Abstract
Cardo containing phenoxy and -CF3 derivate diamine was synthesized, and further it was polymerized with 3,3′,4,4′-biphenyl tetracarboxylic dianhydride to prepare polyetherimide containing Cardo group. The transmittance of the prepared polymer increased from 82% to 88% and the dielectric constant decreased from 2.91 to 2.83 with a slight decline in thermal and mechanical performance when -CF3 was introduced. The molecular simulation in terms of charge distribution, electric potential energy, chain stiffness and aggregation state revealed that -CF3 could restrain charge transfer and decrease the unit dipole moment and polarization for its larger volume. The optical and dielectric performance was significantly enhanced, but the thermal and mechanical performance decreased slightly when the -CF3 group was introduced. The glass transition temperature of the polymer declined from 329 °C to 311 °C. The investigation conducted in this paper can offer valuable reference to the optimization and development of synthesis and comprehensive performance of polyimide.
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Acknowledgments: This work was sponsored by national natural science foundation of China under grant 51973056 and 52173034, Hunan provincial project of science and technology under grant 2020NK2035, 2021JJ50031 and 2021JJ50009, scientific research projects of Hunan provincial department of education under grant 18A258 and 18C0524, the science and technology innovation program of Hunan province under grant 2021RC4065.
Supporting information: Information is available regarding the molecular simulation results for the polymer and characterization of diamine. The materials are available via the Internet at http://www.springer.com/13233.
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Peng, J., Wang, Q., Wang, J. et al. Structure and Properties of Low Dielectric Constant Polyetherimide Films Containing-CF3 and Cardo Groups. Macromol. Res. 30, 826–835 (2022). https://doi.org/10.1007/s13233-022-0089-6
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DOI: https://doi.org/10.1007/s13233-022-0089-6