Abstract
The reaction of BiI3 and NaI in acetone gives a trinuclear iodobismuthate complex, [Na3(Me2CO)12][Bi3I12] (I), which was studied by X-ray diffraction (CIF file CCDC no. 996330). The centrosymmetric [Bi III3 I12]3− anions are groups of three distorted {BiI6} octahedra coupled at the faces. The sodium cations combine six Me2CO molecules in the bidentate bridging mode to give linear trimers in which the side sodium ions coordinate six terminal acetone molecules.
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Original Russian Text © S.A. Adonin, E.V. Peresypkina, M.N. Sokolov, V.P. Fedin, 2014, published in Koordinatsionnaya Khimiya, 2014, Vol. 40, No. 12, pp. 699–702.
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Adonin, S.A., Peresypkina, E.V., Sokolov, M.N. et al. Trinuclear iodobismuthate complex [Na3(Me2CO)12][Bi3I12]: Synthesis and crystal structure. Russ J Coord Chem 40, 867–870 (2014). https://doi.org/10.1134/S107032841412001X
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DOI: https://doi.org/10.1134/S107032841412001X