’eva, I.A., Gonchukova, N.O., and Ratushnyak, S.L., Reaction synthesis of gas-impermeable coatings based on the zirconium boride-silicon nitride system for the protection of carbon materials, Fiz. Khim. Stekla, 2012, vol. 38, no. 6, pp. 755–767.
Ban’kovskaya, I.B., Vasilyeva, I.A., and Kolovertnov, D.V., Oxidation processes in a siliconboron-zirconium boride composite in the temperature range 1000–1300°C, Fiz. Khim. Stekla, 2012, vol. 38, no. 3, pp. 409–416.
Ban’kovskaya, I.B., Vasilyeva, I.A., and Kolovertnov, D.V., Oxidation processes in a silicon-boron-zirconium boride composite in the temperature range 1000–1300°C, Glass Phys. Chem, 2012, vol. 38, no. 3, pp. 327–331.
Ban’kovskaya, I.B., Kolovertnov, D.V., and Efimenko, L.P., Preparation of composites in the ZrB2-Si system and investigation of their properties, Fiz. Khim. Stekla, 2011, vol. 37, no. 2, pp. 250–258.
Ban’kovskaya, I.B., Kolovertnov, D.V., and Efimenko, L.P., Preparation of composites in the ZrB2-Si system and investigation of their properties, Glass Phys. Chem., 2011, vol. 37, no. 2, pp. 188–197.
Tikhonov, P.A., Formation, stability, and electrical properties of fluorite-like solid solutions in the ZrO2-Y2O3-Yb2O3, ZrO2-Y2O3-CaO, and ZrO2-Y2O3-MgO systems, Extended Abstract of Candidate’s Sci. Dissertation, Institute of Silicate Chemistry of the Academy of Sciences of the Soviet Union, Leningrad, 1971.
Klyuev, V.P. and Chernousov, M.A., An automated dilatometer with a small measuring force, in Tret’e Vsesoyuznoe soveshchanie “Metody i pribory dlya tochnykh dilatometricheskikh issledovanii materialov v shirokom diapazone temperature” (Proceedings of the Third All-Union Conference “Methods and Instruments for Precision Dilatometric Investigations of Materials over a Wide Temperature Range”), Leningrad, 1984, pp. 53–54.
Properties and Structure of Oxide Glasses, Klyuev, V.P. and Pevzner, B.Z., Eds., Kerala, India: Research Signpost, 2010.
Voitovich, R.F., Pugach, E.A., and Men’shikova, L.A., Investigation of high-temperature oxidation of zirconium diboride, Poroshk. Metall., 1967, no. 6 (54), pp. 44–48.
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Original Russian Text © D.V. Kolovertnov, I.B. Ban’kovskaya, 2015, published in Fizika i Khimiya Stekla.
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Kolovertnov, D.V., Ban’kovskaya, I.B. Kinetics of oxidation of the zirconium boride-silicon carbide composition in the air medium. Glass Phys Chem 41, 324–328 (2015). https://doi.org/10.1134/S1087659615030104
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DOI: https://doi.org/10.1134/S1087659615030104