Abstract
New ion polymeric gold(III)–silver(I) complexes, {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n have been synthesized and characterized by X-ray diffraction data and IR spectra. The structure of the first complex is represented by [Au{S2CNEt2}2]+ complex cations and polymeric silver chloride anion ([AgCl2]–)n; the second complex consists of isomeric cations, linear [AgCl2]– anions, chloride ions, and water molecules. Gold cations are involved in zigzag (AuAuAu angle 99.06°) and linear polymeric chains via secondary Au···S bond pairs. Thermal decomposition of the complexes with regeneration of gold and silver has been studied by simultaneous thermal analysis (STA).
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Original Russian Text © E.V. Korneeva, O.V. Loseva, A.I. Smolentsev, A.V. Ivanov, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 8, pp. 1361–1370.
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Korneeva, E.V., Loseva, O.V., Smolentsev, A.I. et al. Reactivity of Silver(I) Diethyldithiocarbamate and Ion-Polymeric Complexes {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n: Synthesis, Supramolecular Structures, and Thermal Behavior. Russ J Gen Chem 88, 1681–1689 (2018). https://doi.org/10.1134/S1070363218080200
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DOI: https://doi.org/10.1134/S1070363218080200