Abstract
In this study, we describe the application of carbon paste electrode modified with multiwall carbon nanotubes as a voltammetric sensor for determination of penicillamine (PA) in the presence of chlorpromazine as a mediator. This modified electrode showed very efficient electrocatalytic activity for the anodic oxidation of PA. The peak current of linear sweep voltammograms of PA increased linearly with it’s concentration in the range of 0.5–500 μM PA. The detection limit for PA was 0.2 μM. The RSDs for 1.0 and 10.0 μM PA were 1.1 and 1.7%, respectively. The proposed sensor was successfully applied for the determination of PA in human urine and tablet.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
Walshe, J.M., Am. J. Med., 1956, vol. 21, p. 487.
Sarkar, B., Chem. Rev., 1999, vol. 99, p. 2535.
Gooneratne, S.R. and Christensen, D.A., Vet. J., 1997, vol. 153, p. 171.
LeRoy, E.C., Trojanowska, M., and Smith, E.A., Clin. Exp. Rheumatol., 1991, vol. 9, p. 173.
Jaffe, I.A., Am. J. Med., 1983, vol. 75, p. 63.
Stephens, A.D., J. Inherited Metab. Dis., 1989, vol. 12, p. 197.
Cervantes, G., Moreno, V., Molins, E., and Quiros, M., Polyhedron, 1998, vol. 17, p. 3343.
Liang, S.C., Wang, H., Zhang, Z.M., and Zhang, H.S., Anal. Bioanal. Chem., 2005, vol. 381, p. 1095.
Saetre, R. and Rabenstein, D.L., Anal. Chem., 1978, vol. 50, p. 276.
Ensafi, A.A., Karimi-Maleh, H., and Mallakpour, S., Electroanalysis, 2011, vol. 23, p. 1478.
Khalilzadeh, M.A., Karimi-Maleh, H., Amiri, A., Gholami, F., and Motaghed, M., Chin. Chem. Lett., 2010, vol. 21, p. 1467.
Ensafi, A.A. and Karimi-Maleh, H., J. Electroanal. Chem., 2010, vol. 640, p. 75.
Ensafi, A.A. and Karimi-Maleh, H., Electroanalysis, 2010, vol. 22, p. 2558.
Karimi-Maleh, H., Tahernejad-Javazmi, F., Atar, N., Yola, M.L., Gupta, V.K., and Ensafi, A.A., Ind. Eng. Chem. Res., 2015, vol. 54, p. 3634.
Karimi-Maleh, H., Tahernejad-Javazmi, F., Ensafi, A.A., Moradi, R., Mallakpour, S., and Beitollahi, H., Biosens. Bioelectron., 2014, vol. 60, p. 1.
Karimi-Maleh, H., Biparva, P., and Hatami, M., Biosens. Bioelectron., 2013, p. 270.
Moradi, R., Sebt, S.A., Karimi-Maleh, H., Sadeghi, R., Karimi, F., Bahari, A., and Arabi, H., Phys. Chem. Chem. Phys., 2013, vol. 15, p. 5888.
Afsharmanesh, E., Karimi-Maleh, H., Pahlavan, A., and Vahedi, J., J. Mol. Liq., 2013, vol. 181, p. 8.
Beitollah, H., Goodarzian, M., Khalilzadeh, M.A., Karimi-Maleh, H., Hassanzadeh, M., and Tajbakhsh, M., J. Mol. Liq., 2012, vol. 173, p. 137.
Najafi, M., Khalilzadeh, M.A., and Karimi-Maleh, H., Food Chem., 2014, vol. 158, p. 125.
Raoof, J.B., Ojani, R., and Karimi-Maleh, H., Electroanalysis, 2008, vol. 20, p. 1259.
Bahari, A., Karimi-Maleh, H., Hosseinzadeh, R., and Mirnia, N., Sens. Actuators, B, 2013, vol. 177, p. 70.
Ensafi, A.A., Karimi-Maleh, H., Ghiaci, M., and Arshadi, M., J. Mater. Chem., 2011, vol. 21, p. 15022.
Yaghoubian, H., Karimi-Maleh, H., Khalilzadeh, M.A., and Karimi, F., Int. J. Electrochem. Sci., 2009, vol. 4, p. 993.
Karimi-Maleh, H., Mehdipour-Ataei, S., Hatami, M., and Khalilzadeh, M.A., J. Anal. Chem., 2014, vol. 69, p. 162.
Keyvanfard, M., Ensafi, A.A., and Karimi-Maleh, H., J. Solid State Electrochem., 2012, vol. 16, p. 2949.
Keyvanfard, M., Rezaei, B., and Alizad, K., Curr. Nanosci., 2014, vol. 10, p. 512.
Keyvanfard, M., Karimi-Maleh, H., and Alizad, K., Chin. J. Catal., 2013, vol. 34, p. 1883.
Keyvanfard, M., Khosravi, V., Karimi-Maleh, H., Alizad, K., and Rezaei, B., J. Mol. Liq., 2013, vol. 177, p. 182.
Keyvanfard, M., Sami, S., Karimi-Maleh, H., and Alizad, K., J. Braz. Chem. Soc., 2013, vol. 24, p. 32.
Keyvanfard, M., Shakeri, R., Karimi-Maleh, H., and Alizad, K., Mater. Sci. Eng., 2013, vol. 33, p. 811.
Author information
Authors and Affiliations
Corresponding author
Additional information
The article is published in the original.
Rights and permissions
About this article
Cite this article
Keyvanfard, M., Najjarian, N. & Alizad, K. Electrocatalytic determination of penicillamine using multiwall carbon nanotubes paste electrode and chlorpromazine as a mediator. J Anal Chem 72, 1045–1050 (2017). https://doi.org/10.1134/S1061934817100136
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1061934817100136