Abstract
Primary and secondary aliphatic, alkylaromatic, cyclic, and organoelement alcohols are efficiently oxidized by tert-butyl hydroperoxide in the presence of both equimolar and catalytic quantities of chromium tetra-tert-butoxide (С6Н6, 20°С). α-Diols containing tertiary hydroxyl groups interact with this system via oxidative splitting of the carbon scaffold. The oxidation includes the stages of formation and decomposition of chromium-containing peroxy compounds. Further transformations of the carbonyl compounds depend on the structure of radicals in the molecules.
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Original Russian Text © L.P. Stepovik, Е.А. Zaburdaeva, G.K. Fukin, K. Karaghiosoff, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 11, pp. 1805–1817.
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Stepovik, L.P., Zaburdaeva, E.A., Fukin, G.K. et al. Reactions of hydroxyl-containing compounds with tert-butyl hydroperoxide in the presence of chromium tetra-tert-butoxide. Russ J Gen Chem 85, 2547–2559 (2015). https://doi.org/10.1134/S1070363215110080
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DOI: https://doi.org/10.1134/S1070363215110080