Abstract
Reactions were studied of peroxide ozonolysis products obtained from linear and cyclic alkenes with hydroxylamine prepared in situ from NH2OH·HCl by hydrogen chloride neutralization with sodium acetate. A one-pot reactions sequence was performed: alkene oxidation with ozone → reduction to a carbonyl compound with hydroxylamine → condensation of the carbonyl compound with hydroxylamine providing a possibility of direct transformation of alkenes in keto- and aldoximes excluding the stage of preparation and isolation of the carbonyl compound.
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Original Russian Text © Yu.V. Legostaeva, L.R. Garifullina, I.S. Nazarov, N.M. Ishmuratova, G.Yu. Ishmuratov, 2018, published in Zhurnal Organicheskoi Khimii, 2018, Vol. 54, No. 8, pp. 1116–1120.
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Legostaeva, Y.V., Garifullina, L.R., Nazarov, I.S. et al. Hydroxylamine Reactions with Peroxide Products of Alkenes Ozonolysis. Russ J Org Chem 54, 1122–1126 (2018). https://doi.org/10.1134/S107042801808002X
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DOI: https://doi.org/10.1134/S107042801808002X