Abstract
The influence of the composition of solutions of peracetic acid on a change in the characteristics of cellulose during the oxidative-hydrolytic destruction of aspen and pine wood under microwave radiation was investigated. Samples of the prepared cellulose were characterized by viscometry, X-ray diffraction and IR spectroscopy. It was found that the main factor determining the rate of destruction of cellulose to a low degree of polymerization values in an acid medium at the initial concentration of peracetic acid not exceeding 15% and initial concentration of hydrogen peroxide no more than 3 mol/dm3 is the concentration of sulfuric acid. The disordering effect of microwave radiation on the crystallites of cellulose during preparation from pine wood in the presence of sulfuric acid in a concentration of 0.06 mol/dm3 and increased duration of oxidative-hydrolytic treatment from 1 to 2 h was revealed. It was shown that the characteristics of the products obtained from aspen and pine wood by oxidative-hydrolytic treatment with 15% peracetic acid under microwave radiation, the duration of the process of 1.5–2 h and the sulfuric acid concentration of 0.3–0.7 mol/dm3 correspond to partially oxidized microcrystalline cellulose.
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Original Russian Text © E.Yu. Kushnir, S.A. Autlov, N.G. Bazarnova, 2014, published in Khimiya Rastitel’nogo Syr’ya, 2014, No. 2, pp. 41–50.
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Kushnir, E.Y., Autlov, S.A. & Bazarnova, N.G. Preparation of microcrystalline cellulose directly from wood under microwave radiation. Russ J Bioorg Chem 41, 713–718 (2015). https://doi.org/10.1134/S1068162015070079
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DOI: https://doi.org/10.1134/S1068162015070079