Abstract
Mononuclear complexes TBA[Bi(NN)I4] (TBA = tetra-n-butylammonium, NN = 2,2′-bipyridyl (1) and 1,10-phenanthroline (2)) are synthesized by the reaction of BiI3, tetra-n-butylammonium iodide, and the corresponding ligand in acetone with subsequent crystallization from a benzene-acetone mixture. By changing the solvent used in crystallization to ethanol, binuclear [Bi2(NN)2I6] complexes (3 and 4) are produced. The crystal structure of the compounds is determined by single crystal X-ray diffraction.
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Translated from Zhurnal Strukturnoi Khimii, Vol. 56, No. 4, pp. 758-763, July-August, 2015. Original article submitted January 28, 2015.
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Adonin, S.A., Sokolov, M.N. & Fedin, V.P. Mono- and binuclear Bi(III) iodide complexes containing 2,2′-bipyridyl and 1,10-phenanthroline: Synthesis and structure. J Struct Chem 56, 708–713 (2015). https://doi.org/10.1134/S0022476615040149
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DOI: https://doi.org/10.1134/S0022476615040149