Abstract
The NMR spectra of several heterocyclic compounds synthesized at Omsk universities revealed manifestation of a diasteomerism at a large (up to fifteen bonds) distance between the stereogenic centers. This phenomenon was explained by a regular helical secondary structure of the tether between the centers.
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Russian Text © V.P. Talsi, S.N. Evdokimov, A.L. Shatsauskas, 2019, published in Zhurnal Organicheskoi Khimii, 2019, Vol. 55, No. 2, pp. 208–214.
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Talsi, V.P., Evdokimov, S.N. & Shatsauskas, A.L. Investigation of the Diastomerism of Compounds with a Long-Chain Tether between the Stereogenic Centers. Russ J Org Chem 55, 161–167 (2019). https://doi.org/10.1134/S1070428019020064
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DOI: https://doi.org/10.1134/S1070428019020064