Abstract
After the addition of the saturated NaClO4 solution to a solution of trans-[Ru(NO)(NH3)4SO4]HSO4•H2O, trans-[Ru(NO)(NH3)4SO4]ClO4 perchlorate salt (I) is obtained with the yield of ~80%. The heating of trans-[Ru(NO)(NH3)4(H2O)](HSO4)SO4 at a temperature of ~220 °C results in a complete removal of coordination water and a partial removal of ammonia molecules. Successive treatment of the thermolysis product with sulfuric and hydrochloric acids yields [Ru(NO)(NH3)4SO4][Ru(NO)(NH3)3Cl(SO4)]HSO4•H2O crystals (II). The single crystal X-ray diffraction method is used to determine the structure of the compounds obtained. For I: space group P21/c, a = 6.6949(9) Å, b = 13.7049(19) Å, c = 12.8641(17) Å, β = 101.028(4)°; for II: space group Р21/c, a = 14.1304(4) Å, b = 12.4908(3) Å,, c = 11.6264(3) Å, β = 94.1980(10)°.
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Original Russian Text © 2016 A. N. Makhinya, M. A. Il’in, I. A. Baidina, and I. V. Korol’kov.
Translated from Zhurnal Strukturnoi Khimii, Vol. 57, No. 6, pp. 1242-1247, July-August, 2016.
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Makhinya, A.N., Il’in, M.A., Baidina, I.A. et al. Synthesis and crystal structure of trans-[Ru(NO)(NH3)4SO4]ClO4 and [Ru(NO)(NH3)4SO4][Ru(NO)(NH3)3Cl(SO4)]HSO4•H2O. J Struct Chem 57, 1182–1187 (2016). https://doi.org/10.1134/S0022476616060184
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DOI: https://doi.org/10.1134/S0022476616060184