Abstract
The miscibility of linear polyisobutylene and silica nanoparticles with surfaces modified by decyl groups is studied. The phase state of these systems corresponds to the amorphous equilibrium and may be described by a binodal with the UCST. As the radius of the inorganic core of nanoparticles and the molecular mass of polyisobutylene increase, the insolubility region on the phase diagram becomes wider. The addition of nanoparticles to the polymer leads to decreases in the viscoelastic characteristics of homogeneous media and provides the non-Newtonian behavior of the composition in the two-phase region. Shear deformation causes shifts of the phase equilibrium lines in the direction depended on the sizes of the nanoparticles.
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References
M. Xanthos, Functional Fillers for Plastics (Wiley-VCH Verlag, Berlin, 2010).
F. Gao, Advances in Polymer Nanocomposites (Wood-head Publ., Cambridge, 2012).
L. Nicolais and G. Carotenuto, Metal-Polymer Nanocomposites (Wiley, Hoboken, 2005).
V. Favier, H. Chanzy, and J. Y. Cavaille, Macromolecules 28(18), 6365 (1995).
Y. Zhou, S. Yu, C. Wang, et al., Chem. Commun. 13, 1229 (1999).
R. A. Vaia, B. B. Sauer, O. K. Tse, and E. P. Giannelis, J. Polym. Sci., Polym. Phys. Ed. 35(1), 59 (1997).
M. Moniruzzaman and K. I. Winey, Macromolecules 39(16), 5194 (2006).
M. S. Wang and T. J. Pinnavaia, Chem. Mater. 6(4), 468 (1994).
P. Podsiadlo, A. K. Kaushik, E. M. Arruda, et al., Science 318(5847), 80 (2007).
E. P. Giannelis, Appl. Organomet. Chem. 12, 675 (1998).
T. Kashiwagi, F. Du, J. F. Douglas, et al., Nature Mater. 4, 928 (2005).
R. Gangopadhyay and A. De, Chem. Mater. 12(3), 608 (2000).
R. A. Vaia, S. Vasudevan, W. Krawiec, et al., Adv. Mater. 7(2), 154 (1995).
H. Zou, S. Wu, and J. Shen, Chem. Rev. 108(9), 3893 (2008).
M. Tanahashi, Materials 3(3), 1593 (2010).
O. Aso, J. I. Eguiazarbal, and J. Nazarbal, Compos. Sci. Technol 67, 2854 (2007).
H. Sertchook, H. Elimelech, C. Makarov, et al., J. Am. Chem. Soc. 129, 98 (2007).
M. Z. Rong, M. Q. Zhang, and W. H. Ruan, Mater. Sci. Technol 22(7), 787 (2006).
S.-W. Zhang, S.-X. Zhou, Y.-M. Weng, and L.-M. Wu, Langmuir 21, 2124 (2005).
M. Nakamura, US Patent No. 0330582 (2010).
V. V. Kazakova, A. S. Zhiltsov, O. B. Gorbatsevitch, et al., J. Inorg. Organomet. Polym. Mater 22(3), 564 (2012).
L. A. Novokshonova, P. N. Brevnov, V. G. Grinev, et al., Nanotechnol. Russ. 3(5–6), 330 (2008).
N. V. Voronina, I. B. Meshkov, V. D. Myakushev, et al., Nanotechnol. Russ. 3(5–6), 321 (2008).
N. V. Voronina, I. B. Meshkov, V. D. Myakushev, et al., J. Polym. Sci., Part A: Polym. Chem. 48, 4310 (2010).
V. V. Kazakova, E. A. Rebrov, V. D. Myakushev, et al. in Am. Chem. Soc. Symp. Book Series 729, Ed. by S. J. Clarson, J. J. Fitzgerald, M. J. Owen, and S. D. Smith (Am. Chem. Soc, New York, 2000).
Z. Grubisic, R. Rempp, and H. Benoir, J. Polym. Sci., Part B: Polym. Phys. 5, 753 (1967).
A. E. Chalykh, V. K. Gerasimov, and Yu. M. Mikhailov, Phase State Diagrams of Polymer Systems (Yanus-K, Moscow, 1998) [in Russian].
V. Makarova and V. Kulichikhin, Interferometry. Research and Applications in Science and Technology, Ed. by I. Padron (InTech, Rijeka, 2012).
A. B. Bourlinos, R. Herrera, N. Chalkias, et al., Adv. Mater. 17, 234 (2005).
R. Rodriguez, R. Herrera, L. A. Archer, and E. P. Giannelis, Adv. Mater. 20, 4353 (2008).
S. Ilyin, V. Kulichikhin, and A. Malkin, Appl. Rheol 24(1), 13653 (2014).
S. O. Ilyin, A. Ya. Malkin, and V. G. Kulichikhin, Polym. Sci., Ser. A 56(1), 98 (2014).
M. B. Kossuth, D. C. Morse, and F. S. Bates, J. Rheol 43, 167 (1999).
C. Y. Ryu, M. S. Lee, D. A. Hajduk, and T. P. Lodge, J. Polym. Sci., Part B: Polym. Phys. 35, 2811 (1997).
A. B. Bourlinos, E. P. Giannelis, Q. Zhang, et al., Eur. Phys. J. 20, 109 (2006).
A. E. Chalykh and V. K. Gerasimov, Russ. Chem. Rev. 73(1), 59 (2004).
S. A. Vshivkov and E. V. Rusinova, Polym. Sci., Ser. A 36(1), 81 (1994).
S. V. Kotomin, S. O. Il’in, T. N. Filippova, and G. K. Shambilova, Polym. Sci., Ser. A 55(3), 186 (2013).
A. Ya. Malkin and S. G. Kulichikhin, Polym. Sci., Ser. B 38(2), 362 (1996).
W. Kuhn, H. Majer, and F. Burkhardt, Helv. Chim. Acta 43(5), 1208 (1960).
H. Edwards, J. Appl. Polym. Sci. 12(10), 2213 (1968).
T. M. Clausen, P. K. Vinson, J. R. Minter, et al., J. Phys. Chem. 96(1), 474 (1992).
E. K. Wheeler, P. Izu, and G. G. Fuller, Rheol. Acta. 35(2), 139 (1996).
L. M. Walker, Curr. Opin. Colloid Interface Sci 6, 451 (2001).
A. Ya. Malkin, Polym. Sci., Ser. A 48(1), 39 (2006).
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Original Russian Text © E.A. Karpukhina, S.O. Il’in, V.V. Makarova, I.B. Meshkov, V.G. Kulichikhin, 2014, published in Vysokomolekulyarnye Soedineniya. Ser. A, 2014, Vol. 56, No. 6, pp. 670–684.
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Karpukhina, E.A., Il’in, S.O., Makarova, V.V. et al. Phase state and rheology of polyisobutylene mixtures with decyl surface modified silica nanoparticles. Polym. Sci. Ser. A 56, 798–811 (2014). https://doi.org/10.1134/S0965545X14060066
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DOI: https://doi.org/10.1134/S0965545X14060066