Abstract
Three new complexes, [CdL2(CH3COO)2(H2O)2] (I), CdL2Br2 (II), CdL2I2 (III), have been successfully synthesized by self-assembly of corresponding metal salts with (E)-2-(3-(4-(1H-imidazole-1-yl)styryl)-5,5-dimethylcyclohex-2-enylidene)malononitrile (L). The structures of the complexes were determined by single crystal X-ray diffraction analysis (CIF file CCDC nos. 957831 (I), 957792 (II), 957832 (III)). In complex I, central metal is six-coordinated and the crystal packing shows a 3D supramolecular framework. Complexes II and III display the similar 2D supramolecular structures in which the central metals are four-coordination. The luminescent properties were investigated.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
Xie, Y.P., Yang, J., Ma, J.F., et al., Cryst. Growth Des., 2009, vol. 9, no. 9, p. 3881.
Guha, S., Drew, M.G., and Banerjee, A., Cryst. Growth Des., 2010, vol. 10, no. 11, p. 4716.
Corma, A., Garcia, H., and Llabrés i Xamena, F., Chem. Rev., 2010, vol. 110, no. 8, p. 4606.
Liu, Q.K., Ma, J.P., and Dong, Y.B., Chem. Commun., 2011, vol. 47, p. 12343.
Jin, F., Zhang, Y., Wang, H.Z., et al., Cryst. Growth Des., 2013, vol. 13, p. 1978.
Yan, D., Patel, B., Delory, A., et al., Cryst. Growth Des., 2013, vol. 13, p. 333.
Ebenezer, S., Muthiah, P.T., and Butcher, R.J., Cryst. Growth Des., 2011, vol. 11, p. 3579.
Liu, Y., Zhao, Y.L., Zhang, H.Y., et al., Macromolecules, 2004, vol. 37, no. 17, p. 6362.
Richards, V.J., Argent, S.P., Kewley, A., et al., Dalton Trans., 2012, vol. 41, p. 4020.
Fang, S.M., Zhang, Q., Hu, M., et al., Inorg. Chem., 2010, vol. 49, no. 20, p. 9617.
Plessis, M. du and Barbour, L.J., Dalton Trans., 2012, vol. 41, p. 3895.
Tedesco, C., Erra, L., Immediata, I., et al., Cryst. Growth Des., 2010, vol. 10, no. 4, p. 1527.
Luo, L., Chen, K., Liu, Q., et al., Cryst. Growth Des., 2013, vol. 13, p. 2312.
Li, G.B., Liu, J.M., Cai, Y.P., et al., Cryst. Growth Des., 2011, vol. 11, p. 2763.
Morrison, C.N., Powell, A.K., and Kostakis, G.E., Cryst. Growth Des., 2011, vol. 11, p. 3653.
Hou, S., Liu, Q.K., Ma J.P., et al., Inorg. Chem., 2013, vol. 52, p. 3225.
Shin, J.W., Bae, J.M., Kim, C., et al., Inorg. Chem., 2013, vol. 52, p. 2265.
Jin, F., Wang, H.Z., Zhang, Y., et al., CrystEngComm, 2013, vol. 15, p. 3687.
Zaman, M.B., Udachin, K.A., and Ripmeester, J.A., Cryst. Growth Des., 2004, vol. 4, p. 585.
Zheng, Z., Yu, Z.P., Yang, M.D., et al., J. Org. Chem., 2013, vol. 78, p. 3222.
Sheldrick, G.M., SADABS, A Program for Exploiting the Redundancy of Area-Detector X-ray Data, Göttingen (Germany): Univ. of Göttingen, 1999.
Wei, G.H., Yang, J., Mang, J.F., et al., Dalton Trans., 2008, vol. 29, p. 3080.
Zhao, W., Fan J., Okamura, T.A., et al., New J. Chem., 2004, vol. 28, p. 1142.
Wang, L., Yan, Z.H., Xiao, Z.Y., et al., CrystEngComm, 2013, vol. 15, p. 5552.
Kuai, H.W., Fan, J., Liu, Q., et al., CrystEngComm, 2012, vol. 14, p. 3708.
Alvarez, H.M., Tran, T.B., Richter, M.A., et al., Inorg. Chem., 2003, vol. 42, no. 6, p. 2149.
Li, C.Y., Liu, C.S., Li, J.R., et al., Cryst. Growth Des., 2007, vol. 7, no. 2, p. 286.
Bai, H.Y., Ma, J.F., Yang J., et al., Cryst. Growth Des., 2010, vol. 10, no. 2, p. 995.
Kimblin, C. and Parkin, G., Inorg. Chem., 1996, vol. 35, no. 24, p. 6912.
Zhang, S., Lan, J., Mao, Z., et al., Cryst. Growth Des., 2008, vol. 8, no. 9, p. 3134.
Du, M., Chen, S.T., and Bu, X.H., Cryst. Growth Des., 2002, vol. 2, no. 6, p. 625.
Ma, Q., Zhu, M., Yuan, C., et al., Cryst. Growth Des., 2010, vol. 10, no. 4, p. 1706.
Author information
Authors and Affiliations
Corresponding author
Additional information
The article is published in the original.
Rights and permissions
About this article
Cite this article
Xi, W.G., Yang, M.D., Wang, L.P. et al. Crystal structures and luminescence of a series of cadmium(II) complexes based on isophorone derivative containing imidazolyl. Russ J Coord Chem 40, 704–710 (2014). https://doi.org/10.1134/S107032841410011X
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S107032841410011X